Bearing of Isotopic Composition of Contained Lead on the Genesis of Mississippi Valley Ore Deposits

Author(s):  
Edwin T. McKnight
Geosciences ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 172
Author(s):  
Jonathan Chick ◽  
Sydney E. McKim ◽  
Adriana Potra ◽  
Walter L. Manger ◽  
John R. Samuelsen

Southern Ozark Mississippi Valley-type ores are enriched in radiogenic Pb, with isotopic signatures suggesting that metals were supplied by two end-member components. While the less radiogenic component appears to be derived from various shale and sandstone units, the source of the more radiogenic component has not yet been identified. Analyses of cherts from the Early Ordovician Cotter Dolomite and tripolitic chert from the Early Mississippian Boone Formation contain highly radiogenic Pb, with isotopic ratios comparable to those of ores. However, most samples have lower 208Pb/204Pb and 207Pb/204Pb for a given 206Pb/204Pb compared to ores. These relationships demonstrate that the enriched Pb isotopic values of the ore array cannot be related to the host and regional lithologies sampled, suggesting that the source of high ratios may lay further afield. The slope of the linear trend defined by the Pb isotope ratios of ores corresponds to an age of about 1.19 Ga. Therefore, an alternative for the linear array is the involvement of Precambrian basement in supplying ore Pb. Rare earth element patterns show that diagenetic processes involving the action of groundwater and hydrothermal fluids affected the sampled lithologies to various degrees, with Cotter Dolomite having experienced the highest degree of alteration.


1996 ◽  
Vol 33 (10) ◽  
pp. 1363-1374 ◽  
Author(s):  
M. Bouadellah ◽  
A. C. Brown ◽  
Y. Héroux

Reflectance measurements and organic petrography were used to study altered organic matter in the dolomitic Middle Jurassic Beddiane sequence hosting the Beddiane lead–zinc deposit. Organic matter occurs in the lower dolostone units of the formation where zinc sulfide mineralization prevails. The upper units, where lead sulfide mineralization is dominant, contain lesser amounts of organic matter. The organic matter in the Beddiane sequence consists of macerals, amorphous kerogen, and solid bitumen, inertinite and vitrinite are ubiquitous. The amount of exinite increases toward mineralized areas but the ratio exinite/kerogen remains constant. Two types of vitrinite are considered on the basis of their reflectance: Vt1 with low reflectance values (0.3–0.5%) and Vt2 with higher values (0.7–1.25%). The ratio Vt1/Vt2 increases and the reflectance values for Vt1 decrease toward the zinc-prevailing units, Organic matter associated with the mineralization exhibits features such as oxidation halos and desiccation cracks, together with a low-fluorescent exinite. The association of the kerogen content, the trend in reflectance values, and the alteration features of the Mississippi Valley-type Beddiane deposit support the hypothesis that the regional flow of hot brines associated with the mineralization process was the cause of anomalous heating, that the occurrence of exinite maceral and its associated gas played a role in the ore deposition, and that the new chemical equilibrium reached by the zinc-dominant host rock after ore deposition is responsible for the suppressed reflectance values within and near the ore deposits.


2018 ◽  
Vol 769 ◽  
pp. 227-232
Author(s):  
Nataliya Rusinova ◽  
Vasilii Ivanovich Leontev

This work presents the results of an analysis of the sulfur isotopic composition of pyrites from different metasomatic rocks of the Samolazovskoe and Podgolechnoe (Central Aldan ore district) deposits. The sulfur isotopic ratio of pyrite from ore-bearing metasomatic rocks of the Podgolechnoe deposit is characterized by δ34S values varying in a range from –1.8 to –5.5 ‰; that of pyrite from the Samolazovskoe deposit is in a range from –6.9 to –12.3‰. This is in agreement with the suggestion that a magmatic source made a significant contribution to the formation of the ore-forming fluid.


1974 ◽  
Vol 11 (2) ◽  
pp. 211-223 ◽  
Author(s):  
F. W. Beales ◽  
J. C. Carracedo ◽  
D. W. Strangway

Paleomagnetism can provide useful information about the stratigraphic relationships between the host rocks and the ore of some ore deposits.Four North American mines with stratabound ore deposits of Mississippi Valley type were sampled and the direction and intensity of the natural remanent magnetization (NRM) were measured. Two of the sites sampled (Newfoundland Zinc Co. property near Daniel's Harbour in western Newfoundland and the St. Joe Minerals Co., #8 Mine in southeast Missouri) had a weak, but measurable NRM in both host and ore rocks. This magnetization proved to be highly stable upon alternating field (AF) demagnetization. The other two mines (Magmont Mine, southeast Missouri, and Pine Point Mine, Northwest Territories, Canada) had intensities of magnetization too low to be measured after demagnetization.The pole positions computed for the ores and their corresponding hosts are identical within the statistical uncertainty, strongly suggesting that the ore and the host are, geologically speaking, of roughly the same age. This study gives two reliable pole positions, one for late lower Ordovician dolostone and sphalerite ore from Newfoundland of 26 °N, 126 °E, and the other for the upper Cambrian, based on the Bonneterre dolostone and galena ore from southeast Missouri of 35 °S, 170 °W.Within the present limitations of the method the results agree with published opinions concerning the age of the ore, i.e. that host rock and ore formation were relatively close in time. Therefore, when significant time differences occur between epigenetic ores and their host rocks, the method may be expected to define this. The method will become progressively more valuable as the apparent polar wandering curves for various continental areas become better defined.


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