Programmable droplet manipulation and wetting with soft magnetic carpets

The ability to regulate interfacial and wetting properties is highly demanded in anti-icing, anti-biofouling, and medical and energy applications. Recent work on liquid-infused systems achieved switching wetting properties, which allow us to turn between slip and pin states. However, patterning the wetting of surfaces in a dynamic fashion still remains a challenge. In this work, we use programmable wetting to activate and propel droplets over large distances. We achieve this with liquid-infused soft magnetic carpets (SMCs) that consist of pillars that are responsive to external magnetic stimuli. Liquid-infused SMCs, which are sticky for a water droplet, become slippery upon application of a magnetic field. Application of a patterned magnetic field results in a patterned wetting on the SMC. A traveling magnetic field wave translates the patterned wetting on the substrate, which allows droplet manipulation. The droplet speed increases with an increased contact angle and with the droplet size, which offers a potential method to sort and separate droplets with respect to their contact angle or size. Furthermore, programmable control of the droplet allows us to conduct reactions by combining droplets loaded with reagents. Such an ability of conducting small-scale reactions on SMCs has the potential to be used for automated analytical testing, diagnostics, and screening, with a potential to reduce the chemical waste.

Laser fabrication of modular superhydrophobic chips for reconfigurable assembly and self-propelled droplet manipulation

Natural creatures that enables controllable liquid transport provides the inspiration for developing novel microfluidic devices by engineering functional surfaces with superwettability. However, towards microfluidic applications, the strict requirements of sophisticated droplet manipulation make it challenging to reach this end. In this work, we report a conceptually new self-propelled droplet manipulation strategy based on reconfigurable superhydrophobic chips. The modular droplet chip (MDC) is developed by laser embossing a series of superhydrophobic structures on elastomer jigsaws that act as functional units. MDC is potable since only gravity is used as the driving force for dynamic manipulation of liquid droplets, including droplets transporting, splitting, merging and bouncing without mass loss. The MDC demonstrated reasonable anti-cross-contamination property due to the water repellence of the superhydrophobicity. Modular assembly of MDC enables different chip functions including solution dilution, SERS detection, cell labeling and chemical synthesis. As a miniature and portable experimental platform, the MDC is promising for next-generation lab-on-a-chip systems.