Atomically Thin 2D Transition Metal Oxides: Structural Reconstruction, Interaction with Substrates, and Potential Applications

2018 ◽  
Vol 6 (1) ◽  
pp. 1801160 ◽  
Author(s):  
Tong Yang ◽  
Ting Ting Song ◽  
Martin Callsen ◽  
Jun Zhou ◽  
Jian Wei Chai ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Oxides ◽  
Transition Metal Oxides ◽  
Potential Applications

Mesoporous Crystals of Transition Metal Oxides

2008 ◽  
Vol 140 ◽  
pp. 37-46 ◽  
Author(s):  
Wu Zong Zhou
Keyword(s):  
Crystal Growth ◽  
Transition Metal ◽  
Metal Oxides ◽  
Transition Metal Oxides ◽  
Mesoporous Silicas ◽  
Technical Development ◽  
Potential Applications ◽  
New Form

Using mesoporous silicas as hard templates and facilitating crystal growth of transition metal oxides inside the pores, some mesoporous crystals can be produced after removing the templates. This paper gives a brief review of the research of mesoporous crystals of transition metal oxides in the last five years, including the technical development and potential applications of the new form of oxides.

scholarly journals Towards a Large-Area Freestanding Single-Crystal Ferroelectric BaTiO3 Membrane

Crystals ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 733
Author(s):  
Qixiang Wang ◽  
Hong Fang ◽  
Di Wang ◽  
Jie Wang ◽  
Nana Zhang ◽  
...  
Keyword(s):  
Transition Metal ◽  
Single Crystal ◽  
Metal Oxides ◽  
Data Storage ◽  
Transition Metal Oxides ◽  
Crack Density ◽  
Device Fabrication ◽  
Large Area ◽  
Study Approach ◽  
Potential Applications

The fabrication and transfer of freestanding single-crystal ferroelectric membranes deserve intensive investigations as to their potential applications in flexible wearable devices, such as flexible data storage devices and varied sensors in E-skin configurations. In this report, we have shown a comprehensive study approach to the acquisition of a large-area freestanding single-crystal ferroelectric BaTiO3 by the Sr3Al2O6 scarification layer method. By controlling the thickness of the BaTiO3 and Sr3Al2O6, the exposed area of the Sr3Al2O6 interlayer, and the utilization of an additional electrode La2/3Sr1/3MnO3 layer, the crack density on the freestanding BaTiO3 can be dramatically decreased from 24.53% to almost none; then, a more than 700 × 530 μm2 area high-quality freestanding BaTiO3 membrane can be achieved. Our results offer a clear and repeatable technology routine for the acquisition of a flexible large-area ferroelectric membrane, which should be instructive to other transition metal oxides as well. Our study can confidently boost flexible device fabrication based on single-crystal transition metal oxides.

HREM Study of electron-induced surface radiation damage in ReO3

1991 ◽  
Vol 49 ◽  
pp. 636-637
Author(s):  
R. Ai ◽  
H.-J. Fan ◽  
L. D. Marks
Keyword(s):  
Transition Metal ◽  
Metal Ions ◽  
Metal Oxides ◽  
Electron Irradiation ◽  
Transition Metal Oxides ◽  
Carbon Film ◽  
Transition Metal Ions ◽  
Surface Radiation ◽  
Valence Transition ◽  
Electron Microscopes

It has been known for a long time that electron irradiation induces damage in maximal valence transition metal oxides such as TiO2, V2O5, and WO3, of which transition metal ions have an empty d-shell. This type of damage is excited by electronic transition and can be explained by the Knoteck-Feibelman mechanism (K-F mechanism). Although the K-F mechanism predicts that no damage should occur in transition metal oxides of which the transition metal ions have a partially filled d-shell, namely submaximal valence transition metal oxides, our recent study on ReO3 shows that submaximal valence transition metal oxides undergo damage during electron irradiation.ReO3 has a nearly cubic structure and contains a single unit in its cell: a = 3.73 Å, and α = 89°34'. TEM specimens were prepared by depositing dry powders onto a holey carbon film supported on a copper grid. Specimens were examined in Hitachi H-9000 and UHV H-9000 electron microscopes both operated at 300 keV accelerating voltage. The electron beam flux was maintained at about 10 A/cm2 during the observation.

Problems with oxygen analysis in the system MgO-Al2O3-SiO2 with the electron microprobe

1992 ◽  
Vol 50 (2) ◽  
pp. 1624-1625
Author(s):  
Michel Fialin ◽  
Guy Rémond
Keyword(s):  
Transition Metal ◽  
Metal Oxides ◽  
Transition Metal Oxides ◽  
Electrostatic Charge ◽  
Carbon Layer ◽  
Sample Holder ◽  
Rock Matrix ◽  
Electrical Discharges ◽  
Thin Carbon ◽  
Beam Instabilities

Oxygen-bearing minerals are generally strong insulators (e.g. silicates), or if not (e.g. transition metal oxides), they are included within a rock matrix which electrically isolates them from the sample holder contacts. In this respect, a thin carbon layer (150 Å in our laboratory) is evaporated on the sections in order to restore the conductivity. For silicates, overestimated oxygen concentrations are usually noted when transition metal oxides are used as standards. These trends corroborate the results of Bastin and Heijligers on MgO, Al2O3 and SiO2. According to our experiments, these errors are independent of the accelerating voltage used (fig.l).Owing to the low density of preexisting defects within the Al2O3 single-crystal, no significant charge buildup occurs under irradiation at low accelerating voltage (< 10keV). As a consequence, neither beam instabilities, due to electrical discharges within the excited volume, nor losses of energy for beam electrons before striking the sample, due to the presence of the electrostatic charge-induced potential, are noted : measurements from both coated and uncoated samples give comparable results which demonstrates that the carbon coating is not the cause of the observed errors.

scholarly journals Electronic Phenomena of Transition Metal Oxides

Crystals ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 256
Author(s):  
Christian Rodenbücher ◽  
Kristof Szot
Keyword(s):  
Solid State ◽  
Transition Metal ◽  
Metal Oxides ◽  
Real World ◽  
Transition Metal Oxides ◽  
Major Research ◽  
Research Fields ◽  
Real World Applications

Transition metal oxides with ABO3 or BO2 structures have become one of the major research fields in solid state science, as they exhibit an impressive variety of unusual and exotic phenomena with potential for their exploitation in real-world applications [...]

Generalized Synthetic Strategy for Amorphous Transition Metal Oxides‐Based 2D Heterojunctions with Superb Photocatalytic Hydrogen and Oxygen Evolution

2020 ◽  
pp. 2009230
Author(s):  
Bing‐Xin Zhou ◽  
Shuang‐Shuang Ding ◽  
Kang‐Xin Yang ◽  
Jing Zhang ◽  
Gui‐Fang Huang ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Oxides ◽  
Oxygen Evolution ◽  
Transition Metal Oxides ◽  
Synthetic Strategy

Recent advances of layered-transition metal oxides for energy-related applications

2021 ◽  
Vol 36 ◽  
pp. 514-550
Author(s):  
Zhihao Lei ◽  
Jang Mee Lee ◽  
Gurwinder Singh ◽  
C.I. Sathish ◽  
Xueze Chu ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Oxides ◽  
Transition Metal Oxides ◽  
Recent Advances ◽  
Layered Transition Metal
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