Copper‐Coordinated Histidyl Bolaamphiphile Assembly as an Oxidative Catalyst: Coordination Structure and Catalytic Activity in Cyclohexane Oxidation

ChemCatChem ◽  
2019 ◽  
Vol 11 (19) ◽  
pp. 4935-4943 ◽  
Author(s):  
Changjoon Keum ◽  
Junghyun Cho ◽  
Sunggook Park ◽  
Sang‐Yup Lee
Molecules ◽  
2016 ◽  
Vol 21 (4) ◽  
pp. 425 ◽  
Author(s):  
Manas Sutradhar ◽  
Elisabete Alegria ◽  
M. Guedes da Silva ◽  
Luísa Martins ◽  
Armando Pombeiro

2001 ◽  
Vol 171 (1-2) ◽  
pp. 251-257 ◽  
Author(s):  
Rosenira Serpa da Cruz ◽  
Juliana Martins de Souza e Silva ◽  
UIrich Arnold ◽  
Ulf Schuchardt

2016 ◽  
Vol 24 (4) ◽  
pp. 855-866 ◽  
Author(s):  
Savita Khare ◽  
Priti Shrivastava ◽  
Rajendra Chokhare ◽  
Jagat Singh Kirar ◽  
Swati Parashar

2021 ◽  
Vol 17 ◽  
Author(s):  
Weiqing Xu ◽  
Yu Wu ◽  
Lei Jiao ◽  
Wenling Gu ◽  
Dan Du ◽  
...  

Background: Nanozymes are a kind of emerging nanomaterials that can mimic the catalytic activity of natural enzymes with good stability. Objective: Benefited by the unique coordination structure and constitution, metal-organic frameworks (MOFs) have been widely exploited as novel nanozymes. Importantly, various MOFs engineered with fascinating functions provide great opportunities to enhance their enzyme-like activity and improve their applied performance, achieving the goal of vividly mimicking natural enzymes. Conclusion: This review summarized recent advances in the fabrication of the MOFs-based nanozymes and their applications in biosensing. First, MOFs-based nanomaterials containing pristine MOFs, functionalized MOFs, MOFs-based composites and MOFs derivatives are introduced, where the design strategy, enzyme-like activity and the catalytic mechanisms are highlighted systematically. Then, their applications in various target assays are summarized. Finally, the challenges and possible research directions for the development and application of MOFs-based nanozymes are provided.


2011 ◽  
Vol 40 (12) ◽  
pp. 2822 ◽  
Author(s):  
Maximilian N. Kopylovich ◽  
Andreia C. C. Nunes ◽  
Kamran T. Mahmudov ◽  
Matti Haukka ◽  
Tatiana C. O. Mac Leod ◽  
...  

2008 ◽  
Vol 29 (1) ◽  
pp. 4-6 ◽  
Author(s):  
Chen CHEN ◽  
Qiaohong ZHANG ◽  
Hong MA ◽  
Jin GAO ◽  
Zhiqiang SUN ◽  
...  

Catalysts ◽  
2018 ◽  
Vol 8 (2) ◽  
pp. 69 ◽  
Author(s):  
Ana Ribeiro ◽  
Inês Matias ◽  
Elisabete Alegria ◽  
Ana Ferraria ◽  
Ana Botelho do Rego ◽  
...  

For the first time, a magnetic C-scorpionate catalyst was prepared from the iron(II) complex [FeCl2{κ3-HC(pz)3}] (pz = pyrazol-1-yl) and ferrite, using the sustainable mechanochemical synthetic procedure. Its catalytic activity for the cyclohexane oxidation with tert-butyl hydroperoxide (TBHP) was evaluated in different conditions, namely under microwave irradiation and under the effect of an external magnetic field. The use of such magnetic conditions significantly shifted the catalyst alcohol/ketone selectivity, thus revealing a promising, easy new protocol for tuning selectivity in important catalytic processes.


2005 ◽  
Vol 99 (3-4) ◽  
pp. 231-234 ◽  
Author(s):  
Lipeng Zhou ◽  
Jie Xu ◽  
Hong Miao ◽  
Xiaoqiang Li ◽  
Feng Wang

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