Study of non-Newtonian polymer blends using large amplitude oscillatory shearing flow

Large amplitude oscillatory shear (LAOS) was performed on non-Newtonian minor phase in Newtonian matrix phase polymer blends as a first step toward understating more complex immiscible polymer blends under high deformation condition. The blend consists polybutadiene (PBD) as the droplet phase and polydimethylsiloxane (PDMS) as the matrix phase. The PBD droplet phase was an elastic “Boger” fluid prepared by dissolving a high-molecular-weight PBD into a low-molecular-weight Newtonian PBD. Different percentages of the high-molecular-weight PBD were used to prepare different types of Boger fluids that resulted in blends with different viscosity ratios from lower than unity, to unity and higher than unity. Furthermore, the LAOS results of the blends were analyzed by using the Fourier Transform (FT) technique. From a theoretical point of view, the constrained volume model (CV-model) for Newtonian components is adapted to the case of a Newtonian matrix phase and non-Newtonian Boger fluid droplet phase by taking into account stresses that arise in the Boger fluids. The adapted model and the Newtonian CV-model were compared to the experimental results of FT-LAOS for checking the predictability of the model against the rheological properties. The adapted model shows some reasonable qualitative and quantitative agreements at high strain amplitude values.

Loss Factor Behavior of Thermally Aged Magnetorheological Elastomers

Polymer composites have been widely used as damping materials in various applications due to the ability of reducing the vibrations. However, the environmental and surrounding thermal exposure towards polymer composites have affected their mechanical properties and lifecycle. Therefore, this paper presents the effect of material-temperature dependence on the loss factor and phase shift angle characteristics. Two types of unageing and aging silicone-rubber-based magnetorheological elastomer (SR-MRE) with different concentrations of carbonyl iron particles (CIPs), 30 and 60 wt%, are utilized in this study. The morphological, magnetic, and rheological properties related to the loss factor and phase shift angle are characterized using a low-vacuum scanning electron microscopy, and vibrating sample magnetometer and rheometer, respectively. The morphological analysis of SR-MRE consisting of 30 wt% CIPs revealed a smoother surface area when compared to 60 wt% CIPs after thermal aging due to the improvement of CIPs dispersion in the presence of heat. Nevertheless, the rheological analysis demonstrated inimitable rheological properties due to different in-rubber structures, shear deformation condition, as well as the influence of magnetic field. No significant changes of loss factor occurred at a low CIPs concentration, whilst the loss factor increased at a higher CIPs concentration. On that basis, it has been determined that the proposed changes of the polymer chain network due to the long-term temperature exposure of different concentrations of CIPs might explain the unique rheological properties of the unaged and aged SR-MRE.

INFLUENCE OF CREEP CONCRETE ON SPACE STABILITY THIN-WALLED DOME COVERINGS

The task was set, due to the capabilities of modern software systems, to assess the effect of the increase in inelastic deformations under prolonged load action on the loss of stability of thin-walled dome coverings. The study of the dependences of the forms of the loss of stability of dome covering from creep concrete that will help further with optimization calculations when determining of the most influencing parameters of designs. Calculation results of thin-walled concrete dome roof of circular outline under the influence of operational loadings with use of two modern program complexes are given in article. It is investigated intense and deformation condition of dome coverings as a part of construction from position of forecasting of possible forms of loss of stability, with use of opportunities of the final and element «MidasCivil» computer system. In work provisions of the theory of elasticity, mechanics of deformation of solid body, construction mechanics and also methods of mathematical modeling based on application of finite element method are used. The received results give the chance to rationally select geometrical parameters and material of design and also to set structural strength safety factors at the solution of problems of stability of different covers taking into account possible creep of material.

Strengthening of Precast RC Frame to Mitigate Progressive Collapse by Externally Anchored Carbon Fiber Ropes

The robustness of precast reinforced concrete (RC) frames is relatively poor, while the precast RC frames are strengthened to mitigate progressive collapse, avoiding “strong beams and weak columns” and the anchorage failure of strengthening materials under large deformation condition are the key problems. Aiming to discuss these problems, this paper carried out an experimental research of strengthening on three half-scale assembled monolithic frame subassemblages to mitigate progressive collapse. One specimen was strengthened by implanting carbon fiber rope (CFR) with polymer into concrete, one specimen was strengthened by binding CFR with special knot, and the last one was not strengthened. The failure mode, collapse failure mechanism and strengthening effect of subassemblages were discussed. Analytical models of load capacity increment contributed by CFR and construction suggestions of precast RC frame to mitigate progressive collapse were proposed. The results indicated that none of the strengthened specimens had anchorage failure. The two strengthening methods significantly increased the load capacity of the subassemblages in the catenary action (CA) stage with little effect on the flexural action (FA) stage and compressive arch action (CAA) stage.

High Temperature Behaviors of a Casting Nickel-Based Superalloy Used for 815 °C

The hot deformation behaviors of the SJTU-1 alloy, the high-throughput scanned casting Nickel-based superalloy, was investigated by compression test in the temperature range of 900 to 1200 °C and strain rate range of 0.1–0.001 s−1. The hot processing map has been constructed with the instability zone. At the beginning of hot deformation, the flow stress moves rapidly to the peak value with the increased strain rates. Meanwhile, the peak stress is decreased with the increased temperature at the same strain rates. However, the peak stress shows the same tendency with the strain rates at the same temperature. The optimum hot deformation condition was determined in the temperature range of 1000–1075 °C, and the strain rate range of 0.005–0.1 s−1. The microstructure investigation indicates the strain rate significantly affects the characteristics of the microstructure. The deformation constitutive equation has also been discussed as well.

Effect of Equal Channel Angular Pressing on the Dynamic Softening Behavior of Ti-6Al-4V Alloy in the Hot Deformation Process

To investigate the effect of equal channel angular pressing (ECAP) on the deformation of Ti-6Al-4V alloy at a higher temperature, hot compression tests were conducted on alloys having two different initial microstructures (the original alloy (Pre-ECAP) and ECAP-deformed alloy (Post-ECAP)). Post-ECAP, the alloy showed a higher degree of dynamic softening during the hot deformation process due to its finer grain size and higher distortion energy. The flow stress of Post-ECAP alloy was higher than the Pre-ECAP alloy at 500 °C when ε˙= 0.003 s−1. However, the stress of the Post-ECAP alloy decreased rapidly with increasing temperature and strain rate, until the stress value was much lower than that of Pre-ECAP at 700 °C when ε˙= 0.03 s−1. The value of the dynamic softening coefficient revealed that the dynamic softening behavior of Post-ECAP was more pronounced than that of Pre-ECAP in the hot compression deformation process. The main dynamic softening mechanism of Pre-ECAP is dynamic recovery, while the dynamic recrystallization process plays a more important role in the deformation process of Post-ECAP alloy. The microstructures observation results showed that dynamic recrystallization was more likely to occur to Post-ECAP alloys under the same deformation condition. Almost fully dynamic recrystallization had occurred in the deformation process of Post-ECAP at 700 °C and a strain rate of ε˙= 0.01 s−1. The grains of Post-ECAP alloys were further refined. The Post-ECAP alloy exhibits better plastic deformation at temperatures higher than 600 °C due to its significant dynamic recrystallization.

Microstructural evolution of amphibolite-eclogite facies quartz veins under low greenschist facies deformation condition

<p>Quartz veins in poly-metamorphic settings often accommodate the latest deformation state and therefore can provide important information. Identification of microfabric (microstructure and crystallographic preferred orientation, CPO) evolution of quartz during mylonitization, and especially of the grain-scale interplay between brittle and crystal-plastic processes, has different relevant implications: e.g., on understanding the efficiency of fluid mobility through deforming quartz that can dramatically influence the rheology and the degree of chemical exchange. However, in order to interpret the microstructure and the related deformation processes it is necessary to relate these especially to the deformation temperature. Particularly the CPO and the Ti-in-qtz geothermometry is used to constrain the deformation temperature. However, both methods have to be applied with great caution because even when many times used some fundamental processes are not fully understood yet.</p><p> </p><p>Here we present results from deformed quartz veins from the Prijakt Nappe (Autroalpine Unit, Schober Mountains, Central Eastern Alps). These veins localized ductile shear and eventually seismic faulting (recorded by the occurrence of pseudotachylytes) within Eo-Alpine eclogite-facies shists. The veins formed shortly after the eclogitic peak, but the temperature of their deformation remains unconstrained. CL imaging reveals critical details for understanding the role of microfracturing and fluid-rock interaction during initial stages of shear localization, the onset of dynamic recrystallization and the resetting of the Ti-in-quartz geochemistry. Even when optical-light-microscopy and EBSD analysis indicate crystal plastic deformation by subgrain rotation CL and orientation contrast (OC) imaging gives evidence of brittle stage of deformation at least for some of the deformation microstructure. Microshear zones show a bulk dark-CL, but still bright tones in cores of new recrystallized grains similar to the CL signature of the host coarse quartz crystals. CL dark tones also match with the pattern of subgrain boundaries. This reflects fluid permeability pathways along subgrain and grain boundaries (identified by widespread fluid inclusions) and the associated partial resetting of Ti concentrations. The CPO of the new grains within the micro-shear zones rotate with the sense of shear around the kinematic Y-axis and cannot be related to the activity of specific slip systems. In contrast the partial single girdle of c-axis within the ultramylonite with its elongated substructured grains and its characteristic layered microstructure can be related to the activity of several slip systems. Misorientation axis analysis indicates that prism</p><p> </p><p> </p><p> </p>

Effect of 0.8 at.% H on the Mechanical Properties and Microstructure Evolution of a Ti–45Al–9Nb Alloy Under Uniaxial Tension at High Temperature

To investigate the effect of hydrogen on the high-temperature deformation behaviors of TiAl-based alloys, the high-temperature tensile experiment was carried out on a Ti–45Al–9Nb (at.%) alloy with the H content of 0 and 0.8 at.%, respectively. Then, the effect of hydrogen on the high-temperature mechanical properties of the as-cast alloy was studied, the constitutive relations among stress, temperature, and strain rate were established, and the microstructure was analyzed. The results indicated that, compared with the unhydrogenated alloy, the flow stress of the hydrogenated alloy was significantly reduced, and the peak stress of the hydrogenated alloy decreased by (16.28 ± 0.17)% deformed at 1150 °C/0.0004 s−1. Due to the presence of hydride (TiAl)Hx in the alloy, the elongation showed a decline trend with increasing strain rate at the same deformation temperature. Compared with the unhydrogenated alloy, the elongation of the hydrogenated alloy reduced by (26.05 ± 0.45)% (0.0004 s−1), (23.49 ± 0.38)% (0.001 s−1), and (14.23 ± 0.19)% (0.0025 s−1), respectively, indicating that 0.8 at.% H softened the Ti–45Al–9Nb alloy and reduced the high-temperature plastic deformability. Under the same deformation condition, the deformation extent of the hydrogenated alloy was less than that of the unhydrogenated alloy. There were more residual lamellae in the hydrogenated alloy, and the extent of dynamic recrystallization was lower than that of the unhydrogenated alloy.

DYNAMIC COMPRESSIBILITY OF BIRCH AT DIFFERENT TYPES OF STRESS-STRAINED STATE

The results of dynamic tests for compression across the fibers at room temperature of birch samples with air humidity are presented. Dynamic tests were carried out on a setup with a split Hopkinson bar according to the Kolsky method at a strain rate of ~2000 s–1. To assess the effect of the type of stress-strain state on the behavior of the material, in addition to specimens in the form of cylinders with its free expansion during loading (uniaxial stress state condition), specimens were tested in a rigid casing that prevents the radial expansion of the specimen (uniaxial deformation condition), as well as local compressive tests of rectangular board fragments. In the latter case, the material surrounding the loading zone plays the role of a compliant confining casing. In this case, a certain intermediate stress-strain state is realized in the sample. For these three types of stress-strain state, dynamic deformation diagrams were obtained with registration of additional loading cycles. Comparison of obtained deformation diagrams shows a significant effect of the type of stress-strain state on the behavior of the material under study. In the case of free expansion of the specimen in the radial direction, the absence of strain hardening is observed in the first loading cycle. In subsequent cycles, hardening is negligible. The deformation diagrams of specimens in the casing as well as board fragments are characterized by a noticeable increase in the modulus of the hardening branch with increasing deformation. In this case, it can be noted that the behavior of the material in the case of testing a piece of board is intermediate between the cases of uniaxial stress state and uniaxial strain state. Some mechanical characteristics of the material are determined using the diagrams obtained. The obtained experimental results can serve as the basis for the subsequent identification of the model of deformation and destruction of wood.