scholarly journals Unveiling the Unique Roles of Metal Coordination and Modulator in the Polymorphism Control of Metal–Organic Frameworks

2021 ◽  
Author(s):  
Zi‐Jian Li ◽  
Yu Ju ◽  
Zeya Zhang ◽  
Huangjie Lu ◽  
Yongxin Li ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Metal Coordination ◽  
Metal Organic

scholarly journals Towards highly active and stable nickel-based metal–organic frameworks as ethylene oligomerization catalysts

2019 ◽  
Vol 48 (10) ◽  
pp. 3415-3421 ◽  
Author(s):  
Ubed S. F. Arrozi ◽  
Volodymyr Bon ◽  
Christel Kutzscher ◽  
Irena Senkovska ◽  
Stefan Kaskel
Keyword(s):  
Metal Organic Frameworks ◽  
Ethylene Oligomerization ◽  
Metal Coordination ◽  
Highly Active ◽  
Metal Organic

The crucial impact of metal coordination on selectivity and leaching is elucidated by comparing MOFs constructed from different clusters and linkers.

scholarly journals Nickel(ii) metal–organic frameworks with N,N′-di(4-pyridyl)-naphthalenediimide ligands: influence of secondary building unit geometry on dimensionality and framework dimensions

CrystEngComm ◽  
2017 ◽  
Vol 19 (37) ◽  
pp. 5558-5564 ◽  
Author(s):  
Constance R. Pfeiffer ◽  
Naomi Biggins ◽  
William Lewis ◽  
Neil R. Champness
Keyword(s):  
Intermolecular Interactions ◽  
Metal Organic Frameworks ◽  
Metal Coordination ◽  
Coordination Geometry ◽  
Secondary Building Unit ◽  
Building Unit ◽  
Metal Organic

The influence of intermolecular interactions and metal coordination geometry on MOF framework dimensions are discussed.

Tubular metal organic frameworks from the curvature of 2D-honeycombed metal coordination

2020 ◽  
Vol 49 (8) ◽  
pp. 2403-2406
Author(s):  
Junhui Bao ◽  
Shanshan Wu ◽  
Xin Xu ◽  
Liping Huang ◽  
Liwei Zhang ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Metal Coordination ◽  
Catalytic Kinetics ◽  
Metal Organic

A tubular catalyst showed fast catalytic kinetics for CO2 conversion with a TON of 2300 and a TOF of up to 173 h−1.

Metal coordination and metal activation abilities of commonly unreactive chloromethanes toward metal–organic frameworks

2018 ◽  
Vol 54 (50) ◽  
pp. 6458-6471 ◽  
Author(s):  
Jinhee Bae ◽  
Eun Ji Lee ◽  
Nak Cheon Jeong
Keyword(s):  
Metal Organic Frameworks ◽  
Metal Coordination ◽  
Coordination Sites ◽  
Metal Organic

The commonly inert chloromethanes, dichloromethane and trichloromethane, can exchange other solvents bonded at open coordination sites in metal–organic frameworks, providing a new route to activate the open coordination sites for subsequent use in applications.

scholarly journals The Significance of Metal Coordination in Imidazole‐Functionalized Metal–Organic Frameworks for Carbon Dioxide Utilization

2020 ◽  
Vol 26 (60) ◽  
pp. 13606-13610
Author(s):  
William R. Webb ◽  
Matthew E. Potter ◽  
Daniel J. Stewart ◽  
Stuart J. Elliott ◽  
Pier J. A. Sazio ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Metal Organic Frameworks ◽  
Metal Coordination ◽  
Carbon Dioxide Utilization ◽  
Metal Organic

Metal-Organic Frameworks

2021 ◽  
Author(s):  
Lars Öhrström ◽  
Francoise M. Amombo Noa
Keyword(s):  
Metal Organic Frameworks ◽  
Metal Organic

Substrate templated synthesis of single-phase and uniform Zr-porphyrin-based metal–organic frameworks

2020 ◽  
Vol 7 (1) ◽  
pp. 221-231
Author(s):  
Seong Won Hong ◽  
Ju Won Paik ◽  
Dongju Seo ◽  
Jae-Min Oh ◽  
Young Kyu Jeong ◽  
...  
Keyword(s):  
Chemical Bath Deposition ◽  
Single Phase ◽  
Metal Organic Frameworks ◽  
Templated Synthesis ◽  
Pore Structures ◽  
Phase Pure ◽  
Metal Organic ◽  
Cbd Method

We successfully demonstrate that the chemical bath deposition (CBD) method is a versatile method for synthesizing phase-pure and uniform MOFs by controlling their nucleation stages and pore structures.

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