The Source of Fracture-Cave Mud Fillings of the Ordovician Yingshan Formation and Its Paleokarst Environment in the Northern Slope of the Tazhong Uplift, Tarim Basin, China: Based on Petrology and Geochemical Analysis

The karst fracture-cave oil and gas reservoirs of the Yingshan Formation in the northern slope of the Tazhong Uplift are well developed and have achieved good exploration results. However, the karst fracture-cave near the top of the Yingshan Formation is basically filled with mud fillings, which seriously affect the reservoir property, and the source and filling environment of the mud fillings have been unclear. Through the petrological and geochemical analysis of the fracture-cave fillings system in the typical wells of the Yingshan Formation, it has been found that (1) the fracture-cave fillings are mainly composed of a mixture of the bedrock dissolution dissociation particles, clay minerals, and calcite cements of the Yingshan Formation, and the content of each component in the different wells or in the cave interval is quite different. (2) Rare earth element analysis shows that the rare earth distribution pattern of the fracture-cave fillings is similar to the bottom marlstone of the Lianglitage Formation, indicating that the fracture-cave fillings should be mainly derived from the early seawater of the deposition during the Lianglitage Formation. (3) Cathodoluminescence, trace element analysis, and previous studies have shown that the formation and fillings of the fractures and caves mainly occurred in the hypergene period, which had the characteristics of an oxidized environment, and that there are two filling effects. First, the limestone of the Yingshan Formation experienced the formation of karst caves due to meteoric freshwater dissolution during the exposure period, and the limestone of the Yingshan Formation was dissolved, resulting in some insoluble clay and residual limestone gravel particles brought into the cave by the meteoric freshwater for filling. Second, the seawater transgression also played an important role during the deposition of the Lianglitage Formation. The clay content in the seawater was high during the early deposition of the Lianglitage Formation, which led to the clay being brought into the caves by the seawater during the deposition of the Lianglitage Formation for further filling; at the same time, calcite deposited into the caves with the clay. The above research promotes the study of the formation mechanism of the karst cave reservoir in the Yingshan Formation and has important theoretical significance for the guiding of the next oil and gas exploration in this area.

Variability and Main Controlling Factors of Hydrocarbon Migration and Accumulation in the Lower Paleozoic Carbonate Rocks of the Tazhong Uplift, the Tarim Basin, Northwest China

Hydrocarbon migration patterns and pathways were studied on the basis of three-dimensional seismic interpretation, drilling, geochemistry, production performance, and other data. Using these findings, the main factors controlling hydrocarbon migration and accumulation in the Lower Paleozoic carbonate rocks of the Tazhong Uplift were discussed. The spatiotemporal relationship between the hydrocarbon kitchens and pathway systems of the Tazhong Uplift and the spatial pattern of pathway systems were considered the main factors causing differences in hydrocarbon enrichment. Results also revealed that the Lower Paleozoic carbonates of the Tazhong Uplift have two hydrocarbon accumulation systems (inside and outside the source rocks). For the accumulation system within the source rocks, hydrocarbon migration and enrichment are vertically differentiated. Middle Cambrian gypsum salt rocks serve as the boundary, above which thrust and strike-slip faults mainly allow vertical transport of hydrocarbons. A multistage superposition pattern of strike-slip faults controls the differences in hydrocarbon enrichment on the periphery of the fault zone. Beneath the gypsum-salt rocks, hydrocarbon migration and enrichment is controlled by the topography of paleostructures and paleogeomorphology. For the hydrocarbon accumulation system outside the source rocks, hydrocarbon migration and enrichment are restricted by the layered pathway system, and the topography of the paleostructures and paleogeomorphology is the key factor controlling hydrocarbon enrichment. The Tazhong No. 1 Fault is the main vertical pathway system in the area underlain by no source rocks, and hydrocarbons are enriched at the periphery of the Middle-Lower Cambrian and No. 1 Fault Zone.

Experimental study on brine-CO2-rock interaction in carbonate formations of Tazhong-Uplift, Tarim Basin China

<p>Abstract: CO<sub>2</sub> storage in saline aquifers is one of the most effective ways of geological carbon sequestration. In order to better understand brine-CO<sub>2</sub>-rock interaction in carbonate reservoirs, 4 series of autoclave experiments with the carbonate rock powder samples with injection of super critical CO<sub>2</sub> have been performed. Two core samples were collected from the TC1well at the depth of 4030m (Lianglitage Formation) and 5100m (Qiulitage Formation), and another two samples from corresponding formation  and with varing mineral content were collected from the Yijianfang outcrop and Xiaoerbulake outcrop in Tazhong-Uplift, Tarim Basin, China. The experimental conditions simulate the environment of the reservoir around 4000m depth at the Tazhong Uplift with 25Mpa and 120 degree, where the brine water is CaCl<sub>2</sub> type with TDS equal to 135g/l. The FESEM,EDS, XRD, ICP-OES analysis have been performed to examine the mineral chemical composition, morphology and water solution change. The results show that, in all cases after the injection of CO<sub>2</sub>, with CO<sub>2</sub> dissolution, pH shows a decrease at the beginning days of the experiments and start to rise, becomes stable at the end of the experiment. Where as, with the dissolution of the minerals results in continuous increase in electrical conductivity. The SEM analysis demonstrates the dissolution of the calcite and dolomite resulted in a rough surface structure and the sharp edges of calcite and dolomite are dissolved. Also, it is able to observe the formations of new micropores and formation of secondary minerals such as ankerite. In the fluid analysis, Ca<sup>2+</sup> is the dominant dissolved cation and originated from calcite and dolomite dissolution. The concentration of Ca<sup>2+</sup>will first increase sharply and then decreases, whereas concentration of Mg<sup>2+ </sup>will increase slowly, which means calcite dissolution take places faster than dolomite dissolution. Numerical modeling has been applied to validate the experimental observations with corrected reaction rate. These results can be used for numerical calculation of mineral trapping over long period. This study is helpful for implementation of carbon sequestration plan in Tarim Basin, China.</p>