Interplay of Chemical Microenvironment and Redox Environment on Thiol-Disulfide Exchange Kinetics

2011 ◽  
Vol 17 (36) ◽  
pp. 10064-10070 ◽  
Author(s):  
Chuanliu Wu ◽  
Cristina Belenda ◽  
Jean-Christophe Leroux ◽  
Marc A. Gauthier
Keyword(s):  
Disulfide Exchange ◽  
Redox Environment ◽  
Chemical Microenvironment ◽  
Exchange Kinetics

Chemical control of the aromatic disulfide exchange kinetics for tailor-made epoxy vitrimers

Polymer ◽  
2021 ◽  
pp. 124457
Author(s):  
Alaitz Ruiz de Luzuriaga ◽  
Gema Solera ◽  
Izaskun Azcarate-Ascasua ◽  
Virginie Boucher ◽  
Hans-Jürgen Grande ◽  
...  
Keyword(s):  
Chemical Control ◽  
Disulfide Exchange ◽  
Exchange Kinetics

Electrostatic influence of local cysteine environments on disulfide exchange kinetics

Biochemistry ◽  
1981 ◽  
Vol 20 (23) ◽  
pp. 6509-6519 ◽  
Author(s):  
Grayson H. Snyder ◽  
Michael J. Cennerazzo ◽  
Anthony J. Karalis ◽  
Dorothy Locey
Keyword(s):  
Disulfide Exchange ◽  
Exchange Kinetics

Pyridyl disulfide-based thiol–disulfide exchange reaction: shaping the design of redox-responsive polymeric materials

2020 ◽  
Vol 11 (48) ◽  
pp. 7603-7624
Author(s):  
Ismail Altinbasak ◽  
Mehmet Arslan ◽  
Rana Sanyal ◽  
Amitav Sanyal
Keyword(s):  
Exchange Reaction ◽  
Functional Materials ◽  
Polymeric Materials ◽  
Disulfide Exchange ◽  
Redox Responsive ◽  
Synthetic Approaches

This review provides an overview of synthetic approaches utilized to incorporate the thiol-reactive pyridyl-disulfide motif into various polymeric materials, and briefly highlights its utilization to obtain functional materials.

Fast oxygen exchange kinetics of pore-free Bi1−xSrxFeO3−δ thin films

2011 ◽  
Vol 13 (37) ◽  
pp. 16530 ◽  
Author(s):  
Anja Wedig ◽  
Rotraut Merkle ◽  
Benjamin Stuhlhofer ◽  
Hanns-Ulrich Habermeier ◽  
Joachim Maier ◽  
...  
Keyword(s):  
Thin Films ◽  
Oxygen Exchange ◽  
Exchange Kinetics ◽  
Kinetics Of

scholarly journals Hydrogen exchange kinetics of human hemoglobins. The pH dependence of solvent accessibility in cyanomet-, oxy-, and deoxyhemoglobin.

1978 ◽  
Vol 253 (10) ◽  
pp. 3702-3707
Author(s):  
B.E. Hedlund ◽  
P.E. Hallaway ◽  
B.E. Hallaway ◽  
E.S. Benson ◽  
A. Rosenberg
Keyword(s):  
Hydrogen Exchange ◽  
Solvent Accessibility ◽  
Ph Dependence ◽  
Exchange Kinetics ◽  
Kinetics Of

Chain Exchange Kinetics of Bottlebrush Block Copolymer Micelles

2021 ◽  
Author(s):  
Seyoung Kim ◽  
Sangho Lee ◽  
Soo-Hyung Choi ◽  
Kookheon Char
Keyword(s):  
Block Copolymer ◽  
Block Copolymer Micelles ◽  
Exchange Kinetics ◽  
Copolymer Micelles ◽  
Kinetics Of

scholarly journals Adventures in molecular recognition. The ins and outs of templating

2000 ◽  
Vol 72 (12) ◽  
pp. 2265-2274 ◽  
Author(s):  
Jeremy K. M. Sanders
Keyword(s):  
Molecular Recognition ◽  
Combinatorial Chemistry ◽  
Biological Systems ◽  
Design Approach ◽  
Supramolecular Systems ◽  
Disulfide Exchange ◽  
Dynamic Combinatorial Chemistry ◽  
Evolutionary Features ◽  
Selection Approach ◽  
Porphyrin Dimers

Two different approaches are described for the creation of supramolecular systems potentially capable of recognition and catalysis. Using the design approach, we have been able to accelerate and influence two different Diels­Alder reactions within the cavities of porphyrin dimers and trimers; this is templating from the outside inwards. The selection approach is a synthetic chemical attempt to capture some of the key evolutionary features of biological systems: dynamic combinatorial chemistry is used to create equilibrating mixtures of potential receptors, and then a template is used to select and amplify the desired system. Five potential reactions for such dynamic chemistry are discussed: base-catalyzed transesterification, hydrazone exchange, disulfide exchange, alkene metathesis, and Pd-catalyzed allyl exchange, and preliminary templating results (inside outwards) are presented.

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