Abstract
The experimental evidence points to the fact that a transition of some kind takes place at about 210° K, which, however, in consequence of supercooling, may take effect at a considerably lower temperature. As is mentioned in the Introduction, there is other evidence of such a transition. The thin curve in Figure 2, which is taken from the paper of Bekkedahl and Matheson, gives the specific heat of amorphous rubber. A sudden rise of this quantity occurs just below 200° K, and we feel sure that this near coincidence is more than accidental. The temperature lag between the two may be accounted for by the fact that Bekkedahl and Matheson worked with pure rubber hydrocarbon, whereas the material used for our investigation was vulcanized rubber. Bekkedahl's experiments on the temperature-volume relationship of various kinds of rubber showed that this transition is shifted towards higher temperatures when the rubber has been vulcanized.