Development of Solutions to Two-Resistance Mass Transport Models Based on External and Pore Diffusion. Part I: Theoretical Development

2008 ◽  
Vol 1 (2-3) ◽  
pp. 129-145
Author(s):  
Gordon Mckay ◽  
Bushra Al-Duri ◽  
Stephen Mckee
Atmosphere ◽  
2020 ◽  
Vol 11 (10) ◽  
pp. 1057
Author(s):  
Marc L. Mansfield

When they dissolve in water, aldehydes become hydrated to gem-diols: R−COH+H2O↔RCH(OH)2. Such reactions can complicate air–water transport models. Because of a persistent belief that the gem-diols do not exist in the vapor phase, typical models do not allow them to pass through the air–water interface, but in fact, they do. Therefore, transport models that allow both molecular forms to exist in both phases and to pass through the interface are needed. Such a model is presented here as a generalization of Whitman’s two-film model. Since Whitman’s model has fallen into disuse, justification of its use is also given. There are hypothetical instances for which the flux predicted by the current model is significantly larger than the flux predicted when models forbid the diol form from passing through the interface. However, for formaldehyde and acetaldehyde, the difference is about 6% and 2%, respectively.


2014 ◽  
Vol 92 (11) ◽  
pp. 2681-2693 ◽  
Author(s):  
Thidarat Wongsawa ◽  
Niti Sunsandee ◽  
Ura Pancharoen ◽  
Anchaleeporn Waritswat Lothongkum

2015 ◽  
Vol 2015 (11) ◽  
pp. P11031 ◽  
Author(s):  
Yu-Xi Chau ◽  
Colm Connaughton ◽  
Stefan Grosskinsky

2019 ◽  
Vol 10 (1) ◽  
Author(s):  
N. Sundararajan ◽  
S. Sankaran

AbstractIn general, groundwater flow and transport models are being applied to investigate a wide variety of hydrogeological conditions besides to calculate the rate and direction of movement of groundwater through aquifers and confining units in the subsurface. Transport models estimate the concentration of a chemical in groundwater which requires the development of a calibrated groundwater flow model or, at a minimum, an accurate determination of the velocity and direction of groundwater flow that is based on field data. All the available hydrogeological, geophysical and water quality data in Musi basin, Hyderabad, India, were fed as input to the model to obtain the groundwater flow velocities and the interaction of surface water and groundwater and thereby seepage loss was estimated. This in turn paved the way to calculate the capacity of the storage treatment plants (STP) to be established at the inlets of six major lakes of the basin. The total dissolved solid was given as the pollutant load in the mass transport model, and through model simulation, its migration at present and futuristic scenarios was brought out by groundwater flow and mass transport modeling. The average groundwater velocity estimated through the flow model was 0.26 m/day. The capacities of STP of various lakes in the study area were estimated based on the lake seepage and evaporation loss. Based on the groundwater velocity and TDS as pollutant load in the lakes, the likely contamination from lakes at present and for the next 20 years was predicted.


2013 ◽  
Vol 64 (3) ◽  
pp. 216-234 ◽  
Author(s):  
Kamil Kwiatkowski ◽  
Bartosz Górecki ◽  
Jakub Korotko ◽  
Wojciech Gryglas ◽  
Marek Dudyński ◽  
...  

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