Design and synthesis of a magnetic hierarchical porous organic polymer: A new platform in heterogeneous phase-transfer catalysis

2018 ◽  
Vol 32 (4) ◽  
pp. e4214 ◽  
Author(s):  
Arash Mouradzadegun ◽  
Mohammad Reza Ganjali ◽  
Mahsa Alsadat Mostafavi
Keyword(s):  
Phase Transfer Catalysis ◽  
Phase Transfer ◽  
Organic Polymer ◽  
Porous Organic Polymer ◽  
Design And Synthesis ◽  
Hierarchical Porous ◽  
Heterogeneous Phase

A hierarchical porous ionic organic polymer as a new platform for heterogeneous phase transfer catalysis

2015 ◽  
Vol 3 (47) ◽  
pp. 23871-23875 ◽  
Author(s):  
Qi Sun ◽  
Shengqian Ma ◽  
Zhifeng Dai ◽  
Xiangju Meng ◽  
Feng-Shou Xiao
Keyword(s):  
Phase Transfer Catalysis ◽  
Phase Transfer ◽  
Phase Transfer Catalyst ◽  
Organic Polymer ◽  
Ionic Polymer ◽  
Hierarchical Porous ◽  
Heterogeneous Phase

A hierarchical porous ionic polymer with excellent amphiphilicity has been successfully constructed and demonstrates extraordinary performances as a heterogeneous phase transfer catalyst.

Heterogeneous Phase Transfer Catalysis in Solid Phase Syntheses of Anth-Cyclic Tetrapeptides

2016 ◽  
Vol 81 (17) ◽  
pp. 8077-8081 ◽  
Author(s):  
Dongyue Xin ◽  
Jian Yuan ◽  
Kwok-Yin Wong ◽  
Kevin Burgess
Keyword(s):  
Phase Transfer Catalysis ◽  
Phase Transfer ◽  
Solid Phase ◽  
Cyclic Tetrapeptides ◽  
Heterogeneous Phase

ChemInform Abstract: Heterogeneous Phase Alkylation of Phenols Making Use of Phase Transfer Catalysis and Microwave Irradiation.

ChemInform ◽  
2010 ◽  
Vol 41 (17) ◽  
Author(s):  
Gyoergy Keglevich ◽  
Erika Balint ◽  
Eva Karsai ◽  
Judit Varga ◽  
Alajos Gruen ◽  
...  
Keyword(s):  
Microwave Irradiation ◽  
Phase Transfer Catalysis ◽  
Phase Transfer ◽  
Heterogeneous Phase

Adsorption desulfurization by hierarchical porous organic polymer of poly-methylbenzene with metal impregnation

Fuel ◽  
2016 ◽  
Vol 170 ◽  
pp. 100-106 ◽  
Author(s):  
Yanting Xia ◽  
Yankai Li ◽  
Yuntao Gu ◽  
Tian Jin ◽  
Qiang Yang ◽  
...  
Keyword(s):  
Organic Polymer ◽  
Porous Organic Polymer ◽  
Hierarchical Porous ◽  
Adsorption Desulfurization ◽  
Metal Impregnation

Hierarchical porous organic polymer as an efficient metal-free catalyst for acetalization of carbonyl compounds with alcohols

2018 ◽  
Vol 451 ◽  
pp. 43-50 ◽  
Author(s):  
Joong-Jo Kim ◽  
Cheang-Rae Lim ◽  
Benjaram M. Reddy ◽  
Sang-Eon Park
Keyword(s):  
Carbonyl Compounds ◽  
Organic Polymer ◽  
Metal Free ◽  
Porous Organic Polymer ◽  
Hierarchical Porous

scholarly journals Ultrasonically Promoted Synthesis of Ethyl 2-(naphthalen-2-yloxy)acetate in Solid-Liquid Heterogeneous Phase Transfer Catalysis Condition

2016 ◽  
Vol 11 (3) ◽  
pp. 273 ◽  
Author(s):  
Pachaiyappan Abimannan ◽  
Venugopal Rajendran
Keyword(s):  
Rate Constant ◽  
Quaternary Ammonium ◽  
Apparent Rate Constant ◽  
Phase Transfer Catalysis ◽  
Phase Transfer ◽  
Tetrabutylammonium Bromide ◽  
Phase Reaction ◽  
Catalysis Condition ◽  
Heterogeneous Phase ◽  
Solid Liquid

<p>In this paper, the synthesis of ethyl 2-(naphthalen-2-yloxy)acetate from β-naphthol and ethyl 2-bromoacetate under ultrasound and catalyzed by quaternary ammonium salt in solid-liquid heterogeneous condition was described. Trace amount of water play a major role in this solid-liquid reaction. The reaction follows pseudo first order rate law. The apparent rate constant of the organic phase reaction was obtained form the experimental data. The combination of small amount of tetrabutylammonium bromide (TBAB) and ultrasound (k<sub>app</sub> = 25.22×10<sup>-3 </sup>min<sup>-1</sup>) shows several fold enhanced rate of the reaction than the conventional operation (k<sub>app</sub> = 6.42×10<sup>-3 </sup>min<sup>-1 </sup>for TBAB only).  The rate constant increases (0.05 to 0.3 g) with increase in the concentration of catalyst (from k<sub>app</sub> = 10.12×10<sup>-3 </sup>min<sup>-1 </sup>to k<sub>app</sub> = 34.46×10<sup>-3 </sup>min<sup>-1</sup>). The other kinetic effects such as, effect of agitation speed, kind of frequency of ultrasound, kind of various quantity of K<sub>2</sub>CO<sub>3</sub>, quantity of water, temperature, different quaternary ammonium salts, solvents and volume of organic solvents on the conversion of ethyl 2-bromoacetate  and apparent rate constant were investigated in detail and rational explanations are provided. Copyright © 2016 BCREC GROUP. All rights reserved</p><p><em>Received: 4<sup>th</sup> November 2015; Revised: 13<sup>rd</sup> January 2016; Accepted: 16<sup>th</sup> January 2016</em></p><p><strong>How to Cite:</strong> Abimannan, P., Rajendran, V. (2016). Ultrasonically Promoted Synthesis of Ethyl 2-(naphthalen-2-yloxy)acetate in Solid-Liquid Heterogeneous Phase Transfer Catalysis Condition. <em>Bulletin of Chemical Reaction Engineering &amp; Catalysis</em>, 11 (3): 273-283 (doi:10.9767/bcrec.11.3.567.273-283)</p><p><strong>Permalink/DOI:</strong><a href="http://doi.org/10.9767/bcrec.11.3.567.273-283"> http://doi.org/10.9767/bcrec.11.3.567.273-283</a></p>

Heterogeneous Phase Alkylation of Phenols Making Use of Phase Transfer Catalysis and Microwave Irradiation

2009 ◽  
Vol 6 (7) ◽  
pp. 535-539 ◽  
Author(s):  
Gyorgy Keglevich ◽  
Erika Balint ◽  
Eva Karsai ◽  
Judit Varga ◽  
Alajos Grun ◽  
...  
Keyword(s):  
Microwave Irradiation ◽  
Phase Transfer Catalysis ◽  
Phase Transfer ◽  
Heterogeneous Phase

Progress in Reaction-Controlled Phase-Transfer Catalysis

2010 ◽  
Vol 31 (8) ◽  
pp. 895-911 ◽  
Author(s):  
Jun LI ◽  
Shuang GAO ◽  
Zuwei XI
Keyword(s):  
Phase Transfer Catalysis ◽  
Phase Transfer
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