Reaction Mechanism of Titanium with Carbon During Reactive Melt Infiltration of a Carbon Fiber Reinforced TiC and Carbon Composite

Author(s):  
Shuxin Bai ◽  
Yonggang Tong ◽  
Hong Zhang ◽  
Yicong Ye
Author(s):  
Bai Shuxin ◽  
Tong Yonggang ◽  
Ye Yicong ◽  
Zhang Hong

Carbon fiber reinforced ultra high temperature ceramic matrix composite (C/UHTC) is one of the most promising structural materials capable of prolonged operation in oxidizing environment at ultra high temperatures above 2000 ?C. Reactive melt infiltration (RMI) is a viable processing choice for C/UHTC composite. Compared with chemical vapor infiltration (CVI) and polymer impregnation and pyrolysis (PIP), RMI does not suffer from the drawbacks of time-consuming and high cost. It is viewed as a promising means of achieving near-net shape manufacturing with quick processing time and at low cost. Recently, great efforts have been made on RMI process for C/UHTC composite. Carbon fiber reinforced ZrC, HfC and TiC composites have been successfully fabricated by RMI. The aim of the following chapter is to introduce the RMI process and summarize the progress in RMI process for C/UHTC composite. In addition, future research directions of RMI are also proposed.


Author(s):  
Jun Lu ◽  
Dewei Ni ◽  
Chunjing Liao ◽  
Haijun Zhou ◽  
Youlin Jiang ◽  
...  

AbstractFiber damage and uniform interphase preparation are the main challenges in conventional short fiber reinforced ceramic matrix composites. In this work, we develop a novel processing route in fabrication of short carbon fiber reinforced ZrB2-SiC composites (Csf/ZrB2-SiC) overcoming the above two issues. At first, Csf preforms with oriented designation and uniform PyC/SiC interphase are fabricated via direct ink writing (DIW) of short carbon fiber paste followed by chemical vapor infiltration. After that, ZrB2 and SiC are introduced into the preforms by slurry impregnation and reactive melt infiltration, respectively. Microstructure evolution and optimization of the composites during fabrication are investigated in detail. The as-fabricated Csf/ZrB2-SiC composites have a bulk density of 2.47 g/cm3, with uniform weak interphase and without serious fiber damage. Consequently, non-brittle fracture occurs in the Csf/ZrB2-SiC composites with widespread toughening mechanisms such as crack deflection and bridging, interphase debonding, and fiber pull-out. This work provides a new opportunity to the material design and selection of short fiber reinforced composites.


Author(s):  
Shunichi Kubo ◽  
Hiroshi Tsuchiya

The metal-impregnated carbon fiber-reinforced carbon composite (C/C composite) is expected to be a candidate material for pantograph contact strips of high-speed electric railway vehicles, because its mechanical strength for flexure and impact is much higher than that of the conventional metal-impregnated carbon. The authors have investigated the wear properties of copper-titanium-alloy impregnated C/C composite sliding against a copper disk under an electric current and frequent arc discharges. The tested C/C composite was prepared by press molding and baking of laminated carbon fiber woven sheets. There exists anisotropy in the physical properties originated from the orientation of carbon fiber woven sheets lamination. The C/C composite was slid in two directions, in parallel with or perpendicular to the sheet layer. The test results show that the wear rate in sliding in the parallel direction exceeds that in the perpendicular direction, especially in the cases where the material is subjected to higher current density and more frequent arc discharges.


1998 ◽  
Vol 55 (2) ◽  
pp. 96-102 ◽  
Author(s):  
Hirotaka NAGAO ◽  
Takao NAKAGAWA ◽  
Hidefumi HIRAI

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