Quantum Phases of Time Order in Many-Body Ground States

Understanding phases of matter is of both fundamental and practical importance. Prior to the widespread appreciation and acceptance of topological order, the paradigm of spontaneous symmetry breaking, formulated along the Landau-Ginzburg-Wilson (LGW) dogma, is central to understanding phases associated with order parameters of distinct symmetries and transitions between phases. This work proposes to identify ground state phases of quantum many-body system in terms of time order, which is operationally defined by the appearance of nontrivial temporal structure in the two-time auto-correlation function of a symmetry operator (order parameter). As a special case, the (symmetry protected) time crystalline order phase detects continuous time crystal (CTC). Time order phase diagrams for spin-1 atomic Bose-Einstein condensate (BEC) and quantum Rabi model are fully worked out. Besides time crystalline order, the intriguing phase of time functional order is discussed in two non-Hermitian interacting spin models.

Molecular Dynamics Simulations of Crystal Nucleation near Interfaces in Incompatible Polymer Blends

We apply molecular dynamics (MD) simulations to investigate crystal nucleation in incompatible polymer blends under deep supercooling conditions. Simulations of isothermal nucleation are performed for phase-separated blends with different degrees of incompatibility. In weakly segregated blends, slow and incompatible chains in crystallizable polymer domains can significantly hinder the crystal nucleation and growth. When a crystallizable polymer is blended with a more mobile species in interfacial regions, enhanced molecular mobility leads to the fast growth of crystalline order. However, the incubation time remains the same as that in pure samples. By inducing anisotropic alignment near the interfaces of strongly segregated blends, phase separation also promotes crystalline order to grow near interfaces between different polymer domains.