Nowadays along with the rapid development of industrialization across the globe, the environmental and ecological impacts of products have become a serious issue. Taking into account purely the economic impacts of industrial decisions, and excluding their ecological impacts, make the human beings and animals more at risk to many threats such as global warming, ozone layer depletion, toxic environments, and natural resources depletion. To minimize the environmental effect, implementation of green supply chain management (GSCM) is much more essential for industries in the environmental and social point of view. The purpose of this chapter is to analyze barriers to an implementation of green supply chain management in a stone crushing plant of Southern India by using modified simple additive weighting (SAW) to rank approaches. Further, this study will help the small-scale industries to understand the factors affecting implementation of GSCM in their organizations.