Vocabulary of radioanalytical methods (IUPAC Recommendations 2020)

These recommendations are a vocabulary of basic radioanalytical terms which are relevant to radioanalysis, nuclear analysis and related techniques. Radioanalytical methods consider all nuclear-related techniques for the characterization of materials where ‘characterization’ refers to compositional (in terms of the identity and quantity of specified elements, nuclides, and their chemical species) and structural (in terms of location, dislocation, etc. of specified elements, nuclides, and their species) analyses, involving nuclear processes (nuclear reactions, nuclear radiations, etc.), nuclear techniques (reactors, accelerators, radiation detectors, etc.), and nuclear effects (hyperfine interactions, etc.). In the present compilation, basic radioanalytical terms are included which are relevant to radioanalysis, nuclear analysis and related techniques.

Identifying the Cause of and Fixing Ill-Conditioned Matrices in Nuclear Analysis Codes

Many of the analytical codes used in the nuclear industry, such as TRACE, RELAP5, and PARCS, approximate the equations that model the physics via a linearized system of equations. One common difficulty when solving linearized systems is that an accurately formulated system of equations may be ill-conditioned. Ill-conditioned matrices can result in significant amplification of error leading to poor, or even invalid, results. Ill-conditioned matrices lead to some challenging issues for the analytical code developers: • An ill-conditioned matrix is often solvable, and there may be no obvious indication numerically that something has gone wrong even though numerical error is large. Thus, how can ill-conditioning be effectively detected for a matrix? • When ill-conditioning is detected, how can the source of the ill-conditioning be determined so that it can be analyzed and corrected? Ill-conditioning is fundamentally a geometric problem that can be understood with geometric concepts associated with matrices and vectors. Geometric concepts and tools, useful for understanding the cause of ill-conditioning of a matrix, are presented. A geometric understanding of ill-conditioning can point to the rows or columns of the matrix that most contribute to ill-conditioning so that the source of ill-conditioning can be analyzed and understood, and leads to techniques for building matrix preconditioners to improve the solvability of the matrix.