This study explores the relationship between cooling rate and
microsegregation of directionally solidified ductile iron. The unidirectional
heat transfer system used in this research is made up of a copper mold kept
chilled by circulating water and embedded in the bottom of Furan sand mold.
Thermocouples are connected to the computer measuring system to record the
cooling curves of the castings at a distance of 0, 30, 60 and 90 mm from the
chilled copper mold surface. Alloys including Mn, Cr, Cu, Ni and Ti were
added to the specimens. Electron microprobe analysis (EPMA) was employed to
examine distribution of elements between the dendrite arms and nodular
graphite. Results show that unidirectional heat transfer affects directly the
solidification mode and microstructure of the casting. The cooling curves
reveal that local solidification time increases with increasing distance from
the chilled copper mold surface. Different solidification rates with
corresponding microstructure and element segregation were observed in the
same unidirectionally solidified casting. Local solidification time was
closely related to element segregation. The effective segregation coefficient
(Keff) calculated using the Scheil equation was found to vary, according to
the stage of solidification. The actual segregation characteristics of
complex alloys generally follow the Scheil equation.