scholarly journals Theoretical Evaluation of Ultrasonic Velocities in Ternary Liquid Mixture of Tetrahydrofuran, Heptane and Decane at Different Temperatures

2015 ◽  
Keyword(s):  
Liquid Mixture ◽  
Ultrasonic Velocities ◽  
Theoretical Evaluation ◽  
Different Temperatures

Pressure-dependent study of ultrasonic velocity of benzene + nitrobenzene system at 293.15, 303.15, and 313.15 K

1989 ◽  
Vol 67 (3) ◽  
pp. 437-441 ◽  
Author(s):  
J. D. Pandey ◽  
R. D. Rai ◽  
R. K. Shukla
Keyword(s):  
Binary Mixtures ◽  
Ultrasonic Velocity ◽  
Liquid Mixture ◽  
Binary Liquid Mixture ◽  
Ultrasonic Velocities ◽  
Theoretical Evaluation ◽  
Binary Liquid ◽  
Elevated Pressures ◽  
Different Temperatures ◽  
Theory And Experiment

Various statistical and empirical theories of ultrasonic velocity have been applied to a binary liquid mixture (benzene + nitrobenzene) at elevated pressures and their validity have been tested. A pressure-dependent study of ultrasonic velocities has been made at three different temperatures (293.15, 303.15, and 313.15 K). The agreement between the theory and experiment is found to be satisfactory. Keywords: ultrasonic velocity, benzene + nitrobenzene, pressure dependent, theoretical evaluation, binary mixtures at elevated pressures.

scholarly journals Theoretical Evaluation of Ultrasonic Velocities of Binary Liquid Mixtures of 1-Bromopropane in Chlorobenzene at 303.15, 308.15, 313.15 and 318.15 K

2014 ◽  
Vol 30 ◽  
pp. 9-17
Author(s):  
Ch. Praveen Babu ◽  
G. Pavan Kumar ◽  
B. Nagarjun ◽  
K. Samatha
Keyword(s):  
Intermolecular Interactions ◽  
Theoretical Models ◽  
Liquid Mixtures ◽  
Binary Liquid Mixtures ◽  
Ultrasonic Velocities ◽  
Theoretical Evaluation ◽  
Binary Liquid ◽  
Different Temperatures ◽  
Experimental Values ◽  
Good Agreement

Theoretical velocities of binary liquid mixtures of 1-bromopropane with chlorobenzene at 2 MHz and four different temperatures 303.15, 308.15, 313.15 and 318.15 K, have been evaluated as a function of concentration and temperature. The experimental values are compared with theoretical models of liquid mixtures such as Nomoto, Van Dael-Vangeel, Impedance Relation, Rao’s Specific Velocity Method, Junjie’s relations and Free Length Theory. In the chosen system there is a good agreement between experimental and theoretical values calculated by Nomoto’s theory. The deviation in the variation of U2exp/U2imx from unity has also been evaluated for explaining the non ideality in the mixtures. The results are explained in terms of intermolecular interactions occurring in these binary liquid mixtures.

scholarly journals Experimental and Theoretical Evaluation of Ultrasonic Velocities of Binary Liquid Mixtures of Anisaldehyde and Toluene at Different Temperatures

2011 ◽  
Vol 8 (3) ◽  
pp. 977-981
Author(s):  
CH. Srinivasu ◽  
K. Narendra ◽  
CH. Kalpana
Keyword(s):  
Ultrasonic Velocity ◽  
Theoretical Models ◽  
Liquid Mixtures ◽  
Binary Liquid Mixtures ◽  
Ultrasonic Velocities ◽  
Theoretical Evaluation ◽  
Binary Liquid ◽  
Different Temperatures ◽  
Experimental Values ◽  
Good Agreement

Theoretical velocities of binary liquid mixtures of anisaldehyde with toluene at 303.15, 308.15, 313.15 and 318.15 K have been evaluated by using theoretical models of liquid mixtures such as Nomoto, Van Dael-Vangeel, Schaff’s collision factor theory and Junjie’s relations. Density and ultrasonic velocity of these mixtures have also been measured as a function of concentration and temperature and the experimental values are compared with the theoretical values. A good agreement has been found between experimental and Nomoto’s theoretical ultrasonic velocities. The results are explained in terms of intermolecular interactions occurring in these binary liquid mixtures.

scholarly journals Theoretical Evaluation of Ultrasonic Velocities in Binary Liquid Mixtures of Anisaldehyde with Some Alcoxyethanols at Different Temperatures

2012 ◽  
Vol 2012 ◽  
pp. 1-12 ◽  
Author(s):  
Zareena Begum ◽  
P. B. Sandhya Sri ◽  
C. Rambabu
Keyword(s):  
Interaction Parameter ◽  
Liquid Mixtures ◽  
Binary Liquid Mixtures ◽  
Ultrasonic Velocities ◽  
Theoretical Evaluation ◽  
Binary Liquid ◽  
Ideal Mixing ◽  
Different Temperatures ◽  
Relation Ideal ◽  
Molecular Interaction Parameter

Ultrasonic velocities and densities of the binary liquid mixtures of anisaldehyde with alcoxyethanols like methoxyethanol (MOE), ethoxyethanol (EOE), and butoxyethanol (BOE) have been measured at temperatures 303.15 K, 308.15 K, 313.15 K, and 318.15 K over the entire composition range of mole fractions. The theoretical values of ultrasonic velocity were evaluated using Nomoto's relation (), impedance relation (), ideal mixing relation (), Jungie's relation (), and Rao’s specific velocity relation (). The molecular interaction parameter () has been evaluated from the values of experimental and theoretical velocities. The variation of this interaction parameter with the composition mixture has been discussed in terms of molecular interactions.

Study of Molecular Interactions through Theoretical Evaluation of Ultrasonic Velocities in Binary Mixtures of Ethyl lactate at Different Temperatures

2017 ◽  
Vol 7 (12) ◽  
pp. 1257-1266
Author(s):  
K.R.K. Rajakumar ◽  
P.B. Sandhya Sri ◽  
G. Lakshmana Rao ◽  
A. Koteswara Rao ◽  
G.R. Satyanarayana ◽  
...  
Keyword(s):  
Binary Mixtures ◽  
Molecular Interactions ◽  
Ethyl Lactate ◽  
Ultrasonic Velocities ◽  
Theoretical Evaluation ◽  
Different Temperatures

scholarly journals Theoretical Evaluation of Ultrasonic Velocities in Binary Liquid Mixtures at Different Temperatures

2013 ◽  
Vol 10 ◽  
pp. 1-6
Author(s):  
M. Durga Bhavani ◽  
A. Ratnakar ◽  
Ch. Kavitha
Keyword(s):  
Liquid Mixtures ◽  
Binary Liquid Mixtures ◽  
Present System ◽  
Ultrasonic Velocities ◽  
Theoretical Evaluation ◽  
Binary Liquid ◽  
Ideal Mixing ◽  
Different Temperatures ◽  
Experimental Values ◽  
Mole Fraction Range

Ultrasonic velocities calculated from various theories and relations like Nomoto’s relation, Van dael ideal mixing relation, Impedance relation, Rao’s specific velocity relation and Jungie’s theory are compared with experimental values in binary liquid mixtures o-anisidine with o-cresol at temperatures 303.15, 308.15, 313.15 and 318.15 K over the entire mole fraction range. The relative applicability of these theories to the present system is checked and discussed. A good agreement is observed between experimental and theoretical values. The results are explained in the light of molecular interactions occuring in these mixtures.

scholarly journals Theoretical Ultrasonic Velocities in Binary Liquid Mixture Containing Aniline and Anisole at Different Temperatures – A Comparative Study

2013 ◽  
Vol 12 ◽  
pp. 120-124 ◽  
Author(s):  
Y. Sreedevi ◽  
Ch. Srinivasu ◽  
Sk. Fakruddin ◽  
K. Narendra ◽  
B.R. Venkateswara Rao ◽  
...  
Keyword(s):  
Comparative Study ◽  
Ultrasonic Velocity ◽  
Composition Range ◽  
Liquid Mixture ◽  
Binary Liquid Mixture ◽  
Ultrasonic Velocities ◽  
Binary Liquid ◽  
Different Temperatures ◽  
Experimental Values ◽  
Good Agreement

Ultrasonic velocity is measured experimentally at 3MHz frequency in the binary liquid mixture containing aniline and anisole at different temperatures over the entire composition range and theoretical values of ultrasonic velocity have been evaluated by using Nomoto’s relation, Impedance relation, Van Dael ideal mixture relation. These theoretical values are compared with the experimental values. A good agreement has been found between experimental and theoretical ultrasonic velocities.

scholarly journals Acustical Studies of Interactions in the Binary Mixtures of Ethylmethyl Ketone (EMK) and N,N-Dimethylformamide (DMF) through Ultrasonic Measurements at Different Temperatures

2015 ◽  
Vol 47 ◽  
pp. 120-132
Author(s):  
Baljeet Singh Patial
Keyword(s):  
Relaxation Time ◽  
Internal Pressure ◽  
Acoustic Impedance ◽  
Adiabatic Compressibility ◽  
Ultrasonic Velocities ◽  
Intermolecular Free Length ◽  
Acoustical Parameter ◽  
Wada’S Constant ◽  
Ultrasonic Measurements ◽  
Different Temperatures

Ultrasonic velocities (u), densities (ρ) and viscosities (η) are measured in respect of ethylmethylketone (EMK) and N,N-dimethylformamide (DMF) over the entire composition at 298, 308and 318K. Attempt have been made to extract the information with respect to various kind of intermolecular interactions, such as H-bonding, dipole-dipole, solute –solvent, dispersion type interactions existing between these two components from the following acoustical parameter when examined as a function of solvent composition at different temperatures: adiabatic compressibility (β), specific acoustic impedance (Z), intermolecular free length (Lf), molar sound velocity (Rm), wada’s constant (W), viscous relaxation time (τ), free volume and internal pressure (πi).

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