Focused Microwave-Assisted Synthesis of 2,5-Dihydrofuran Derivatives as Electron Acceptors for Highly Efficient Nonlinear Optical Chromophores

2003 ◽  
Vol 15 (78) ◽  
pp. 603-607 ◽  
Author(s):  
S. Liu ◽  
M.A. Haller ◽  
H. Ma ◽  
L.R. Dalton ◽  
S.-H. Jang ◽  
...  
Keyword(s):  
Nonlinear Optical ◽  
Electron Acceptors ◽  
Microwave Assisted Synthesis ◽  
Microwave Assisted ◽  
Highly Efficient ◽  
Nonlinear Optical Chromophores ◽  
Optical Chromophores

Focused Microwave-assisted Synthesis of 2,5-Dihydrofuran Derivatives as Electron Acceptors for Highly Efficient Nonlinear Optical Chromophores

2003 ◽  
Vol 771 ◽  
Author(s):  
Sen Liu ◽  
Marnie A. Haller ◽  
Jingdong Luo ◽  
Sei-Hum Jang ◽  
Hong Ma ◽  
...  
Keyword(s):  
Single Mode ◽  
Electron Acceptors ◽  
Microwave Assisted Synthesis ◽  
High Glass Transition Temperature ◽  
New Class ◽  
Highly Efficient ◽  
Electro Optic ◽  
Nlo Chromophores ◽  
Nonlinear Optical Chromophores ◽  
Optical Chromophores

AbstractA diversified family of 2,5-dihydrofuran derivatives has been synthesized as a new class of highly efficient and tunable electron acceptors using the single-mode focused microwave irradiation. High poling efficiency and very large electro-optic coefficients (r33 values of 128 and 116 pm/V at 1.3 μm) have been demonstrated using 2-dicyanomethylen-3-cyano-4,5,-dimethyl-5-trifluoromethyl-2,5-dihydrofuran (CF3-TCF)-based chromophores as dopant in poly(methyl methacrylate) (PMMA) and a high glass-transition temperature polyquinoline (PQ-100) respectively. Excellent dipole alignment stability has also been demonstrated in the guest/host composite at 85°C. Multi-functionalized NLO chromophores based on hydroxy containing 2,5-dihydrofuran acceptors were also synthesized through microwave methodology for further characterizations.

Microwave-assisted synthesis of novel julolidinyl-based nonlinear optical chromophores with enhanced electro-optic activity

RSC Advances ◽  
2014 ◽  
Vol 4 (110) ◽  
pp. 65088-65097 ◽  
Author(s):  
Airui Zhang ◽  
Hongyan Xiao ◽  
Chengcheng Peng ◽  
Shuhui Bo ◽  
Huajun Xu ◽  
...  
Keyword(s):  
Nonlinear Optical ◽  
Conventional Heating ◽  
Microwave Assisted Synthesis ◽  
Heating Method ◽  
Microwave Assisted ◽  
Electro Optic ◽  
Mw Irradiation ◽  
Nonlinear Optical Chromophores ◽  
Optical Chromophores

Under microwave (MW) irradiation at a proper temperature, three chromophores (A, B and C) with julolidinyl-based donors and TCF or CF3-Ph-TCF acceptors have been synthesized in high overall yields compared with the conventional heating method.

Towards highly efficient nonlinear optical chromophores: molecular engineering of octupolar molecules

1999 ◽  
Vol 12 (2-3) ◽  
pp. 333-338 ◽  
Author(s):  
Mireille Blanchard-Desce ◽  
Jean-Bernard Baudin ◽  
Ludovic Jullien ◽  
Robert Lorne ◽  
Odile Ruel ◽  
...  
Keyword(s):  
Nonlinear Optical ◽  
Molecular Engineering ◽  
Highly Efficient ◽  
Nonlinear Optical Chromophores ◽  
Optical Chromophores

Facile Synthesis of Highly Efficient Phenyltetraene-Based Nonlinear Optical Chromophores for Electrooptics

2006 ◽  
Vol 8 (7) ◽  
pp. 1387-1390 ◽  
Author(s):  
Jingdong Luo ◽  
Yen-Ju Cheng ◽  
Tae-Dong Kim ◽  
Steven Hau ◽  
Sei-Hum Jang ◽  
...  
Keyword(s):  
Nonlinear Optical ◽  
Facile Synthesis ◽  
Highly Efficient ◽  
Nonlinear Optical Chromophores ◽  
Optical Chromophores

ChemInform Abstract: Donor-Acceptor-Substituted Phenylethenyl Bithiophenes: Highly Efficient and Stable Nonlinear Optical Chromophores.

ChemInform ◽  
2010 ◽  
Vol 31 (8) ◽  
pp. no-no
Author(s):  
Chengzhi Cai ◽  
Ilias Liakatas ◽  
Man-Shing Wong ◽  
Martin Boesch ◽  
Christian Bosshard ◽  
...  
Keyword(s):  
Nonlinear Optical ◽  
Highly Efficient ◽  
Donor Acceptor ◽  
Nonlinear Optical Chromophores ◽  
Optical Chromophores
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