Optical Properties of Select Particulates After High-Temperature Exposure

One increasingly viable option for high temperature concentrator solar power (CSP) is a central receiver system with a particle heating receiver (PHR). A PHR system uses suitable particulates to capture and store energy. It is expected that the particles will be sustained at high temperatures (in the range of 300°C or 400°C to 700°C or 800°C or even 1000°C) on most typical days of plant operation, so there is interest in how the particle optical properties might change after prolonged high-temperature exposure. This paper presents the results from experiments conducted over a 5-month period in which samples of various types of particulates including silica sands and alumina proppants were exposed to high temperatures for extended periods of time. The reflectance of a bed of particles was measured at room temperature in 8 wavelength bands using the 410-Solar reflectometer device developed by Surface Optics Corporation. The infrared emittance was determined using the ETS-100 emissometer instrument, also developed by Surface Optics Corporation [1,2]. Particles were heated to 950°C and 350°C, and measurements were recorded at intervals during the exposure so that trends in the optical properties over time could be observed. From the measured data, the total solar absorptance and total hemispherical emittance at high temperature were computed; these results are also presented.

Characterization of Pyromark 2500 for High-Temperature Solar Receivers

Pyromark 2500 is a silicone-based high-temperature paint that has been used on central receivers to increase solar absorptance. The cost, application, curing methods, radiative properties, and absorber efficiency of Pyromark 2500 are presented in this paper for use as a baseline for comparison to high-temperature solar selective absorber coatings currently being developed. The directional solar absorptance was calculated from directional spectral absorptance data, and values for pristine samples of Pyromark 2500 were as high as 0.96–0.97 at near normal incidence angles. At higher irradiance angles (>40°–60°), the solar absorptance decreased. The total hemispherical emittance of Pyromark 2500 was calculated from spectral directional emittance data measured at room temperature and 600°C. The total hemispherical emittance values ranged from ∼0.80–0.89 at surface temperatures ranging from 100°C – 1,000°C. The aging and degradation of Pyromark 2500 with exposure at elevated temperatures were also examined. Previous tests showed that solar receiver panels had to be repainted after three years due to a decrease in solar absorptance to 0.88 at the Solar One central receiver pilot plant. Laboratory studies also showed that exposure of Pyromark 2500 at high temperatures (750°C and higher) resulted in significant decreases in solar absorptance within a few days. However, at 650°C and below, the solar absorptance did not decrease appreciably after several thousand hours of testing. Finally, the absorber efficiency of Pyromark 2500 was determined as a function of temperature and irradiance using the calculated solar absorptance and emittance values presented in this paper.