Synthesis of a hydrosoluble reversible addition‐fragmentation chain transfer agent and application in the preparation of micro/nano‐polyacrylamide gel dispersions

2021 ◽  
pp. 50930
Author(s):  
Ziteng Yang ◽  
Yaxing Dai ◽  
Fengrunze Zhang ◽  
Yixi Zhang ◽  
Hongmei Zheng ◽  
...  
Keyword(s):  
Chain Transfer ◽  
Polyacrylamide Gel ◽  
Chain Transfer Agent ◽  
Reversible Addition

The photo-controlled polymerization-induced self-assembly and reorganization process for fabrication of polymeric nanomaterials

2017 ◽  
Vol 1 (6) ◽  
pp. 1200-1206 ◽  
Author(s):  
Jiemei Zhou ◽  
Chunyan Hong ◽  
Caiyuan Pan
Keyword(s):  
Visible Light ◽  
Self Assembly ◽  
Dispersion Polymerization ◽  
Chain Transfer ◽  
Chain Transfer Agent ◽  
Controlled Polymerization ◽  
Dimethylaminoethyl Methacrylate ◽  
Reversible Addition

A visible light mediated reversible addition–fragmentation chain transfer (RAFT) dispersion polymerization of benzyl methacrylate (BzMA) is conducted in ethanol using poly(2-dimethylaminoethyl methacrylate) (PDMAEMA) as a macro-chain transfer agent (macro-CTA), affording polymeric nanomaterials with various morphologies.

Homophase and heterophase polymerizations of butyl acrylate mediated by poly(acrylic acid) as a reversible addition–fragmentation chain-transfer agent

2015 ◽  
Vol 57 (6) ◽  
pp. 547-559 ◽  
Author(s):  
E. V. Chernikova ◽  
A. V. Plutalova ◽  
K. O. Mineeva ◽  
I. R. Nasimova ◽  
E. Yu. Kozhunova ◽  
...  
Keyword(s):  
Acrylic Acid ◽  
Butyl Acrylate ◽  
Chain Transfer ◽  
Chain Transfer Agent ◽  
Reversible Addition ◽  
Poly Acrylic Acid

scholarly journals Synthesis of bottlebrush polymers via transfer-to and grafting-through approaches using a RAFT chain transfer agent with a ROMP-active Z-group

2015 ◽  
Vol 6 (31) ◽  
pp. 5643-5652 ◽  
Author(s):  
Scott C. Radzinski ◽  
Jeffrey C. Foster ◽  
John B. Matson
Keyword(s):  
Chain Transfer ◽  
Chain Transfer Agent ◽  
Multiple Strategies ◽  
Reversible Addition ◽  
Grafting Through ◽  
Chain Transfer Polymerization

A novel dithiocarbamate chain transfer agent for reversible addition–fragmentation chain transfer polymerization with a directly polymerizable Z-group was synthesized and used to make bottlebrush polymers via multiple strategies.

Copolymerization of Glycidyl Methacrylate and 1,1,1,3,3,3-Hexafluoroisopropyl Acrylate

2021 ◽  
Vol 899 ◽  
pp. 387-391
Author(s):  
Alexandra O. Grigoreva ◽  
Kseniia Tarankova ◽  
Sergey D. Zaitsev
Keyword(s):  
Glycidyl Methacrylate ◽  
Molar Mass ◽  
Chain Transfer ◽  
Good Control ◽  
Chain Transfer Agent ◽  
Polymeric Chain ◽  
Reactivity Ratios ◽  
Reversible Addition

The copolymerization of 1,1,1,3,3,3-hexafluoroisopropyl acrylate (HFIPA) and glycidyl methacrylate via reversible addition-fragmentation chain transfer (RAFT) process was investigated. 2-cyano-2-propyl dodecyl trithiocarbonate (CPDT) was used as chain transfer agent. It is turned out that CPDT and polymeric chain transfer agent obtained based on HFIPA and CPDT provide a good control over molar mass characteristic of copolymers (Đ = 1.05). Reactivity ratios were found to be r1(GMA) = 1.57 and r2(HFIPA) = 0.05 by Fineman–Ross model.

Reversible addition–fragmentation chain transfer polymerization of styrene using a novel thiophene dithioester as the reversible addition–fragmentation chain transfer agent

2007 ◽  
Vol 105 (4) ◽  
pp. 2357-2362 ◽  
Author(s):  
Nianchen Zhou ◽  
Lude Lu ◽  
Jian Zhu ◽  
Xujie Yang ◽  
Xin Wang ◽  
...  
Keyword(s):  
Chain Transfer ◽  
Chain Transfer Agent ◽  
Reversible Addition ◽  
Chain Transfer Polymerization

Novel Amide-Based Chain Transfer Agent for Reversible Addition Fragmentation Chain Transfer Polymerization

2005 ◽  
Vol 38 (4) ◽  
pp. 1057-1060 ◽  
Author(s):  
Pittaya Takolpuckdee ◽  
Craig A. Mars ◽  
Sébastien Perrier ◽  
Stephen J. Archibald
Keyword(s):  
Chain Transfer ◽  
Chain Transfer Agent ◽  
Reversible Addition ◽  
Chain Transfer Polymerization

RAFT Polymerization of 2,2,3,3-Tetrafluoropropyl Methacrylate in the Presence of Lewis Acids

2021 ◽  
Vol 899 ◽  
pp. 525-531
Author(s):  
Oleg A. Lebedev ◽  
Alexandra O. Grigoreva ◽  
Sergey D. Zaitsev
Keyword(s):  
Polymer Chain ◽  
Lewis Acids ◽  
Chain Transfer ◽  
Raft Polymerization ◽  
Point Of View ◽  
Chain Transfer Agent ◽  
Reversible Addition

The influence of various tacticity regulators on the reversible addition-fragmentation (RAFT) polymerization of 2,2,3,3-tetrafluoropropyl methacrylate in the presence of 2-cyano-2-propyldodecyltritiocarbonate as an chain transfer agent was investigated. Among Lewis acids considered, the polymerization of TFPMA in dioxane with ZnBr2 turned out to be the most effective from the point of view of tacticity; the polymer with the highest isotacticity is formed. The addition of hexafluoroisopropanol leads to an increase in the heterotacticity and a decrease in the isotacticity of the polymer chain.

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