spinel cathode
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Author(s):  
Toshihiko MANDAI ◽  
Ayaka KUTSUMA ◽  
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ACS Catalysis ◽  
2021 ◽  
pp. 58-65
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2021 ◽  
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Author(s):  
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Arumugam Manthiram


Author(s):  
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Kyungwha Chung ◽  
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2021 ◽  
pp. 106589
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...  


2021 ◽  
pp. 35-46
Author(s):  
Mesfin A. Kebede ◽  
Nithyadharseni Palaniyandy ◽  
Lehlohonolo F. Koao ◽  
Fabian I. Ezema ◽  
Motlalepula R. Mhlongo


Materials ◽  
2021 ◽  
Vol 14 (16) ◽  
pp. 4670
Author(s):  
Minsang Jo ◽  
Seong-Hyo Park ◽  
Hochun Lee

LiMn2O4 (LMO) spinel cathode materials suffer from severe degradation at elevated temperatures because of Mn dissolution. In this research, monobasic sodium phosphate (NaH2PO4, P2) is examined as an electrolyte additive to mitigate Mn dissolution; thus, the thermal stability of the LMO cathode material is improved. The P2 additive considerably improves the cyclability and storage performances of LMO/graphite and LMO/LMO symmetric cells at 60 °C. We explain that P2 suppresses the hydrofluoric acid content in the electrolyte and forms a protective cathode electrolyte interphase layer, which mitigates the Mn dissolution behavior of the LMO cathode material. Considering its beneficial role, the P2 additive is a useful additive for spinel LMO cathodes that suffer from severe Mn dissolution.



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