Ternary Diffusion of Carbon Dioxide in Alkaline Solutions of Aqueous Sodium Hydroxide and Aqueous Sodium Carbonate

1985 ◽  
Vol 89 (7) ◽  
pp. 786-793 ◽  
Author(s):  
Derek G. Leaist





1985 ◽  
Vol 63 (11) ◽  
pp. 2933-2939 ◽  
Author(s):  
Derek G. Leaist

Ternary diffusion coefficients can be determined from restricted-diffusion experiments by evaluating zeroth and first time moments of the difference in a concentration-dependent property measured at two levels along the diffusion column. The method is used to determine ternary diffusion coefficients for aqueous sodium sulfite + sodium hydroxide solutions from conductance measurements. It is shown that these data can be analyzed to obtain the ternary diffusivity of sulfur dioxide in strongly alkaline solutions where sulfite is the major transporting species for the sulfur dioxide component. At high pH values, coupled flow of hydroxide ions leads to a significant increase in the diffusivity of the sulfur dioxide component relative to its diffusivity in pure water. Binary diffusion coefficients for aqueous sodium sulfite solutions are also reported.







1964 ◽  
Vol 17 (7) ◽  
pp. 740 ◽  
Author(s):  
KN Marsh ◽  
RH Stokes

The conductances of sodium hydroxide solutions at 15�, 25�, 50�, and 75� have been determined at concentrations up to 0.02N with special precautions to eliminate the effects of carbon dioxide and of alkaline attack on glass cells. The limiting conductances have been determined from the Fuoss-Onsager and Pitts equations, and the mobility of the hydroxide ion calculated. The theoretical specific conductance of water at various temperatures has been calculated.



1972 ◽  
Vol 5 (1) ◽  
pp. 27-33 ◽  
Author(s):  
KAKUSABURO ONDA ◽  
HIROSHI TAKEUCHI ◽  
TAKESHI KOBAYASHI ◽  
KENJIRO YOKOTA


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