Colloidal Crystals: Three-Dimensionally Ordered Macroporous Polymeric Materials by Colloidal Crystal Templating for Reversible CO2Capture (Adv. Funct. Mater. 37/2013)

Three dimensionally ordered macroporous (3DOM) Li4Ti5O12 was successfully prepared by a colloidal crystal templating process. Colloidal crystal consisting of monodisperse polystyrene particles (1 9m diameter) was used as a template for the synthesis of macroporous Li4Ti5O12. A precursor sol consisting of titanium isopropoxide and lithium acetate was injected into the template, and it was calcined at high temperatures. A macroporous membrane of Li4Ti5O12 with inverse-opal structure was obtained. The prepared material had a spinel-related crystallographic structure. The interconnected pores with uniform size (0.8 9m) were clearly observed on entire part of the membrane. The electrochemical properties of the 3DOM Li4Ti5O12were characterized with cyclic voltammetry and glavanostatic charge-discharge in an organic electrolyte containing a lithium salt. 3DOM Li4Ti5O12 exhibited a discharge capacity of 160 mA h g-1 at the electrode potential of 1.55 V vs. Li/Li+ due to the solid state redox of Ti3+/4+ accompanying with Li+ ion insertion and extraction. The discharge capacity was close to the theoretical capacity (167 mA h g-1). This means that the Li+ insertion and extraction took place at all part of the 3DOM Li4Ti5O12 membrane.

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Facile synthesis of functionalized polymer microsphere with three-dimensionally ordered macroporous structure by a colloidal crystal templating method

Colloid & Polymer Science ◽

10.1007/s00396-018-4335-6 ◽

2018 ◽

Vol 296 (7) ◽

pp. 1267-1271

Author(s):

Siqi Li ◽

Dandan Xu ◽

Ting Pan ◽

Quanzhou Wu ◽

Jianfeng He

Keyword(s):

Colloidal Crystal ◽

Macroporous Structure ◽

Facile Synthesis ◽

Polymer Microsphere ◽

Templating Method ◽

Colloidal Crystal Templating ◽

Ordered Macroporous

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Colloidal Crystal Templating of Two-Dimensional Ordered Macroporous SiCN Ceramics

Solid State Phenomena - Nanocomposites and Nanoporous Materials VIII ◽

10.4028/3-908451-48-5.27 ◽

2008 ◽

pp. 27-30

Author(s):

In Hyuck Song ◽

Yong Jin Kim ◽

Hai Doo Kim ◽

Dong Pyo Kim

Keyword(s):

Colloidal Crystal ◽

Two Dimensional ◽

Colloidal Crystal Templating ◽

Ordered Macroporous

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Facile synthesis of three-dimensionally ordered macroporous silicon-doped La0.8K0.2CoO3 perovskite catalysts for soot combustion

Catalysis Science & Technology ◽

10.1039/c6cy00677a ◽

2016 ◽

Vol 6 (21) ◽

pp. 7718-7728 ◽

Cited By ~ 24

Author(s):

Nengjie Feng ◽

Chong Chen ◽

Jie Meng ◽

Yang Wu ◽

Geng Liu ◽

...

Keyword(s):

Colloidal Crystal ◽

Macroporous Silicon ◽

Macroporous Structure ◽

Soot Combustion ◽

Facile Synthesis ◽

Templating Method ◽

Perovskite Catalysts ◽

Colloidal Crystal Templating ◽

Ordered Macroporous ◽

Silicon Doped

Three-dimensionally ordered macroporous (3DOM) silicon-doped La0.8K0.2CoO3 perovskite catalysts were successfully prepared by a colloidal crystal templating method. The catalysts showed a well-ordered macroporous structure and exhibited high activity for soot removal.

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Preparation of Three-dimensionally Ordered Macroporous Li1.5Al0.5Ti1.5(PO4)3 by Colloidal Crystal Templating Method

Journal of the Japan Society of Powder and Powder Metallurgy ◽

10.2497/jjspm.53.856 ◽

2006 ◽

Vol 53 (11) ◽

pp. 856-859 ◽

Cited By ~ 3

Author(s):

Yasuhiro Isshiki ◽

Kaoru Dokko ◽

Kiyoshi Kanamura

Keyword(s):

Colloidal Crystal ◽

Templating Method ◽

Colloidal Crystal Templating ◽

Ordered Macroporous

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MORPHOLOGICALLY CONTROLLED ELECTRODEPOSITION OF ZnO AND Cu2O BY THE COLLOIDAL CRYSTAL TEMPLATE METHOD

Journal of Nonlinear Optical Physics & Materials ◽

10.1142/s0218863509004889 ◽

2009 ◽

Vol 18 (04) ◽

pp. 611-616 ◽

Cited By ~ 1

Author(s):

MING FU ◽

AILUN ZHAO ◽

JI ZHOU ◽

DAWEI HE ◽

YONGSHENG WANG

Keyword(s):

Electrochemical Method ◽

Colloidal Crystal ◽

Colloidal Crystals ◽

Template Method ◽

Inverse Opal ◽

Macroporous Materials ◽

Colloidal Crystal Template ◽

Colloidal Crystal Templating

This paper presents a versatile method for fabricating 3D macroporous materials using colloidal crystals as the templates. ZnO and Cu2O were deposited by the electrochemical method via the colloidal crystal template. Not only were 3D inverse opal structures and 2D nanobowls fabricated, but nanoparticles with a controlled shape were also prepared. Morphological controls via colloidal crystal templating are discussed.

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