Enhanced Thermal Decomposition Properties and Catalytic Mechanism of Ammonium Perchlorate over CuO/MoS 2 Composite

2019 ◽  
pp. e5060 ◽  
Author(s):  
Yinghui Hu ◽  
Yulin Yang ◽  
Ruiqing Fan ◽  
Kaifeng Lin ◽  
Dongyu Hao ◽  
...  
CrystEngComm ◽  
2018 ◽  
Vol 20 (43) ◽  
pp. 7010-7019 ◽  
Author(s):  
Ming Zhang ◽  
Fengqi Zhao ◽  
Yanjing Yang ◽  
Jiankan Zhang ◽  
Na Li ◽  
...  

rGO–Fe2O3 composites were fabricated using different solvents via a solvothermal method, and used for thermal decomposition of ammonium perchlorate (AP).


2013 ◽  
Vol 115 (1) ◽  
pp. 887-894 ◽  
Author(s):  
Xiangyu Li ◽  
Xiangling Liu ◽  
Yi Cheng ◽  
Yanchun Li ◽  
Xinliang Mei

2012 ◽  
Vol 535-537 ◽  
pp. 275-279 ◽  
Author(s):  
Hong Bo Liu ◽  
Bing Zhi Guo ◽  
Zhi Yong Huang ◽  
Hong Hui Xu ◽  
Chu Yang Fang ◽  
...  

A series of Cu/Cr nanocomposite oxides (Cu/Cr–NCOs) were prepared by Cu/Cr hydrotalcite precursors. Their catalytic activities on thermal decomposition of ammonium perchlorate (AP) were investigated by differential thermal analysis (DTA). The results show that Cu/Cr–NCOs are efficient in enhancing thermal decomposition of AP. With 4 wt. % addition of 500 °C calcined Cu2Cr–NCOs, the thermal decomposition process of AP can be accelerated by 107 °C. Cu/Cr–NCOs catalysts have better effect compared to mechanical mixture of CuO and Cr2O3 catalyst. Their catalytic mechanism was also discussed.


RSC Advances ◽  
2017 ◽  
Vol 7 (64) ◽  
pp. 40262-40269 ◽  
Author(s):  
Haitao Li ◽  
Kun Zhao ◽  
Shouqin Tian ◽  
Dawen Zeng ◽  
Aimin Pang ◽  
...  

A proposed classical catalytic mechanism based on surface lattice oxygen reveals that AP decomposition is promoted more by ZnO nanosheets than ZnS nanosheets.


2011 ◽  
Vol 197-198 ◽  
pp. 1225-1230 ◽  
Author(s):  
Feng Juan Xiao ◽  
Yun Jun Luo

Structures of ferrocene containing hyperbranched polyester (HBPE-Fc) was characterized by FTIR and H1 NMR. The spectroscopic analysis provided evidence of the successful modification of ferrocene toHBPE. The catalytic performances for thermal decomposition of ammonium perchlorate (AP) were investigated by DSC techniques. The kinetic parameters were computed by the Kissinger method. The results indicated that the presence of HBPE-Fc reduces the maximum decomposition reaction temperature in AP samples. HBPE-Fc presented an efficient catalytic effect on the thermal degradation of AP and the catalytic reactions were characterized by decreased activation energy and increased rate constant of thermal decomposition. The possible catalytic mechanism was proposed.


Author(s):  
Heng Zhai ◽  
Pengfei Xu ◽  
Yueqi Li ◽  
Ping Ye ◽  
Ruihao Wang ◽  
...  

The AP/Co3(CH3COO)5(OH) composites of the core–shell structure were prepared, the safety and thermal decomposition properties of AP were improved simultaneously, and the possible catalytic mechanism was analyzed.


2017 ◽  
Vol 724 ◽  
pp. 720-727 ◽  
Author(s):  
Jiaxin Wang ◽  
Wenchao Zhang ◽  
Zilong Zheng ◽  
Yu Gao ◽  
Kefeng Ma ◽  
...  

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