Lise Meitner, β-decay and non-radiative electromagnetic transitions

The current activities in detecting neutrinos as carriers of information from far out in our Universe prompt us to look back on the research activities a century ago that led to the discovery of these weakly interacting particles. One of the leading researchers was Lise Meitner, who observed electrons with well-defined energy, besides the continuous energy spectrum emitted in β decay. These electron lines are well understood as radiationless nuclear transitions competing with γ-ray emission. It is proposed to name the electrons resulting out of this so-called internal conversion process after Lise Meitner and Charles D. Ellis. The equivalent process within the electronic (atomic) shell is the Auger effect , competing with X-ray emission. In this context, the radioactive decay of UX1 or 234 Th, well studied a century ago by Lise Meitner and Charles Ellis, is re-visited, and the mono-energetic electrons are ascribed entirely to the internal conversion process.

Hydration of Nucleobase as Probed by Electron Emission of Uridine-5′-Mono-Phosphate (UMP) in Aqueous Solution Induced by Nitrogen K-Shell Ionization

To identify the precise early radiation processes of DNA lesions, we measure electron kinetic energy spectra emitted from uridine-5′ monophosphate (UMP) in aqueous solution for the photoionization of the N 1s orbital electron and for the following Auger effect using a monochromatic soft X-ray synchrotron radiation at energies above the nitrogen K-shell ionization threshold. The change of photoelectron spectra for UMP in aqueous solutions at different proton concentrations (pH = 7.5 and 11.3) is ascribed to the chemical shift of the N3 nitrogen atom in uracil moiety of canonical and deprotonated forms. The lowest double ionization potentials for aqueous UMP at different pH obtained from the Auger electron spectra following the N 1s photoionization values show the electrostatic aqueous interaction of uracil moiety of canonical (neutral) and deprotonated (negatively charged) forms with hydrated water molecules.