Enhanced phosphorescence of Pd(II) and Pt(II) complexes adsorbed onto Laponite for optical sensing of triplet molecular dioxygen in water

Two isoleptic complexes involving Pd(II) and Pt(II) centres with a tetradentate luminophoric ligand were adsorbed onto Laponite (LAP), yielding H2O-dispersible nanohybrids with remarkable photoexcited state properties. The adsorption promoted rigidification of the coordination compounds and suppression of roto-vibrational deactivation pathways, thus enhancing the performance of the molecular species. Interestingly, room temperature phosphorescence was achieved in the case of the Pd(II)-containing nanohybrid along with a marked 3O2 sensitivity, whereas the photoluminescence of the Pt(II)-based material showed only a mild dependence on the presence of 3O2 while reaching up to 37% quantum yield.

Generation of Circularly Polarized Luminescence by Symmetry Breaking

Circularly polarized luminescence (CPL) has attracted significant attention in the fields of chiral photonic science and optoelectronic materials science. In a CPL-emitting system, a chiral luminophore derived from chiral molecules is usually essential. In this review, three non-classical CPL (NC-CPL) systems that do not use enantiomerically pure molecules are reported: (i) supramolecular organic luminophores composed of achiral organic molecules that can emit CPL without the use of any chiral auxiliaries, (ii) achiral or racemic luminophores that can emit magnetic CPL (MCPL) by applying an external magnetic field of 1.6 T, and (iii) circular dichroism-silent organic luminophores that can emit CPL in the photoexcited state as a cryptochiral CPL system.