Nickel Laterites: A Review

SEG Discovery ◽  
2003 ◽  
pp. 1-18
Author(s):  
S.A. Gleeson ◽  
C.R.M. Butt ◽  
M. Elias

ABSTRACT Nickel laterite deposits are formed by the prolonged and pervasive weathering of Ni silicate-bearing ultramafıc rocks, generally in tropical to subtropical climates. The deposits can be further classifıed as hydrous silicate deposits (e.g., SLN Operations, New Caledonia), clay silicate deposits (e.g., Murrin Murrin, Australia), and oxide deposits (e.g., Moa Bay, Cuba; Cawse, Australia) on the basis of the ore mineralogy. The physical and chemical nature of a nickel laterite deposit is a function of many factors, including the composition of the parent rock, the tectonic setting, climate, topography (specifıcally, laterite morphology), and drainage. Nickel laterite ore is extracted using both selective and bulk mining methods in open cast mining operations. The mined ore has traditionally been processed either by hydrometallurgical leaching technology (pressure acid leach or Caron processes) to produce oxides of nickel and cobalt or mixed Ni-Co sulfıdes for market, or by pyrometallurgical smelting to produce ferronickel granules or nickel matte. However, recent advances in high-pressure acid leaching and continued testing of atmospheric leach technology should lead to a reduction in overall operating costs and increased exploitation of Ni laterite resources in the future.

2003 ◽  
Vol 70 (1-3) ◽  
pp. 31-46 ◽  
Author(s):  
B.I. Whittington ◽  
R.G. McDonald ◽  
J.A. Johnson ◽  
D.M. Muir

2017 ◽  
Vol 133 (4) ◽  
pp. 68-75
Author(s):  
Shinichi HEGURI ◽  
Hirofumi SHOJI ◽  
Isao NISHIKAWA ◽  
Hiroshi KOBAYASHI ◽  
Atsushi IDEGAMI

2005 ◽  
Vol 78 (3-4) ◽  
pp. 264-270 ◽  
Author(s):  
J.A. Johnson ◽  
R.G. McDonald ◽  
D.M. Muir ◽  
J.-P. Tranne

2003 ◽  
Vol 70 (1-3) ◽  
pp. 47-62 ◽  
Author(s):  
B.I. Whittington ◽  
J.A. Johnson ◽  
L.P. Quan ◽  
R.G. McDonald ◽  
D.M. Muir

2005 ◽  
Vol 38 (6) ◽  
pp. 927-933 ◽  
Author(s):  
Ian C. Madsen ◽  
Nicola V. Y. Scarlett ◽  
Barry I. Whittington

This paper outlines the use of an innovative system for thein situinvestigation of hydrothermal reactions by X-ray diffraction. The key features are the use of: (i) a purpose-built capillary reaction vessel which allows close emulation of the conditions present in mineral processing plants; (ii) MoKα radiation, to ensure that the X-ray beam penetrates through the capillary, and (iii) an Inel CPS120 position-sensitive detector, to enable simultaneous collection of a wide range (120° 2θ) of diffraction data. The pressure acid leaching (PAL) of nickel laterite ores is used to illustrate the capabilities of this system, with a particular focus on the PAL of saprolite in strong H2SO4at 493 K. Saprolitic ore, which largely consists of serpentine mineral phases [(Mg,Fe,Ni,Al)3(Si,Al)2O5(OH)4], undergoes a number of mineralogical changes during both the acid leaching reaction and subsequent cooling, thus making it difficult to examine accurately using traditional post-reactionex situtechniques. In particular, kieserite (MgSO4.H2O), which forms during leaching, has a negative temperature coefficient of solubility, causing it to dissolve on cooling. Thein situtechnique described in this paper allows the direct observation of kieserite formation during the saprolite PAL at 493 K and its dissolution upon cooling to ambient temperature.


2009 ◽  
Vol 99 (3-4) ◽  
pp. 189-193 ◽  
Author(s):  
Xiujing Zhai ◽  
Yan Fu ◽  
Xu Zhang ◽  
Linzhi Ma ◽  
Feng Xie

2008 ◽  
Vol 41 (3) ◽  
pp. 572-583 ◽  
Author(s):  
Nicola V. Y. Scarlett ◽  
Ian C. Madsen ◽  
Barry I. Whittington

This paper compares time-resolved diffraction experiments that have been performed using laboratory and synchrotron X-ray sources. The experiments investigated the mechanism and kinetics of pressure acid leaching of nickel laterite ores. The sample environment was a purpose-built capillary reaction vessel, and extensive method development was conducted in the laboratory using Mo Kα radiation prior to repeating and extending the experiments at the Daresbury Synchrotron Radiation Source, beamline MPW6.2. In general, the synchrotron results confirmed the findings from previously reported laboratory work and also confirmed the presence of a minor phase that had been ambiguous in the laboratory experiments,i.e.the formation of hematite in the pressure acid leaching of saprolite. The synchrotron measurements also extended the experimental programme to include poorly diffracting laterite components that could not be examined in the laboratory,e.g.nontronite. The results from these components supported the reaction mechanisms determined fromex-situanalyses conducted in larger scale autoclaves.


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