Representation of deviation from ideality in concentrated aqueous solutions of electrolytes using a mean spherical approximation molecular model

AIChE Journal ◽  
1985 ◽  
Vol 31 (8) ◽  
pp. 1233-1240 ◽  
Author(s):  
Francois-Xavier Ball ◽  
Henri Planche ◽  
Walter Fürst ◽  
Henri Renon
Keyword(s):  
Aqueous Solutions ◽  
Molecular Model ◽  
Spherical Approximation ◽  
Mean Spherical Approximation ◽  
Concentrated Aqueous Solutions ◽  
Solutions Of Electrolytes

scholarly journals Speciation in Aqueous Solutions of Nitric Acid Estimated Within the Binding mean Spherical Approximation (BiMSA)

2012 ◽  
Vol 7 ◽  
pp. 374-379 ◽  
Author(s):  
Alexandre Ruas ◽  
Patrick Pochon ◽  
Stepan Hlushak ◽  
Jean-Pierre Simonin ◽  
Olivier Bernard ◽  
...  
Keyword(s):  
Nitric Acid ◽  
Aqueous Solutions ◽  
Spherical Approximation ◽  
Mean Spherical Approximation

scholarly journals IX.—On the Relationship between Concentration and Electrolytic Conductivity in Concentrated Aqueous Solutions

1906 ◽  
Vol 45 (1) ◽  
pp. 241-259 ◽  
Author(s):  
John Gibson
Keyword(s):  
Aqueous Solutions ◽  
General Relationship ◽  
Electrolytic Conductivity ◽  
Dilute Solutions ◽  
Concentrated Solutions ◽  
Concentrated Aqueous Solutions ◽  
Solutions Of Electrolytes ◽  
Weak Electrolytes ◽  
The Relationship

Although great advances have been made during the last thirty years in our knowledge of dilute solutions, there has been no corresponding advance in respect of concentrated solutions. This is primarily due to the fact that hitherto no simple and general relationship has been discovered between the conductivity and the concentration of concentrated solutions of electrolytes. Ostwald's law of dilution holds only for dilute solutions of weak electrolytes, and the formulæ of Rudolphi and Van T'Hoff are applicable only to dilute solutions of good electrolytes. It seems therefore important to inquire whether the difficulty may not be to some extent overcome by an alteration in the mode of representing the facts.

scholarly journals XXXII.—The Boiling and Freezing Points of Concentrated Aqueous Solutions, and the Question of the Hydration of the Solute

1908 ◽  
Vol 45 (4) ◽  
pp. 855-884 ◽  
Author(s):  
S. M. Johnston
Keyword(s):  
Aqueous Solutions ◽  
Boiling Point ◽  
Freezing Point ◽  
Conductivity Data ◽  
Concentrated Aqueous Solutions ◽  
Freezing Points ◽  
Solutions Of Electrolytes

In this paper the results of observations of the elevation of the boiling point of aqueous solutions of electrolytes are given, and a few results of observations of the depression of the freezing point, together with conductivity data obtained by observations of conductivity at about 99·4° and 0° Centigrade.

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