Effects of residual disinfectants on the redox speciation of lead(ii)/(iv) minerals in drinking water distribution systems

This study investigated the reaction kinetics on the oxidative transformation of lead(ii) minerals by free chlorine (HOCl) and free bromine (HOBr) in drinking water distribution systems.

Segregation-free bromine-doped perovskite solar cells for IoT applications

Heavily Br-doped PSCs have a segregation-free effect in low-illuminance conditions, leading to the highest performances.

Applications of 1,3,5-trimethoxybenzene as a derivatizing agent for quantifying free chlorine, free bromine, bromamines, and bromide in aqueous systems

Free chlorine and free bromine (e.g., HOCl and HOBr) are employed as disinfectants in a variety of aqueous systems, including drinking water, wastewater, ballast water, recreational waters, and cleaning products.

1,3,5-Trimethoxybenzene (TMB) as a new quencher for preserving redox-labile disinfection byproducts and for quantifying free chlorine and free bromine

1,3,5-Trimethoxybenzene can be used to quench residual chlorine and bromine without altering disinfection byproducts that are reactive toward traditional quenchers.

Atomic fluorescence determination of mercury in fresh water ecosystems

This paper reports on an investigation into determining nanogram/l quantities of mercury in marine and fresh water matrices using a cold vapour generation of mercury, followed by fluorescence detection. Samples were prepared for analysis using a free bromine oxidation technique. A high efficiency gas-liquid separator was used to enhance the detection of mercury. For fresh water, typical method detection limits (MDL) were determined at less than 1 nanogram/l (ng/l). For near shore seawater, the MDL was 1.2 ng/l. Method spikes, which were performed at 20 ng/l, showed mean recoveries within US EPA Contract Laboratory Protocol (CLP) acceptance criteria. System blanks averaged 0.12 ng/l, and recoveries of NIST 1641c diluted to 29.4 ng/l averaged 93.4%. A number of local rivers and streams were sampled, and mercury was determined. All results to date indicate mercury levels below the US EPA chronic water quality criteria for mercury.