Pyridyl disulfide-based thiol–disulfide exchange reaction: shaping the design of redox-responsive polymeric materials

2020 ◽  
Vol 11 (48) ◽  
pp. 7603-7624
Author(s):  
Ismail Altinbasak ◽  
Mehmet Arslan ◽  
Rana Sanyal ◽  
Amitav Sanyal
Keyword(s):  
Exchange Reaction ◽  
Functional Materials ◽  
Polymeric Materials ◽  
Disulfide Exchange ◽  
Redox Responsive ◽  
Synthetic Approaches

This review provides an overview of synthetic approaches utilized to incorporate the thiol-reactive pyridyl-disulfide motif into various polymeric materials, and briefly highlights its utilization to obtain functional materials.

scholarly journals Research and application progress of lignin-based composite membrane

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Youjing Li ◽  
Fen Li ◽  
Ying Yang ◽  
Baocai Ge ◽  
Fanzhu Meng
Keyword(s):  
Environmental Pollution ◽  
Raw Materials ◽  
Waste Product ◽  
Functional Materials ◽  
Polymeric Materials ◽  
Composite Membranes ◽  
Organic Polymer ◽  
Future Research ◽  
Sustainable Resources ◽  
New Perspective

Abstract In view of the serious environmental pollution, which is the greatest problem the world is facing, and the continuous consumption of raw materials, it is imminent to search for green and sustainable resources. Lignin is an organic polymer that exists widely in nature, and if it can be transformed from traditional low-value waste product with low range of applications to functional materials with high application prospects, it can be of great significance to alleviate environmental pollution and shortage of fossil resources. One of the functional applications of lignin involves its use to fabricate composite with other polymeric materials, which can then be used to prepare membrane materials. This review summarizes the recent research and application progress of combining lignin with polypropylene, polyvinyl alcohol, starch, cellulose, chitosan, and other polymeric materials to prepare composite membranes; and summarizes the future development direction of lignin-based composite membranes. We hope this review may provide a new perspective to the understanding of lignin-based composite membranes and a useful reference for future research.

Poly(ε-caprolactone) with pendant natural peptides: an old polymeric biomaterial with new properties

2017 ◽  
Vol 8 (35) ◽  
pp. 5415-5426 ◽  
Author(s):  
Yuanyuan Ju ◽  
Mingming Zhang ◽  
Hanying Zhao
Keyword(s):  
Click Chemistry ◽  
Exchange Reaction ◽  
Ring Opening ◽  
The Self ◽  
Disulfide Exchange ◽  
Polymeric Biomaterial ◽  
Natural Peptides

Poly(ε-caprolactone) with pendant glutathione or l-carnosine was synthesized by a combination of ring-opening copolymerization, click chemistry and thiol-disulfide exchange reaction, and the self-assemblies of the polymers were investigated.

Thiol derivatives of cellulose as supports for the immobilization of non-thiol enzymes

1981 ◽  
Vol 46 (7) ◽  
pp. 1693-1700 ◽  
Author(s):  
Peter Gemeiner ◽  
Jiří Zemek
Keyword(s):  
Exchange Reaction ◽  
Proteolytic Activity ◽  
Acetylcholine Esterase ◽  
Mercaptoacetic Acid ◽  
Thiol Groups ◽  
Nucleophilic Reaction ◽  
Disulfide Exchange ◽  
Immobilized Trypsin ◽  
Esterolytic Activity ◽  
Derivatives Of

Thiosulfate derivatives, which can be reduced with mercaptoacetic acid, are suitable intermediates for the preparation of thiol derivatives of polymers. Thiosulfate derivatives of cellulose were prepared via chlorodeoxy- or via 3-chloro-2-hydroxy-propylcellulose, while mercaptodeoxycellulose prepared via chlorodeoxy derivative had more convenient properties for the immobilization of non-thiol enzymes (acetylcholine esterase, butyrylcholine esterase and trypsin). Before immobilization SH groups were introduced into choline esterases by i) reduction of the cystine residues, ii) reaction with methyl 4-mercaptobutyrimidate, and the isothiocyanate groups were introduced into trypsin on reaction with 3-isothiocyanatopropyl 1-isocyanate. The immobilization of the enzymes treated in this way was carried out under the conditions of the oxidation of thiol groups (i), thiol-disulfide exchange reaction (ii), or an addition nucleophilic reaction of isothiocyanates with thiols. In contrast to the proteolytic activity of the immobilized trypsin the esterolytic activity of immobilized choline esterases attained satisfactory values.

scholarly journals Reversible Protein Capture and Release by Redox-Responsive Hydrogel in Microfluidics

Polymers ◽  
2022 ◽  
Vol 14 (2) ◽  
pp. 267
Author(s):  
Chen Jiao ◽  
Franziska Obst ◽  
Martin Geisler ◽  
Yunjiao Che ◽  
Andreas Richter ◽  
...  
Keyword(s):  
Microfluidic Device ◽  
Disulfide Bonds ◽  
Stimuli Responsive ◽  
Disulfide Exchange ◽  
Protein Capture ◽  
Wide Range ◽  
Redox Responsive ◽  
Potential Applications ◽  
Capture And Release ◽  
Cross Linker

Stimuli-responsive hydrogels have a wide range of potential applications in microfluidics, which has drawn great attention. Double cross-linked hydrogels are very well suited for this application as they offer both stability and the required responsive behavior. Here, we report the integration of poly(N-isopropylacrylamide) (PNiPAAm) hydrogel with a permanent cross-linker (N,N′-methylenebisacrylamide, BIS) and a redox responsive reversible cross-linker (N,N′-bis(acryloyl)cystamine, BAC) into a microfluidic device through photopolymerization. Cleavage and re-formation of disulfide bonds introduced by BAC changed the cross-linking densities of the hydrogel dots, making them swell or shrink. Rheological measurements allowed for selecting hydrogels that withstand long-term shear forces present in microfluidic devices under continuous flow. Once implemented, the thiol-disulfide exchange allowed the hydrogel dots to successfully capture and release the protein bovine serum albumin (BSA). BSA was labeled with rhodamine B and functionalized with 2-(2-pyridyldithio)-ethylamine (PDA) to introduce disulfide bonds. The reversible capture and release of the protein reached an efficiency of 83.6% in release rate and could be repeated over 3 cycles within the microfluidic device. These results demonstrate that our redox-responsive hydrogel dots enable the dynamic capture and release of various different functionalized (macro)molecules (e.g., proteins and drugs) and have a great potential to be integrated into a lab-on-a-chip device for detection and/or delivery.

High-performance polymer composites with enhanced mechanical and thermal properties from cyanate ester/benzoxazine resin and short Kevlar/glass hybrid fibers

2018 ◽  
Vol 31 (6) ◽  
pp. 719-732 ◽  
Author(s):  
Abdeldjalil Zegaoui ◽  
Mehdi Derradji ◽  
Abdul Qadeer Dayo ◽  
Aboubakr Medjahed ◽  
Hui-yan Zhang ◽  
...  
Keyword(s):  
Thermal Properties ◽  
High Performance ◽  
Hybrid Composites ◽  
Glass Fibers ◽  
Functional Materials ◽  
Polymeric Materials ◽  
Cyanate Ester ◽  
Resin Matrix ◽  
Mechanical And Thermal Properties ◽  
Hybrid Fibers

The investigation and design of new polymeric materials with an astonishing combination of properties are nowadays of great importance to facilitate the manufacturing process of high-quality products intended to be utilized in different applications and technical fields. For this intent, novel high-performance blend composites composed of the cyanate ester/benzoxazine resin blend reinforced by different proportions of silane-surface modified Kevlar and glass fibers were successfully fabricated by a compression molding technique and characterized by different experimental tests. The mechanical test results revealed that the bending and impact strength properties were considerably improved when increasing the amount of the hybrid fibers. The studied materials also presented excellent thermal stabilities as compared to the unfilled blend’s properties. With respect to the properties of the reinforcing systems, these improvements seen in either the mechanical or thermal properties could be due to the good dispersion as well as excellent adhesion of the reinforcing fibers inside the resin matrix, which were further evidenced by the Fourier transform infrared spectroscopy and scanning electron microscopy results. Consequently, the improved mechanical and thermal properties promote the use of the fabricated hybrid composites in domestic and industrial applications requiring functional materials with advanced properties for aerospace and military applications.

Ultra-Pure Viscoelastic Damping Polymers and Associated Low Outgassing Materials

2000 ◽  
Author(s):  
Jeff W. McCutcheon
Keyword(s):  
Functional Materials ◽  
Polymeric Materials ◽  
Test Methods ◽  
Test Method ◽  
Viscoelastic Damping ◽  
Passive Damping ◽  
Static Headspace Gas Chromatography ◽  
New Generation ◽  
Passive Materials ◽  
Optimum Application

Abstract The key to successful multifunctional materials applications for vibration, shock and acoustic control is often the proper selection of materials, geometric design and optimum application. Much work has been done in the areas of geometric designs and optimum application of the multi-functional materials. The next step is improvements in the passive damping materials themselves. The improvement in the passive materials in the past has often focused on the areas of improved damping performance (loss factor, storage modulus), material performance (acrylics, silicones, etc.) and enhanced features (thermally conductive, electrically conductive, etc). One of the newest requirements for passive damping polymers is in the area of ultra-pure viscoelastic damping polymers. This new generation of materials is finding growing use because the sensitive environment where the passive material is used require a material that will not negatively impact the components in that environment. This new generation of passive materials needs to be ultra-pure with respect to organic material outgassing, anions, catalysts and siloxanes. In addition to the viscoelastic damping polymer requirements for high purity, the associated polymeric materials (epoxies, laminating adhesives and tapes) used in the same environment must also be of a similar low outgassing, ultra-pure, ultra-clean, electronics grade or clean room performance designation. If this is not done, the environment could become contaminated and negate a portion of the benefit of using the clean damping material. This also requires an understanding of the test method used to determine each product’s cleanliness performance, as all test methods are not equal and can give significantly different test results. An example is comparing a polymer sample tested for organic outgassing and using a static headspace gas chromatography/mass spectroscopy (GC/MS) and a dynamic headspace GC/MS.

Bipolar electrochemistry in synergy with electrophoresis: electric field-driven electrosynthesis of anisotropic polymeric materials

2020 ◽  
Vol 56 (92) ◽  
pp. 14327-14336
Author(s):  
Naoki Shida ◽  
Shinsuke Inagi
Keyword(s):  
Synergistic Effect ◽  
Electric Field ◽  
Functional Materials ◽  
Polymeric Materials ◽  
Electrochemistry And Electrophoresis ◽  
Bipolar Electrochemistry

The synergistic effect of bipolar electrochemistry and electrophoresis enables facile access to various anisotropic functional materials.

Antifouling and antibacterial hydrogel coatings with self-healing properties based on a dynamic disulfide exchange reaction

2015 ◽  
Vol 6 (39) ◽  
pp. 7027-7035 ◽  
Author(s):  
Wen Jing Yang ◽  
Xi Tao ◽  
Tingting Zhao ◽  
Lixing Weng ◽  
En-Tang Kang ◽  
...  
Keyword(s):  
Exchange Reaction ◽  
Self Healing ◽  
Disulfide Exchange ◽  
Hydrogel Coatings ◽  
Simple Surface

Antifouling and antibacterial hydrogel coatings with self-healing properties were developed via a simple surface-initiated thiol–ene photopolymerization.

Sign in / Sign up

Export Citation Format

Share Document