Mining of the off-balanced and balanced reserves of mines, being under closure or completing their operation, required the implementation of mobile, complex, and environmentally friendly development technologies based on the processes of well underground coal gasification (WUCG) that unites mining of coal and its energy-chemical use. Environmental friendliness of the WUCG process is possible due to its controllability, hermeticity of the underground gas generator, and complex use of cogeneration technologies in the closed cycle of purification and processing of gasification products. The set engineering tasks were performed using analytical studies, bench studies and field studies. Efficiency of thermal energy generation were studies using rocks enclosing the underground gasifier and generator gases. These sources being the basic heat generating segments of energy chemical complex for coal gasification being formed at the territories of operating coal mines or mines at the stage of their closure. Prospects of coal gasification and thermal energy generation using rock disposals of coal mines have been estimated.