sandwich compounds
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Triazolyl‐functionalized N‐Heterocyclic Carbene Half‐sandwich Compounds: Coordination Mode, Reactivity and in vitro Anticancer Activity

ChemMedChem ◽  
2021 ◽  
Author(s):  
Kelvin Tong ◽  
Muhammad Hanif ◽  
Sanam Movassaghi ◽  
Matthew P. Sullivan ◽  
James Lovett ◽  
...  
Keyword(s):  
Anticancer Activity ◽  
Coordination Mode ◽  
Sandwich Compounds ◽  
Half Sandwich

Synthesis and characterization of heteroleptic rare earth double-decker complexes involving tetradiazepinoporphyrazine and phthalocyanine macrocycles

2021 ◽  
Author(s):  
Ekaterina N. Tarakanova ◽  
Pavel A. Tarakanov ◽  
Anton Olegovich Simakov ◽  
Taniyuki Furuyama ◽  
Nagao Kobayashi ◽  
...  
Keyword(s):  
Rare Earth ◽  
Synthesis And Characterization ◽  
Sandwich Compounds ◽  
Double Decker

Reaction of (2,3,9,10,16,17,23,24-octabutylphthalocyaninato)lanthanide(III) acetylacetonates (BuPcLn(acac), 1a–c, Ln = Lu (a), Eu (b), La (c)) with tetrakis(5,7-bis(4-tert-butylphenyl)-6H-1,4-diazepino)[2,3-b,g,l,q]porphyrazine ligand (tBuPhDzPzH2, 2) produced sandwich compounds (tBuPhDzPz)Ln(BuPc) (3a–c), which represent first heteroleptic double-deckers incorporating...

Increasing the Ligand Field Strength in Butadiene Open Sandwich Compounds from the First to the Second Row Transition Metals

2020 ◽  
Vol 5 (21) ◽  
pp. 6350-6359
Author(s):  
Junfeng Qian ◽  
Qun Chen ◽  
Mingyang He ◽  
Zhihui Zhang ◽  
Xuejun Feng ◽  
...  
Keyword(s):  
Transition Metals ◽  
Field Strength ◽  
Ligand Field ◽  
Sandwich Compounds

scholarly journals Uranium(iv) cyclobutadienyl sandwich compounds: synthesis, structure and chemical bonding

2020 ◽  
Vol 56 (6) ◽  
pp. 944-947 ◽  
Author(s):  
Nikolaos Tsoureas ◽  
Akseli Mansikkamäki ◽  
Richard A. Layfield
Keyword(s):  
Chemical Bonding ◽  
Molecular Structures ◽  
Sandwich Complexes ◽  
Sandwich Complex ◽  
Sandwich Compounds ◽  
Bonding Properties ◽  
Half Sandwich

The synthesis, molecular structures and bonding properties of two uranium(iv) cyclobutadienyl half-sandwich complexes and a doubly activated cyclobutadienyl sandwich complex are described.

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