spin lifetime
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Femtosecond spectroscopy and electron diffraction are used to characterize spin crossover in single crystal iron(II)-tris(bipyridine)-bis(hexafluorophosphate). The high-spin lifetime is reduced compared to in solution. Preliminary electron diffraction experiments show evidence of ultrafast Fe-N bond elongation associated with spin crossover and the subsequent molecular reorganization resulting from vibrational cooling.


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Jinsong Xu ◽  
Tiancong Zhu ◽  
Yunqiu Kelly Luo ◽  
Yuan-Ming Lu ◽  
Roland K. Kawakami

2018 ◽  
Vol 121 (12) ◽  
Author(s):  
Johannes Christian Leutenantsmeyer ◽  
Josep Ingla-Aynés ◽  
Jaroslav Fabian ◽  
Bart J. van Wees

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