Switching of a Spin-Crossover-Material Incorporated in Metal–Organic Frameworks by a Reversible Ligand-Substitution Reaction in the Crystalline State

2003 ◽  
Vol 42 (46) ◽  
pp. 5668-5670 ◽  
Author(s):  
Thorsten Glaser
Keyword(s):  
Substitution Reaction ◽  
Crystalline State ◽  
Spin Crossover ◽  
Metal Organic Frameworks ◽  
Ligand Substitution ◽  
Metal Organic ◽  
Ligand Substitution Reaction

Single crystal to single crystal transformation of spin-crossover coordination polymers from 3D frameworks to 2D layers

2021 ◽  
Vol 9 (15) ◽  
pp. 5082-5087
Author(s):  
Yu Gong ◽  
Wang-Kang Han ◽  
Hui-Shu Lu ◽  
Qing-Tao Hu ◽  
Huan Tu ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Single Crystal ◽  
Coordination Polymers ◽  
Ligand Exchange ◽  
Spin Crossover ◽  
Metal Organic Frameworks ◽  
Crystal Transformation ◽  
Metal Organic

New Hofmann-type metal–organic frameworks display rare and complete ligand exchange induced single crystal to single crystal transformations from 3D frameworks to 2D layers, accompanied by magnetic properties transition from two-step SCO behavior to hysteretic SCO behavior.

Spin-Crossover Behavior in Cyanide-Bridged Iron(II)−Copper(I) Bimetallic 1−3D Metal−Organic Frameworks

2009 ◽  
Vol 48 (8) ◽  
pp. 3371-3381 ◽  
Author(s):  
Gloria Agustí ◽  
M. Carmen Muñoz ◽  
Ana B. Gaspar ◽  
José A. Real
Keyword(s):  
Spin Crossover ◽  
Metal Organic Frameworks ◽  
Crossover Behavior ◽  
Metal Organic

Kinetic determination of cysteine and thiosulphate by inhibition of Hg(II) catalyzed ligand substitution reaction

2008 ◽  
Vol 88 (1) ◽  
pp. 45-51 ◽  
Author(s):  
Radhey Mohan Naik ◽  
Joy Sarkar ◽  
Surendra Prasad
Keyword(s):  
Substitution Reaction ◽  
Ligand Substitution ◽  
Kinetic Determination ◽  
Ligand Substitution Reaction

Spin-Crossover Behavior in Cyanide-Bridged Iron(II)−Silver(I) Bimetallic 2D Hofmann-like Metal−Organic Frameworks

2007 ◽  
Vol 46 (20) ◽  
pp. 8182-8192 ◽  
Author(s):  
M. Carmen Muñoz ◽  
Ana B. Gaspar ◽  
Ana Galet ◽  
José A. Real
Keyword(s):  
Spin Crossover ◽  
Metal Organic Frameworks ◽  
Crossover Behavior ◽  
Metal Organic

scholarly journals Kinetics and mechanism of formation of the complex [Ru(CN)5INH]3− through the ligand substitution reaction between the aquapentacyanoruthenate(II) anion and isoniazid

2019 ◽  
Vol 44 (3) ◽  
pp. 244-256
Author(s):  
Rupal Yadav ◽  
Radhey Mohan Naik
Keyword(s):  
Ionic Strength ◽  
Substitution Reaction ◽  
Ligand Substitution ◽  
Yellow Colour ◽  
First Order ◽  
Charge Transfer Transitions ◽  
Colour Product ◽  
Pseudo First Order ◽  
Experimental Findings ◽  
Ligand Substitution Reaction

The formation kinetics of the complex, [Ru(CN)5INH]3−, formed through the ligand substitution reaction between isoniazid (INH) and aquapentacyanoruthenate(II) ([Ru(CN)5H2O]3−), have been investigated, under pseudo first-order conditions, as a function of concentrations of [INH] and [Ru(CN)5H2O]3−, ionic strength and temperature at pH = 4.0 ± 0.02 in 0.2 M NaClO4 spectrophotometrically at 502 nm ( λmax of intense yellow colour product [Ru(CN)5INH]3−) corresponding to metal-to-ligand charge-transfer transitions, in aqueous medium. The pseudo first-order condition was maintained by taking at least 10% excess of [INH] over [Ru(CN)5H2O]3−. The stoichiometry of the reaction product was found to be 1:1 which was further supported and characterized using elemental analysis, infrared, nuclear magnetic resonance and mass spectrometric techniques. Thermodynamic and kinetic parameters have also been computed, using the Eyring equation, and the values of ΔH≠, Ea, ΔG≠ and ΔS≠ were found to be 47.3 kJ mol−1, 49.8 kJ mol−1, −8.62 kJ mol−1 and 187.6 J K−1mol−1, respectively. The reaction was found to obey first-order kinetics with respect to [INH]. It exhibited a negative salt effect on the rate upon variation of ionic strength of the medium. A tentative mechanistic scheme was proposed on the basis of experimental findings.

scholarly journals Electrical conductivity and magnetic bistability in metal–organic frameworks and coordination polymers: charge transport and spin crossover at the nanoscale

2020 ◽  
Vol 49 (15) ◽  
pp. 5601-5638 ◽  
Author(s):  
Víctor Rubio-Giménez ◽  
Sergio Tatay ◽  
Carlos Martí-Gastaldo
Keyword(s):  
Electrical Conductivity ◽  
Charge Transport ◽  
Coordination Polymers ◽  
Spin Crossover ◽  
Electronic Devices ◽  
Metal Organic Frameworks ◽  
Active Components ◽  
Metal Organic

This review aims to reassess the progress, issues and opportunities in the path towards integrating conductive and magnetically bistable coordination polymers and metal–organic frameworks as active components in electronic devices.

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