Unambiguous Assignment of Short- and Long-Range Structural Restraints by Solid-State NMR Spectroscopy with Segmental Isotope Labeling

ChemBioChem ◽  
2014 ◽  
Vol 16 (1) ◽  
pp. 51-54 ◽  
Author(s):  
Tobias Schubeis ◽  
Thorsten Lührs ◽  
Christiane Ritter
Keyword(s):  
Solid State ◽  
Nmr Spectroscopy ◽  
Long Range ◽  
Solid State Nmr ◽  
Isotope Labeling ◽  
Solid State Nmr Spectroscopy ◽  
Segmental Isotope Labeling ◽  
Structural Restraints ◽  
Unambiguous Assignment

Isotope labeling for studying RNA by solid-state NMR spectroscopy

2018 ◽  
Vol 71 (3) ◽  
pp. 151-164 ◽  
Author(s):  
Alexander Marchanka ◽  
Christoph Kreutz ◽  
Teresa Carlomagno
Keyword(s):  
Solid State ◽  
Nmr Spectroscopy ◽  
Solid State Nmr ◽  
Isotope Labeling ◽  
Solid State Nmr Spectroscopy

Specific Isotope Labeling of Colicin E1 and B Channel Domains For Membrane Topological Analysis by Oriented Solid-State NMR Spectroscopy

ChemBioChem ◽  
2008 ◽  
Vol 9 (6) ◽  
pp. 944-951 ◽  
Author(s):  
Christopher Aisenbrey ◽  
Monica Cusan ◽  
Stephan Lambotte ◽  
Pieter Jasperse ◽  
Julia Georgescu ◽  
...  
Keyword(s):  
Solid State ◽  
Nmr Spectroscopy ◽  
Solid State Nmr ◽  
Isotope Labeling ◽  
Topological Analysis ◽  
Solid State Nmr Spectroscopy ◽  
Colicin E1

scholarly journals Isotope Labeling for Solution and Solid-State NMR Spectroscopy of Membrane Proteins

2012 ◽  
pp. 35-62 ◽  
Author(s):  
Raffaello Verardi ◽  
Nathaniel J. Traaseth ◽  
Larry R. Masterson ◽  
Vitaly V. Vostrikov ◽  
Gianluigi Veglia
Keyword(s):  
Solid State ◽  
Nmr Spectroscopy ◽  
Membrane Proteins ◽  
Solid State Nmr ◽  
Isotope Labeling ◽  
Solid State Nmr Spectroscopy

scholarly journals A New Methodological Approach to Correlate Protective and Microscopic Properties by Soft X-ray Microscopy and Solid State NMR Spectroscopy: The Case of Cusa’s Stone

2021 ◽  
Vol 11 (13) ◽  
pp. 5767
Author(s):  
Veronica Ciaramitaro ◽  
Alberto Spinella ◽  
Francesco Armetta ◽  
Roberto Scaffaro ◽  
Emmanuel Fortunato Gulino ◽  
...  
Keyword(s):  
Solid State ◽  
Nmr Spectroscopy ◽  
Solid State Nmr ◽  
Methodological Approach ◽  
Polymer Chains ◽  
General Question ◽  
Protective Agent ◽  
Vapour Permeability ◽  
X Ray ◽  
Solid State Nmr Spectroscopy

Hydrophobic treatment is one of the most important interventions usually carried out for the conservation of stone artefacts and monuments. The study here reported aims to answer a general question about how two polymers confer different protective performance. Two fluorinated-based polymer formulates applied on samples of Cusa’s stone confer a different level of water repellence and water vapour permeability. The observed protection action is here explained on the basis of chemico-physical interactions. The distribution of the polymer in the pore network was investigated using scanning electron microscopy and X-ray microscopy. The interactions between the stone substrate and the protective agents were investigated by means of solid state NMR spectroscopy. The ss-NMR findings reveal no significant changes in the chemical neighbourhood of the observed nuclei of each protective agent when applied onto the stone surface and provide information on the changes in the organization and dynamics of the studied systems, as well as on the mobility of polymer chains. This allowed us to explain the different macroscopic behaviours provided by each protective agent to the stone substrate.

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