Versatile Covalent Postsynthetic Modification of Metal Organic Frameworks via Thermal Condensation for Fluoride Sensing in Waters

Having access to safe drinking water is one of the 17 sustainable development goals defined by the United Nations (UN). However, many settlements around the globe have limited access to drinkable water due to non-anthropogenic pollution of the water sources. One of those pollutants is fluoride, which can induce major health problems. In this manuscript, we report on a post synthetic functionalization of metal organic frameworks for the sensing of fluoride in water. The proposed thermal condensation methodology allows for a high yield of functionalization using few steps, reducing reagent costs and generating minimal by-products. We identified a Rhodamine B functionalized Al-BDC-NH2 metal organic framework as one particularly suitable for fluoride detection in water.

Hydrazone derivative of 2-hydroxyquinoline-3-carbaldehyde: an efficient anionic and cationic sensor

A hydrazone (1) based on 2-hydroxyquinoline-3-carbaldehyde was synthesized and its anion and cation detection ability were studied. It could detect both fluoride in acetonitrile selectively among anions and copper ions in semiaqueous medium among cations. The addition of fluoride ion to the acetonitrile solution of the receptor produced a sharp colour change from light yellow to bluish green. The corresponding UV–vis measurements showed a red shift of the band of receptor 1 for fluoride and a blue shift of the band for copper ions. The fluorescence intensity of the receptor 1 got quenched with both fluoride and copper ions. The detection limits for both the ions are in order of micromolar level. The practical applications of fluoride detection were extended to oral care products.

Sensitive and selective colorimetric probe for fluoride detection based on the interaction between 3-aminophenylboronic acid and dithiobis(succinimidylpropionate) modified gold nanoparticles

APBA was conjugated on DSP@AuNP to form stable APBA–DSP@AuNP, exhibiting high selectivity towards fluoride against other anions and glucose.