A mantle origin for sulfates in the unusual “salty” Udachnaya-East kimberlite from sulfur abundances, speciation and their relationship with groundmass carbonates

The Udachnaya-East pipe in Yakutia in Siberia hosts a unique dry (serpentine-free) body of hypabyssal kimberlite (<0.64wt% H2O), associated with a less dry type of kimberlite and a serpentinized kimberlitic breccia. The dry kimberlite is anomalously rich in salts (Na2O and Cl both up to 6wt%) whereas the slightly less dry and the breccia kimberlite are salt free. Yet the Udachnaya kimberlite is a group-I kimberlite, as is the archetypical kimberlite from Kimberley, South Africa. Samples were studied from the three different types of kimberlite (dry-salty, n=8, non-salty, n=5 and breccia, n=3) regarding their mineralogy, geochemistry, and more specifically their sulfur content. Our results show the salty kimberlite is unprecedentedly rich in sulfur (0.13-0.57wt%) compared to the non-salty kimberlite (0.04-0.12wt%) and the breccia (0.29-0.33wt%). In the salty kimberlite, most of the sulfur is present as sulfates (up to 97% of Stotal) and is disseminated throughout the groundmass in close association with Na-K-bearing carbonates. Sulfates occur within the crystal structure of these Na-K-bearing carbonates as the replacement of (CO3) by (SO3) groups, or as Na- and K-rich sulfates (e.g. aphtitalite, (K,Na)3Na(SO4)2). The associated sulfides are djerfisherite; also Na- and K-rich species. The close association of sulfates and carbonates in these S-rich alkaline rocks suggests that the sulfates crystallized from a mantle-derived magma, a case that has strong implication for the oxygen fugacity of kimberlite magmatism and more generally for the global S budget of the mantle.

Mineralogy of the P2-West ‘Kimberlite’, Wajrakarur kimberlite field, Andhra Pradesh, India: kimberlite or lamproite?

A detailed mineralogical examination of representative material from the P2-West 'kimberlite' located in the Wajrakarur Kimberlite Field (India) demonstrates that significant differences exist between these rocks and archetypal hypabyssal kimberlite. The intrusion consists of an olivine-phyric facies which has been transected by, and includes clasts of, a consanguineous phlogopite-rich pegmatitic facies. The olivine-rich parts of P2-West are relatively fresh and consist of euhedral-to-subhedral microphenocrystal olivine set in a groundmass of fine-grained anhedral monticellite, amoeboid apatite, and subhedral-to-euhedral perovskite within a partially chloritized-to-fresh phlogopite-rich mesostasis. The rock lacks the abundant olivine macrocrysts characteristic of kimberlite. Monticellite crystals are commonly partially or completely replaced by pectolite and hydrogarnet. Similar material occurs as irregular aggregates randomly scattered throughout the groundmass. The groundmass, in contrast to that of hypabyssal kimberlites, is relatively poor in spinels. Atoll spinels are absent, with the majority of spinels occurring principally as mantles upon microphenocrystal olivine. Disaggregated cumulate-like assemblages of intergrown anhedral perovskite and spinel are common. Spinel compositions are unlike those of kimberlites and their evolutionary trend is similar to that of lamproite and lamprophyre spinels. The pegmatitic facies of the intrusion are highly and pervasively altered, and characterized by the presence of large clasts, veins, and irregular aggregates consisting of large (1–5 mm) crystals of pinkish-bronze Al-poor phlogopite intergrown with and/or including: apatite; pectolite-hydrogarnet pseudomorphs after an unidentified euhedral phase; chlorite laths; barytolamprophyllite; perovskite; tausonite; diverse Sr-Ba-carbonates; and baryte. The presence of barytolamprophyllite and tausonite are typical of potassic undersaturated alkaline rocks and have never been reported from kimberlite; however, neither feldspar nor feldspathoids are present in P2-West. Micas in fresh and altered rocks are Al2O3- and BaO-poor, and exhibit compositional evolutionary trends towards tetraferriphlogopite rather than kinoshitalite. On the basis of these mineralogical data it is suggested that P2-West represents an unusual lamproite-like intrusion which has undergone extensive hydrothermal deuteric alteration and should not be considered a bona fide kimberlite.

The Churchill kimberlite field, Nunavut, Canada: petrography, mineral chemistry, and geochronology

Seventy-nine kimberlite intrusions have been identified in the Churchill Province, Nunavut, the result of an aggressive diamond exploration program by Shear Minerals Ltd. and their partners. This is one of Canada’s newest and largest kimberlite districts, situated immediately west of Hudson Bay between the communities of Rankin Inlet and Chesterfield Inlet. This study documents the occurrence of bonafide kimberlite rocks, classified as mainly sparsely macrocrystic, oxide-rich calcite evolved hypabyssal kimberlite and macrocrystic oxide-rich monticellite phlogopite hypabyssal kimberlite. Electron microprobe analyses of olivine, phlogopite, spinel, and perovskite support this petrographical classification. Low 87Sr/86Sr isotopic compositions determined from perovskite indicate a group I affinity. In addition, 27 precise U–Pb perovskite and Rb–Sr phlogopite emplacement ages have been determined for the Churchill kimberlites, indicating that magmatism spans ∼45 million years (225–170 Ma). The Churchill kimberlites belong to the NW–SE-trending corridor of Jurassic–Triassic kimberlite magmatism in eastern North America, which includes the Kirkland Lake, Timiskaming, and Attawapiskat kimberlite fields. Churchill kimberlites extend this corridor ∼800 km northwest, suggesting that the corridor may continue northwest with older kimberlites. This corridor is interpreted as the continental expression of magmatism linked to either a single or multiple mantle-plume hotspot track(s), a pattern geographically coincident with independent estimates for the timing and location of the continental extension of both the Great Meteor and Verde hotspot tracks.