Thermal history modelling of the western margin of the Bohemian Massif using high-resolution apatite fission-track thermochronology

Author(s):  
Lucie Novakova ◽  
Raymond Jonckheere ◽  
Bastian Wauschkuhn ◽  
Lothar Ratchbacher

<p>The Naab area is situated on the western border of the Bohemian Massif, 60 km south of the KTB (Kontinentalen Tiefbohrung). The main super-deep borehole of the KTB reached a depth of 9,101 meters in the Earth's continental crust. The fission-track data for the KTB and the Naab area present contrasting signatures. The apatite fission-track ages in the upper section of the KTB borehole and surrounding area are in the range 50-70 Ma (Wagner et al., 1994; Wauschkuhn et al., 2015). The apatite fission-track ages of the Naab basement are older than those of the KTB area, and span a broader range: 120-200 Ma (Vercoutere, 1994). The distributions of the confined-track lengths range from unimodal over skewed and mixed to bimodal, with mean lengths in the range 11-13 µm. In broad terms, this can be interpreted as that the Naab samples contain both an older and younger (in particular pre- and post-late Cretaceous) fission-track population. The aim of our research is to investigate the applicability of lab-based models to geological data, using improved measurement techniques.</p><p>We studied eighteen samples dated by Vercoutere (1994) from the Palaeozoic basement and seven large rock samples from the Rotliegend strata north of the Luhe fault.  We intend to extend the confined-track length measurements of Vercoutere (1994), aiming to achieve higher resolution through methodological innovations made possible by computer-controlled motorized microscopes. Improved statistics increase the resolution of the modelled thermal histories, which permits to better distinguish systematic from statistical differences between the modelled palaeotemperatures and geological estimates. Experiments have shown that the rate of length increase permits to distinguish older from younger tracks (Jonckheere et al., 2017). This allows us to distinguish between tracks formed before and after the Late Cre­taceous to Palaeocene exhumation. The etch rate of a confined track is also an indicator of its individual thermal history, supplementing the information gleaned from its etchable length under fixed conditions. We compiled a comprehensive, high-resolution confined-track-length dataset. The Naab thermal histories were determined using modern modelling algorithms, implementing the most recent empirical equations.</p><p><strong>References</strong></p><p>Jonckheere R., Tamer M., Wauschkuhn F., Wauschkuhn B., Ratschbacher L., 2017. Single-track length measurements of step-etched fission tracks in Durango apatite: Vorsprung durch Technik.American Mineralogist 102, 987-996.</p><p>Vercoutere C., 1994. The thermotectonic history of the Brabant Massif (Belgium) and the Naab Basement (Germany):   an apatite fission track analysis. Ph. D. thesis, Universiteit Gent, pp. 191.</p><p>Wagner G.A., Hejl E., Van Den Haute P., 1994. The KTB fission-track project: Methodical aspects and geological implications. Radiation Measurements 23, 95-101.</p><p>Wauschkuhn B., Jonckheere R., Ratschbacher L., 2015. The KTB apatite fission-track profiles: building on a firm foundation? Geochimica et Cosmochimica Acta 167, 27-62.</p>

2021 ◽  
Author(s):  
Jennifer Spalding ◽  
Jeremy Powell ◽  
David Schneider ◽  
Karen Fallas

<p>Resolving the thermal history of sedimentary basins through geological time is essential when evaluating the maturity of source rocks within petroleum systems. Traditional methods used to estimate maximum burial temperatures in prospective sedimentary basin such as and vitrinite reflectance (%Ro) are unable to constrain the timing and duration of thermal events. In comparison, low-temperature thermochronology methods, such as apatite fission track thermochronology (AFT), can resolve detailed thermal histories within a temperature range corresponding to oil and gas generation. In the Peel Plateau of the Northwest Territories, Canada, Phanerozoic sedimentary strata exhibit oil-stained outcrops, gas seeps, and bitumen occurrences. Presently, the timing of hydrocarbon maturation events are poorly constrained, as a regional unconformity at the base of Cretaceous foreland basin strata indicates that underlying Devonian source rocks may have undergone a burial and unroofing event prior to the Cretaceous. Published organic thermal maturity values from wells within the study area range from 1.59 and 2.46 %Ro for Devonian strata and 0.54 and 1.83 %Ro within Lower Cretaceous strata. Herein, we have resolved the thermal history of the Peel Plateau through multi-kinetic AFT thermochronology. Three samples from Upper Devonian, Lower Cretaceous and Upper Cretaceous strata have pooled AFT ages of 61.0 ± 5.1 Ma, 59.5 ± 5.2 and 101.6 ± 6.7 Ma, respectively, and corresponding U-Pb ages of 497.4 ± 17.5 Ma (MSWD: 7.4), 353.5 ± 13.5 Ma (MSWD: 3.1) and 261.2 ± 8.5 Ma (MSWD: 5.9). All AFT data fail the χ<sup>2</sup> test, suggesting AFT ages do not comprise a single statistically significant population, whereas U-Pb ages reflect the pre-depositional history of the samples and are likely from various provenances. Apatite chemistry is known to control the temperature and rates at which fission tracks undergo thermal annealing. The r<sub>mro</sub> parameter uses grain specific chemistry to predict apatite’s kinetic behaviour and is used to identify kinetic populations within samples. Grain chemistry was measured via electron microprobe analysis to derive r<sub>mro</sub> values and each sample was separated into two kinetic populations that pass the χ<sup>2</sup> test: a less retentive population with ages ranging from 49.3 ± 9.3 Ma to 36.4 ± 4.7 Ma, and a more retentive population with ages ranging from 157.7 ± 19 Ma to 103.3 ± 11.8 Ma, with r<sub>mr0</sub> benchmarks ranging from 0.79 and 0.82. Thermal history models reveal Devonian strata reached maximum burial temperatures (~165°C-185°C) prior to late Paleozoic to Mesozoic unroofing, and reheated to lower temperatures (~75°C-110°C) in the Late Cretaceous to Paleogene. Both Cretaceous samples record maximum burial temperatures (75°C-95°C) also during the Late Cretaceous to Paleogene. These new data indicate that Devonian source rocks matured prior to deposition of Cretaceous strata and that subsequent burial and heating during the Cretaceous to Paleogene was limited to the low-temperature threshold of the oil window. Integrating multi-kinetic AFT data with traditional methods in petroleum geosciences can help unravel complex thermal histories of sedimentary basins. Applying these methods elsewhere can improve the characterisation of petroleum systems.</p>


1993 ◽  
Vol 103 (1-4) ◽  
pp. 157-169
Author(s):  
M. Grivet ◽  
M. Rebetez ◽  
N. Ben Ghouma ◽  
A. Chambaudet ◽  
R. Jonckheere ◽  
...  

1992 ◽  
Vol 29 (5) ◽  
pp. 909-924 ◽  
Author(s):  
A. M. Grist ◽  
P. H. Reynolds ◽  
M. Zentilli ◽  
C. Beaumont

Apatite fission track and 40Ar/39Ar age spectrum data from sandstone drill-core minerals taken from depths of 2–5 km in nine wells from the Scotian Basin are presented and interpreted in terms of the thermal history of the basin and the provenance of its sediments. The focus of the study is a comparison of the data from these thermochronometers with each other and with previously published vitrinite reflectance and aromatization–isomerization (A–I) reactions in biomarker compounds from the same or nearby wells.Apatite fission track ages are generally in agreement with expectations in that they trend to zero at a depth of ~4 km (corrected bottom-hole temperature ~120 °C). Shallower (lower present temperature) samples are partially annealed; the degree of partial annealing correlates closely with the degree of A–I reactions. Both thermal indicators are activated over the temperature range 60–120 °C.Samples from two wells, Mic Mac J-77 and Erie D-26, are anomalous. They are more annealed than present formation temperatures would predict, an anomaly that is also indicated by the A–I data. These samples are interpreted as having experienced higher than present temperatures subsequent to deposition, possibly resulting from the passage of hot fluids related to localized volcanism or the sudden venting of an overpressured reservoir.K-feldspars record minor (< 20%) argon loss as a result of burial heating in the basin only at the greatest depths of the sampled range (> 4.3 km). This result is in agreement with the thermal models of the Scotian Basin and extrapolation of the A–I and fission track data to greater depths. The inferred argon loss implies an activation energy of 40 ± 4 kcal/mol for the smallest diffusion domains.The argon age spectra for samples that have not lost argon during residence in the basin provide evidence on the provenance of the sediments. K-feldspars from the Early Cretaceous Missisauga Formation have spectra that are similar to those obtained from K-feldspars from the Grenville Province of the Canadian Shield, whereas muscovites from the same formation give Cambrian to Carboniferous argon ages (mean 387 Ma), an indication of contributions from other source rocks. Corresponding data from the Jurassic Mohican Formation are similar to those reported for plutons from the southern Nova Scotia mainland (ca. 250–350 Ma argon ages). By implication, the Mohican Formation, which is the earliest postrift deposit, was derived from local sources inferred to be adjacent flank uplifts, whereas the Missisauga Formation was derived in part either directly or indirectly from the Grenvillian-aged interior of eastern Canada.


2009 ◽  
Vol 284 (3-4) ◽  
pp. 504-515 ◽  
Author(s):  
Richard A. Ketcham ◽  
Raymond A. Donelick ◽  
Maria Laura Balestrieri ◽  
Massimiliano Zattin

1990 ◽  
Vol 27 (8) ◽  
pp. 1013-1022 ◽  
Author(s):  
Dennis C. Arne ◽  
Ian R. Duddy ◽  
Don F. Sangster

Fission tracks in detrital apatites from the Cambro-Ordovician metasedimentary basement in the vicinity of the Carboniferous-hosted Gays River Pb–Zn deposit, Nova Scotia, provide a record of final cooling during uplift and erosion of the Meguma Zone and constrain the timing of ore formation. Apatite fission track ages range from 203 to 241 Ma, with typical uncertainties of ± 10 Ma. Mean confined track lengths generally vary between 12.0 and 13.4 μm and indicate that the apatites record "apparent" ages only. An inferred thermal history involving regional heating to paleotemperatures > 110 °C during late Paleozoic burial followed by cooling to ~ 110 °C prior to 240–220 Ma is suggested. A more recent phase or regional heating to paleotem-peratures probably in the range of 60–80 °C during Late Cretaceous – early Tertiary (ca. 100–50 Ma) burial is also indicated by the track length data. Apatite fission track ages and mean track lengths from drill-core samples immediately beneath the Gays River orebody are similar to those for regional outcrop samples. At minimum temperatures > 200 °C estimated for ore formation, sulphide mineralization must either have preceded or accompanied regional heating to paleotemperatures > 110 °C during the late Paleozoic. Sulphide mineralization at Gays River must therefore have taken place at some time after ca. 330 Ma (the stratigraphic age of the lower Windsor Group host rocks) but before ca. 240–220 Ma (the last cooling of Meguma Group basement below 110 °C). These constraints on the timing of ore formation at Gays River are compatible with previous suggestions that Pb–Zn mineralization of Carboniferous strata in Nova Scotia occurred at ca. 300 Ma.


2021 ◽  
Author(s):  
Dale R. Issler ◽  
Kalin T. McDannell ◽  
Paul B. O'Sullivan ◽  
Larry S. Lane

Abstract. Compositionally dependent apatite fission track (AFT) annealing is a common but underappreciated cause for age dispersion in detrital AFT samples. We present an interpretation and modelling strategy that exploits multikinetic AFT annealing to obtain thermal histories that can provide more detail and better resolution compared to conventional methods. We illustrate our method using a Permian and a Devonian sample from the Yukon, Canada, both with complicated geological histories and long residence times in the AFT partial annealing zone. Effective Cl values (eCl; converted from rmr0 values), derived from detailed apatite elemental data, are used to define AFT statistical kinetic populations with significantly different total annealing temperatures (~110–245 °C) and ages that agree closely with the results of age mixture modelling. These AFT populations are well-resolved using eCl values but exhibit significant overlap with respect to the conventional parameters, Cl content or Dpar. Elemental analyses and measured Dpar for Phanerozoic samples from the Yukon and Northwest Territories confirm that Dpar has low precision and that Cl content alone cannot account for the compositional and associated kinetic variability observed in natural samples. An inverse multikinetic AFT model, AFTINV, is used to obtain thermal history information by simultaneously modelling multiple kinetic populations as distinct thermochronometers with different temperature sensitivities. A nondirected Monte Carlo scheme generates a set of statistically acceptable solutions at the 0.05 significance level and then these solutions are updated to the 0.5 level using a controlled random search (CRS) learning algorithm. The smoother, closer-fitting CRS solutions allow for a more consistent assessment of the eCl values and thermal history styles that are needed to satisfy the AFT data. The high-quality Devonian sample (39 single grain ages and 202 track lengths) has two kinetic populations that require three cycles of heating and cooling (each subsequent event of lower intensity) to obtain close-fitting solutions. The younger and more westerly Permian sample with three kinetic populations only records the latter two heating events. These results are compatible with known stratigraphic and thermal maturity constraints and the QTQt software produces similar results. Model results for these and other samples suggest that elemental-derived eCl values are accurate within the range, 0–0.25 apfu (rmr0 values of 0.73–0.84), which encompasses most of the data from annealing experiments. Outside of this range, eCl values for more exotic compositions may require adjustment relative to better constrained apatite compositions when trying to fit multiple kinetic populations. Our results for natural and synthetic samples suggest that an element-based multikinetic approach has great potential to increase the temperature range and resolution of thermal histories dramatically relative to conventional AFT thermochronology.


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