Quantification of Quantum Efficiency and Energy Losses in Low Bandgap Polymer:Fullerene Solar Cells with High Open-Circuit Voltage

2012 ◽  
Vol 22 (16) ◽  
pp. 3480-3490 ◽  
Author(s):  
Koen Vandewal ◽  
Zaifei Ma ◽  
Jonas Bergqvist ◽  
Zheng Tang ◽  
Ergang Wang ◽  
...  
2003 ◽  
Vol 762 ◽  
Author(s):  
Jianhua Zhu ◽  
Vikram L. Dalal

AbstractWe report on the growth and properties of microcrystalline Si:H and (Si,Ge):H solar cells on stainless steel substrates. The solar cells were grown using a remote, low pressure ECR plasma system. In order to crystallize (Si,Ge), much higher hydrogen dilution (∼40:1) had to be used compared to the case for mc-Si:H, where a dilution of 10:1 was adequate for crystallization. The solar cell structure was of the p+nn+ type, with light entering the p+ layer. It was found that it was advantageous to use a thin a-Si:H buffer layer at the back of the cells in order to reduce shunt density and improve the performance of the cells. A graded gap buffer layer was used at the p+n interface so as to improve the open-circuit voltage and fill factor. The open circuit voltage and fill factor decreased as the Ge content increased. Quantum efficiency measurements indicated that the device was indeed microcrystalline and followed the absorption characteristics of crystalline ( Si,Ge). As the Ge content increased, quantum efficiency in the infrared increased. X-ray measurements of films indicated grain sizes of ∼ 10nm. EDAX measurements were used to measure the Ge content in the films and devices. Capacitance measurements at low frequencies ( ~100 Hz and 1 kHz) indicated that the base layer was indeed behaving as a crystalline material, with classical C(V) curves. The defect density varied between 1x1016 to 2x1017/cm3, with higher defects indicated as the Ge concentration increased.


2019 ◽  
Vol 55 (30) ◽  
pp. 4315-4318 ◽  
Author(s):  
Shengfan Wu ◽  
Zhen Li ◽  
Jie Zhang ◽  
Tiantian Liu ◽  
Zonglong Zhu ◽  
...  

We present a strategy for suppressing the open-circuit voltage (Voc) loss of perovskite solar cells by incorporating large guanidinium cations (Gua+) into a perovskite lattice, leading to a significantly improved Voc of 1.19 V and an impressive power conversion efficiency of >21%.


2019 ◽  
Vol 7 (29) ◽  
pp. 17324-17333 ◽  
Author(s):  
Meiyue Liu ◽  
Ziming Chen ◽  
Yongchao Yang ◽  
Hin-Lap Yip ◽  
Yong Cao

Ag diffused across the PCBM layer increased the trap density and down-shifted the energy level of the perovskite layer. Fortunately, PCBM/ZnO layer efficiently suppressed the Ag diffusion, resulting in a perovskite solar cell with PCE of 18.1%.


2021 ◽  
Vol 5 (3) ◽  
pp. 242-250
Author(s):  
D. Sergeyev ◽  
K. Shunkeyev ◽  
B. Kuatov ◽  
N. Zhanturina

In this paper, the features of the characteristics of model thin-film solar cells based on the non-toxic multicomponent compound CuZn2AlS4 (CZAS) are considered. The main parameters (open-circuit voltage, short-circuit current, fill factor, efficiency) and characteristics (quantum efficiency, current-voltage characteristic) of thin-film solar cells based on CZAS have been determined. The minimum optimal thickness of the CZAS absorber is found (1-1.25 microns). Deterioration of the performance of solar cells with an increase in operating temperature (280-400 K) is shown. It is revealed that in the wavelength range of 390-500 nm CZAS has a high external quantum efficiency, which allows its use in designs of multi-junction solar cells designed to absorb solar radiation in the specified range. It is shown that the combination of CZAS films with a buffer layer of non-toxic ZnS increases the performance of solar cells.


2011 ◽  
Vol 115 (30) ◽  
pp. 15075-15080 ◽  
Author(s):  
Pablo P. Boix ◽  
Martijn M. Wienk ◽  
René A. J. Janssen ◽  
Germà Garcia-Belmonte

2021 ◽  
Author(s):  
Xuan Liu ◽  
Yang Liu ◽  
Yongfeng Ni ◽  
Ping Fu ◽  
Xuchao Wang ◽  
...  

Increasing electroluminescene quantum efficiency (EQEEL) of photoactive layer to reduce non-radiative recombination energy loss (Eloss) has been demonstrated an effective strategy to improve open-circuit voltage (Voc) of organic solar cells...


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