2D network structure of zinc(II) complex: A new easily accessible and efficient catalyst for the synthesis of pyrazoles

Author(s):  
Gang‐Ming Cao ◽  
Guo‐Dong Zeng ◽  
Ke Li ◽  
Yu‐Feng Liu ◽  
Xiao‐Ling Lin ◽  
...  
2006 ◽  
Vol 457 (1) ◽  
pp. 203-213 ◽  
Author(s):  
Ming Wen ◽  
E. Kejia ◽  
Megumu Munakata ◽  
Yusaku Suenaga ◽  
Takayoshi Kuroda-Sowa ◽  
...  

2017 ◽  
Vol 4 (11) ◽  
pp. 1888-1894 ◽  
Author(s):  
Xiao Zhang ◽  
Xuan Luo ◽  
Nanxi Zhang ◽  
Jie Wu ◽  
Yong-Qing Huang

A novel coordination polymer Zn(DMA)(TBA) (1) (H2TBA = 4-(1H-tetrazol-5-yl)-benzoic acid) features a unique two-dimensional (2D) network structure, exhibiting excellent luminescence and good stability in both water and other organic solvents.


2013 ◽  
Vol 68 (12) ◽  
pp. 1333-1339
Author(s):  
Gang-Hong Pan ◽  
Jing-Niu Tang ◽  
Xian-Hong Yin ◽  
Wei-Man Tian ◽  
Zhong-Jing Huang

A Cd(II) complex based on fluconazole and isophthalate ligands, {[Cd(HFlu)(IPA)(H2O)] · H2O}n (1), (HFlu=fluconazole; H2IPA=isophthalic acid) has been synthesized. Single-crystal X-ray analysis reveals that complex 1 has a 2D network structure including unusual triple hydrogen bonds between hydroxyl and triazolyl groups. The complex has also been characterized by IR, UV=Vis and fluorescence spectroscopy, elemental analysis, and thermogravimetry


2012 ◽  
Vol 67 (12) ◽  
pp. 1319-1324 ◽  
Author(s):  
Bingtao Liu ◽  
Rui Wang ◽  
Guiyang Zhang ◽  
Yanan Ding ◽  
Xiangru Meng

A new Zn(II) complex [Zn2(bimt)2(Ac)(OH)]n (1) has been synthesized by the reaction of the flexible ligand 2-(benzoimidazol-2-yl-methyl)-1H-tetrazole (Hbimt) with Zn(Ac)2 · 2H2O and characterized by single-crystal X-ray diffraction and IR spectra. In complex 1, Zn1 and Zn2 ions are connected by μ2-bridging acetate and hydroxide groups to form a 6-membered ring. The bimt units coordinate to Zn1 and Zn2 ions in a bidentate bridging mode with two nitrogen atoms from the same benzoimidazole ring and connect the 6-membered rings resulting in the formation of a 2D network structure. Adjacent layers are further packed to a threedimensional network through van der Waals bonds. A thermogravimetric analysis was carried out, and the photoluminescent behavior of the complex was investigated.


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