Colour Quality Evaluation of Bluish-Green Serpentinite Based on the CIECAM16 Model

The CIECAM16 colour appearance model is currently a model with high prediction accuracy. It can solve the problem of predicting the influence of different observation conditions on the colour of gemstones. In this study, a computer vision system (CVS) was used to measure the colour of 59 bluish-green serpentinite samples, and the tristimulus values were input into the CIECAM16 forward model to calculate the colour appearance parameters of serpentinite under different surrounds, illuminances, and light sources. It was found that the darkening of the surround causes the lightness and brightness to increase. Pearson’s r of brightness and colourfulness with illuminance is 0.885 and 0.332, respectively, which predicts the Stevens and Hunt effects. When the light source changes from D65 to A, the calculated hue angle shifts to the complementary area of the A light source, which is contrary to the CVS measurement result. The D65 light source is more suitable for the colour presentation and classification of bluish-green serpentinite.

Green Synthesis and Characterization of Copper Nanoparticles Using Fortunella margarita Leaves

The use of biomaterials in the synthesis of nanoparticles is one of the most up-to-date focuses in modern nanotechnologies and nanosciences. More and more research on green methods of producing metal oxide nanoparticles (NP) is taking place, with the goal to overcome the possible dangers of toxic chemicals for a safe and innocuous environment. In this study, we synthesized copper nanoparticles (CuNPs) using Fortunella margarita leaves’ extract, which reflects its novelty in the field of nanosciences. The visual observation of a color change from dark green to bluish green clearly shows the instant and spontaneous formation of CuNPs when the phytochemicals of F. margarita come in contact with Cu+2 ions. The synthesis of CuNPs was carried out at different conditions, including pH, temperature, concentration ratio and time, and were characterized with UV-Vis absorption spectra, scanning electron microscope (SEM) and X-ray diffraction (XRD). The UV-Vis analysis reveals the surface plasmon resonance property (SPR) of CuNPs, showing a characteristic absorption peak at 679 nm, while SEM reveals the spherical but agglomerated shape of CuNPs of the size within the range of 51.26–56.66 nm.

Nephrite of Bazhenovskoye Chrysotile–Asbestos Deposit, Middle Urals: Localization, Mineral Composition and Color

In the Bazhenovskoye chrysotile–asbestos deposit (Middle Urals), nephrite bodies of the serpentinite type were found on the contact of after gabbro rodingites and serpentinites. The color is uniform to non-uniform, green to light green, bluish green, greyish green, and whitish. Spots, streaks, lenticules of bright bluish-green or, on the contrary, light green color are sometimes noted. The nephrite is mostly comprised of tremolite. Chromite decreases the quality of the ornamental stone, but it is replaced by chrome grossular, which gives the nephrite a brighter bluish-green color locally. Crushed grains of chromite contain increased concentrations of Zn and Mn. The quality of the nephrite is decreased by serpentine and talc, as well as by fractures due to drilling and blasting works. The specific feature of the nephrite in the Bazhenovskoye deposit is the formation of nickeline, maucherite, and uvarovite. The green color is associated with Fe2+ ions. The nephrite of the Bazhenovskoye deposit meets the requirements for an ornamental stone. The origin of this nephrite includes a combination of metasomatic and metamorphic processes.

Phthalocyanine green pigments

The dominant organic green pigments are polyhalogenated copper phthalocyanines (CuPcs). These pigments exhibit similar excellent coloristic and technical performance to CuPc blue pigments and are produced worldwide in large quantities. The green pigments are halogenated CuPcs. There are two pigments with CI designations. CI Pigment Green 7 is a bluish green product, in which the 16 ring hydrogen atoms of the CuPc molecule are replaced virtually completely by chlorine. Products designated as CI Pigment Green 36 incorporate a range of bromo- and bromochlorocopper phthalocyanines and are yellowish-green pigments. CuPc green pigments are manufactured by direct exhaustive halogenation of crude CuPc blue with chlorine or bromine or an appropriate mixture of the two halogens, depending on the composition of the product required. The synthesis is carried out at elevated temperatures in a suitable solvent, commonly a molten AlCl3/NaCl eutectic mixture.

A COMPARATIVE STUDY OF THE TYPE OF GROUNDWATER FOR WESTERN MOSUL REGIONS

Three water springs were selected in the western part of the city of Mosul (AinQana belongs to Al-Ayadiyah sub-district, Ain Abu Maria village, and AinSubashi in the center of Tal Afar district) to study some physical and chemical characteristics (temperature, electrical conductivity, acidic function, as well as negative and positive ions) and the biological characteristics of algae. The results of the study showed that the change in water temperature was little during the study period, and the highest value of the electrical connection reached (2557, 2488, and 1817) microsiemens / cm in Subashi, Qana, and Abu Maria sites, respectively. Whereas, the average dissolved oxygen concentration ranged between (0.0 to 3.6) mg / L at Qana and Subashi sites respectively. The total basal values ranged between (128) mg / L as CaCO3 at the site of Qana and (154) mg / L as CaCO3 at the site of Subashi. The results showed that the sodium concentration values were greater than the potassium concentration values in the three sites. Sixteen species of algae that belong to the algae section were diagnosed as bluish-green algae, green algae, and red algae. Oscillatoria was diagnosed in AinQana and the absence of the species belonging to the two algae sections, green and red algae in AinQana.

Visual Detection of Triethylamine and a Dual Input/Output Logic Gate Based on a Eu3+-Complex

A series of Ln3+-metal centered complexes, Ln(TTA)3(DPPI) (Ln = La, 1; Ln = Eu, 2; Ln = Tb, 3; or Ln = Gd, 4) [(DPPI = N-(4-(1H-imidazo [4,5-f][1,10]phenanthrolin-2-yl)phenyl)-N-phenylbenzenamine) and (TTA = 2-Thenoyltrifluoroacetone)] have been synthesized and characterized. Among which, the Eu3+-complex shows efficient purity red luminescence in dimethylsulfoxide (DMSO) solution, with a Commission International De L’ Eclairage (CIE) coordinate at x = 0.638, y = 0.323 and ΦEuL = 38.9%. Interestingly, increasing the amounts of triethylamine (TEA) in the solution regulates the energy transfer between the ligand and the Eu3+-metal center, which further leads to the luminescence color changing from red to white, and then bluish-green depending on the different excitation wavelengths. Based on this, we have designed the IMPLICATION logic gate for TEA recognition by applying the amounts of TEA and the excitation wavelengths as the dual input signal, which makes this Eu3+-complex a promising candidate for TEA-sensing optical sensors.

Crystallomorphological and physical properties of apatite from carbonatites

This paper presents the results of the study of x-ray luminescence of apatite from different genetic types of apatite species in order to study its geochemical characteristics and the possibility of using as a mineral indicator the conditions of ore formation and for search purposes. Apatite Ca2Ca3(F,Cl,OH)2[PO4]3 contains impurities Gd3+, Ce3+, Eu2+, Dy3+, Sm3+, Nd3+ as well as Mn2+ and others. Syngony is hexagonal. Crystals of prismatic habit; usually ending in dipyramide or basopinacoid. Sometimes forms tabular crystals. A hexagonal prism is often preserved. Color greenish, bluish-green; pinkish-purple, gray; often white, colorless or brown. Quite often translucent due to the presence of small internal cracks and inclusions; sometimes the inclusions are arranged oriented, preferably parallel to the main axis of the crystal. Brightly luminesces in cathode, x-ray and ultraviolet rays. The intensity and color of luminescence varies widely depending on the impurities. The presence of three crystal chemical positions in the structure of apatite – two cationic and one anionic makes it possible to be realized in the mineral by a wide heterovalent substitution. The distribution of isomorphic impurities between the crystal chemical positions will depend on the type of cation, its amount, as well as anionic substitutions in apatite. To determine the luminescence intensity values of the characteristic isomorphic impurities of apatite TR3+ (Gd3+, Ce3+, Eu2+, Dy3+, Sm3+, Nd3+) and Mn2+, the X-ray luminescence method was applied. Apatites of different genetic types of the Aldan, Baltic Shields, the Baikal region (Russia), the Sette-Daban Range, and the Maimech-Kotui Province (Yakutia) and the Ukrainian Shield were investigated. The obtained values of luminescence intensity of TR3+ and Mn2+ can be used to diagnose the genetic type of apatite species, the conditions of mineral formation, the type of their mineralization and for search purposes. On the basis of factor analysis, it can be concluded that the intensity of the luminescence centers of rare earth elements in the apatites of each complex depends on the relative age position of the mineral in the groups of successively formed rocks. Analysis of apatite carbonatites from different deposits showed minimal fluctuations in the ratios of radiation intensity of X-ray centers (Ce3+, Sm3+, Mn2+, Eu2+), which may indicate a close geochemical situation and, consequently, the only source of matter in the formation of carbonates. Analysis of apatite carbonatites from different fields showed minimal fluctuations in the radiation intensity ratios of the centers of X-ray luminescence (Ce3+, Sm3+, Mn2+, Eu2+), which, in my opinion, may indicate a close geochemical situation and, as a consequence, the substance or the result.

Gemological and mineralogical-petrographic study of the Eastern Sayan serpentinites

The purpose of the research is to study the mineralogical and petrographic characteristics of the Eastern Sayan serpentinites in order to identify their most decorative varieties. The objects of the study are the samples of serpentinites from the Ulan-Khodinskoye and Khokhurtovskoye deposits of the Eastern Sayan. Six samples were studied macroscopically then polished plates were made from them for gemological examination and thin sections for microscopic examination. All studies were carried out using standard gemological methods at the Gemmology Research Laboratory of the Irkutsk National Research Technical University. The petrographic study of thin sections was carried out using an Axio Lab A1 microscope. Macroscopically, two main ornamental varieties of serpentinite were identified: spotted bluish-green serpentinite and massive serpentinite of the color from dark green to black. The spotted structure of serpentinite is determined by numerous inclusions of ore minerals including magnetite and iron oxides. Its hardness is 4.5 on the Moh’s scale, its gloss is matte. The data on the main gemological characteristics of the samples corresponding to the results of already published studies of gem-quality serpentinites from other deposits were also obtained. Having analyzed the microstructure and mineral composition of the Eastern Sayan serpentinites, their correspondence to the spotty and massive decorative varieties of serpentinites from other Russian deposits was revealed. At the moment, this material is not duly appreciated, although it may well be used as a sculptural and jewelry-ornamental decorative stone.