Information geometry, trade-off relations, and generalized Glansdorff-Prigogine criterion for stability

We discuss a relationship between information geometry and the Glansdorff-Prigogine criterion for stability. For the linear master equation, we found a relation between the line element and the excess entropy production rate. This relation leads to a new perspective of stability in a nonequilibrium steady-state. We also generalize the Glansdorff-Prigogine criterion for stability based on information geometry. Our information-geometric criterion for stability works well for the nonlinear master equation, where the Glansdorff-Prigogine criterion for stability does not work well. We derive a trade-off relation among the fluctuation of the observable, the mean change of the observable, and the intrinsic speed. We also derive a novel thermodynamic trade-off relation between the excess entropy production rate and the intrinsic speed. These trade-off relations provide a physical interpretation of our information-geometric criterion for stability. We illustrate our information-geometric criterion for stability by an autocatalytic reaction model, where dynamics are driven by a nonlinear master equation.

A Nonlinear Master Equation for Open Quantum Systems

A nonlinear master equation is derived, reflecting properly the entropy of open quantum systems. In contrast to linear alternatives, its equilibrium solution is exactly the canonical Gibbs density matrix. The corresponding nonlinear equation for the Wigner function accounts rigorously for the thermo-quantum entropy. It reduces at large friction to the quantum Smoluchowski equation in the coordinate subspace. The previously derived Maxwell–Heisenberg relation for the nonequilibrium momentum dispersion of quantum Brownian particles is confirmed as well as the related quantum generalization of the classical Einstein law of Brownian motion.