scholarly journals Significance of variation in extent of recrystallization of zircon in orogenic eclogite

Author(s):  
Donna Whitney ◽  
Clementine Hamelin ◽  
Christian Teyssier ◽  
Francoise Roger ◽  
Patrice Rey

<p>Migmatite domes are common structures in orogens, and in some cases are comprised of deeply-sourced crust that experienced lateral and subsequent vertical flow, with ultimate emplacement in the mid/upper crust. The record of the deep-crustal history survives in layers and lenses of refractory rock types within the dominant quartzofeldspathic gneiss. These deep-crustal relics are typically the best archives of pressure-temperature-time-deformation conditions of crustal flow, although it can be difficult to extract information about the duration of deep-crustal residence – such as might accompany lateral flow of deep-crust – because intracrystalline diffusion at protracted high temperatures may erase much of the history and/or minerals may record only the timing of final emplacement and cooling. One possible indicator of deep-crustal history is the extent of recrystallization of zircon that experienced eclogite-facies conditions; the conditions of zircon growth/recrystallization are indicated by REE abundance and results of Ti-in-zircon thermometry. For example, in the eclogite-bearing Montagne Noire migmatite dome of the southern French Massif Central, zircon in eclogite from the core of the dome has been extensively recrystallized under eclogite-facies conditions. In contrast, zircon in eclogite from the margin of the dome experienced very little recrystallization and largely consists of inherited (magmatic) cores with very thin (<20 um) eclogite-facies rims. The two eclogites, which both contain garnet + omphacite + rutile + quartz, record the same age of protolith crystallization (~450 Ma) and high-P metamorphism (~315 Ma), and similar metamorphic conditions (700 ± 20°C, 1.4 ±0.1 GPa). Differences in extent of recrystallization of zircon in the two eclogites may relate to duration at high T and/or extent of interaction with aqueous fluid (ongoing work to obtain in situ oxygen isotope data for zircon and garnet will evaluate the latter for each eclogite). Deformation may have been involved in recrystallization of zircon, but is not the primary factor accounting for the differences in extent of recrystallization; both eclogites were deformed during eclogite-facies metamorphism, as indicated by crystallographic-preferred orientation of omphacite and shape-preferred orientation of rutile. Other variables that are also unlikely to explain differences in these eclogite zircons are differences in host rock chemistry, availability of Zr from decompression reactions involving Zr-bearing minerals, extent of radiation damage, and original crystal size. The two most likely explanations for variations in zircon recrystallization are duration at high-T and extent of fluid-rock interaction. In the case of the former, dome-margin eclogite may have had a shorter residence time in the deep crust and was more directly exhumed from a proximal source, whereas the dome-core eclogite may have had a more extended transit in the deep-crust before being exhumed in the steep, median high-strain zone of the migmatite dome.</p>

2020 ◽  
Author(s):  
Michel Bestmann ◽  
Benjamin Huet ◽  
Bernhard Grasemann ◽  
Giorgio Pennacchioni

<p>Quartz veins in poly-metamorphic settings often accommodate the latest deformation state and therefore can provide important information. Identification of microfabric (microstructure and crystallographic preferred orientation, CPO) evolution of quartz during mylonitization, and especially of the grain-scale interplay between brittle and crystal-plastic processes, has different relevant implications: e.g., on understanding the efficiency of fluid mobility through deforming quartz that can dramatically influence the rheology and the degree of chemical exchange. However, in order to interpret the microstructure and the related deformation processes it is necessary to relate these especially to the deformation temperature. Particularly the CPO and the Ti-in-qtz geothermometry is used to constrain the deformation temperature. However, both methods have to be applied with great caution because even when many times used some fundamental processes are not fully understood yet.</p><p> </p><p>Here we present results from deformed quartz veins from the Prijakt Nappe (Autroalpine Unit, Schober Mountains, Central Eastern Alps). These veins localized ductile shear and eventually seismic faulting (recorded by the occurrence of pseudotachylytes) within Eo-Alpine eclogite-facies shists. The veins formed shortly after the eclogitic peak, but the temperature of their deformation remains unconstrained. CL imaging reveals critical details for understanding the role of microfracturing and fluid-rock interaction during initial stages of shear localization, the onset of dynamic recrystallization and the resetting of the Ti-in-quartz geochemistry. Even when optical-light-microscopy and EBSD analysis indicate crystal plastic deformation by subgrain rotation CL and orientation contrast (OC) imaging gives evidence of brittle stage of deformation at least for some of the deformation microstructure. Microshear zones show a bulk dark-CL, but still bright tones in cores of new recrystallized grains similar to the CL signature of the host coarse quartz crystals. CL dark tones also match with the pattern of subgrain boundaries. This reflects fluid permeability pathways along subgrain and grain boundaries (identified by widespread fluid inclusions) and the associated partial resetting of Ti concentrations. The CPO of the new grains within the micro-shear zones rotate with the sense of shear around the kinematic Y-axis and cannot be related to the activity of specific slip systems. In contrast the partial single girdle of c-axis within the ultramylonite with its elongated substructured grains and its characteristic layered microstructure can be related to the activity of several slip systems. Misorientation axis analysis indicates that prism</p><p> </p><p> </p><p> </p>


2020 ◽  
Author(s):  
Anna Rogowitz ◽  
Benjamin Huet

<p>The classical eclogite assemblage consists of the non-hydrous minerals garnet and omphacite. Nevertheless, it is widely accepted that the transformation of mafic magmatic rocks into eclogite requires fluid infiltration. The most common fluid pathway referred to are cracks acting as brittle precursor for fluid-supplied eclogitization, followed by subsequent strain localization, possibly enhancing further eclogitization. While this seems to be a common observation, it is still not fully understood by which processes fluids enhance the metamorphic processes. Herein a set of eclogites from the type-locality (Hohl, Koralpe, Austria, Eastern Alps) representing three different strain stages has been analyzed by means of their microstructure and petrology. Additionally, thermodynamic forward modelling has been performed to constrain pressure, temperature and water activity during eclogitization. All samples are composed of garnet (grt), sodic-clinopyroxene (cpx), quartz (qtz) and a fine grained polycrystalline aggregate (fgpa) of kyanite (ky), clinozoisite (czo) and retrograde plagioclase (pl). While the mineral assemblage is identical in all investigated samples, we do observe minor variation in the volume fraction of each mineral, the specific mineral chemistry and the microstructure with respect to the different eclogite types. <br>Almost unstrained eclogites are characterized by grt coronas surrounding cpx in a fgpa matrix. Locally the replacement of coarse crystals of sodium-poor pyroxene by a polycrystalline mixture of qtz and cpx can be observed. In intermediate strained eclogites grt occurs in elongated clusters surrounded by cpx and fgpa matrix. Clinopyroxene grains start to develop a shape preferred orientation (SPO) together with a weak crystallographic preferred orientation (CPO). Highly strained eclogites are characterized by a pronounced foliation defined by a SPO of cpx and elongated layers of fgpa. Garnet again occurs as elongated clusters locally starting to disaggregate perpendicular to the foliation. Though cpx matrix grains develop a more pronounced CPO with increasing strain hardly any intracrystalline deformation can be observed. In all samples we observe symplectites composed of diopside and pl surrounding elongated cpx grains indicating that deformation occurred at eclogite-facies conditions. <br>Thermodynamic modelling yield formation conditions of approximately 2.4 GPa, 670 °C and a H2O activity slightly lower than 1 suggesting that fluid supply did play an important role during eclogitization and deformation. Nevertheless, different to above mentioned studies, we do not observe any positive correlation between fractures and reaction front. Our microstructural and petrological investigations instead reveal the formation of a micro-porosity along new developed grain boundaries allowing fluids to migrate to the reaction front, slowly consuming the original gabbroic protolith and replacing it with the stable eclogitic mineral paragenesis. This rather static-type of eclogitization seems to be dominated by dissolution-reprecipitation processes and is resulting in a volume reduction of about 12 %. Subsequent volumetric and tectonic strain is further accommodated by dissolution-reprecipitation resulting in the development of foliated eclogites. Finally, lack of chemical zoning in minerals suggests that formation and deformation of the investigated eclogites occurred under stable P-T-fluid conditions. This study emphasizes that the planar and linear fabric of eclogites might not always be directly related to eclogite facies shear zones.</p>


2021 ◽  
Vol 176 (7) ◽  
Author(s):  
Thomas Bovay ◽  
Daniela Rubatto ◽  
Pierre Lanari

AbstractDehydration reactions in the subducting slab liberate fluids causing major changes in rock density, volume and permeability. Although it is well known that the fluids can migrate and interact with the surrounding rocks, fluid pathways remain challenging to track and the consequences of fluid-rock interaction processes are often overlooked. In this study, we investigate pervasive fluid-rock interaction in a sequence of schists and mafic felses exposed in the Theodul Glacier Unit (TGU), Western Alps. This unit is embedded within metaophiolites of the Zermatt-Saas Zone and reached eclogite-facies conditions during Alpine convergence. Chemical mapping and in situ oxygen isotope analyses of garnet from the schists reveal a sharp chemical zoning between a xenomorphic core and a euhedral rim, associated to a drop of ~ 8‰ in δ18O. Thermodynamic and δ18O models show that the large amount of low δ18O H2O required to change the reactive bulk δ18O composition cannot be produced by dehydration of the mafic fels from the TGU only, and requires a large contribution of the surrounding serpentinites. The calculated time-integrated fluid flux across the TGU rocks is 1.1 × 105 cm3/cm2, which is above the open-system behaviour threshold and argues for pervasive fluid flow at kilometre-scale under high-pressure conditions. The transient rock volume variations caused by lawsonite breakdown is identified as a possible trigger for the pervasive fluid influx. The calculated schist permeability at eclogite-facies conditions (~ 2 × 10–20 m2) is comparable to the permeability determined experimentally for blueschist and serpentinites.


2018 ◽  
Vol 490 ◽  
pp. 151-160 ◽  
Author(s):  
Yu Nishihara ◽  
Tomohiro Ohuchi ◽  
Takaaki Kawazoe ◽  
Yusuke Seto ◽  
Genta Maruyama ◽  
...  

2011 ◽  
Vol 96 (10) ◽  
pp. 1630-1635 ◽  
Author(s):  
R. McCormack ◽  
D. P. Dobson ◽  
N. P. Walte ◽  
N. Miyajima ◽  
T. Taniguchi ◽  
...  

2012 ◽  
Vol 39 (8) ◽  
pp. 613-626 ◽  
Author(s):  
P. Kaercher ◽  
S. Speziale ◽  
L. Miyagi ◽  
W. Kanitpanyacharoen ◽  
H.-R. Wenk

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