ChemInform Abstract: PHOTOELECTRON SPECTROSCOPY OF METHYL, ETHYL, ISOPROPYL, AND TERT-BUTYL RADICALS. IMPLICATIONS FOR THE THERMOCHEMISTRY AND STRUCTURES OF THE RADICALS AND THEIR CORRESPONDING CARBONIUM IONS

Chemischer Informationsdienst ◽

10.1002/chin.197944038 ◽

1979 ◽

Vol 10 (44) ◽

Author(s):

F. A. HOULE ◽

J. L. BEAUCHAMP

Keyword(s):

Photoelectron Spectroscopy ◽

Methyl Ethyl ◽

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Photoelectron spectroscopy of methyl, ethyl, isopropyl, and tert-butyl radicals. Implications for the thermochemistry and structures of the radicals and their corresponding carbonium ions

Journal of the American Chemical Society ◽

10.1021/ja00509a010 ◽

1979 ◽

Vol 101 (15) ◽

pp. 4067-4074 ◽

Author(s):

F. A. Houle ◽

J. L. Beauchamp

Keyword(s):

Photoelectron Spectroscopy ◽

Methyl Ethyl ◽

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Energetics and structure of the 1- and 2-adamantyl radicals and their corresponding carbonium ions by photoelectron spectroscopy

Journal of the American Chemical Society ◽

10.1021/ja00269a007 ◽

1986 ◽

Vol 108 (9) ◽

pp. 2162-2169 ◽

Author(s):

Gary H. Kruppa ◽

J. L. Beauchamp

Keyword(s):

Photoelectron Spectroscopy ◽

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217. Hydrolytic decomposition of esters of nitric acid. Part I. General experimental techniques. Alkaline hydrolysis and neutral solvolysis of methyl, ethyl, isopropyl, and tert.-butyl nitrates in aqueous alcohol

Journal of the Chemical Society (Resumed) ◽

10.1039/jr9520001193 ◽

1952 ◽

pp. 1193 ◽

Author(s):

John W. Baker ◽

D. M. Easty

Keyword(s):

Nitric Acid ◽

Alkaline Hydrolysis ◽

Experimental Techniques ◽

Aqueous Alcohol ◽

Methyl Ethyl ◽

Hydrolytic Decomposition

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Stable Carbonium Ions. IV: Secondary and Tertiary Alkyl and Aralkyl Oxocarbonium Hexafluoroantimonates. Formation and Identification of the Trimethylcarbonium Ion by Decarbonylation of the tert-Butyl Oxocarbonium Ion

World Scientific Series in 20th Century Chemistry - Across Conventional Lines ◽

10.1142/9789812791405_0039 ◽

2003 ◽

pp. 219-225

Author(s):

GEORGE A. OLAH ◽

WILLIAM S. TOLGYESI ◽

STEPHEN J. KUHN ◽

MARYANNE E. MOFFATT ◽

IVAN J. BASTIEN ◽

...

Keyword(s):

Carbonium Ions ◽

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ChemInform Abstract: PHOTOELECTRON SPECTROSCOPY OF ISOMERIC C4H7 RADICALS. IMPLICATIONS FOR THE THERMOCHEMISTRY AND STRUCTURES OF THE RADICALS AND THEIR CORRESPONDING CARBONIUM IONS

Chemischer Informationsdienst ◽

10.1002/chin.198512044 ◽

1985 ◽

Vol 16 (12) ◽

Author(s):

J. C. SCHULTZ ◽

F. A. HOULE ◽

J. L. BEAUCHAMP

Keyword(s):

Photoelectron Spectroscopy ◽

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Analysis of the structures, infrared spectra, and Raman spectra for methyl, ethyl, isopropyl, and tert-butyl radicals

Journal of the American Chemical Society ◽

10.1021/ja00001a046 ◽

1991 ◽

Vol 113 (1) ◽

pp. 317-328 ◽

Author(s):

Jacob Pacansky ◽

W. Koch ◽

M. D. Miller

Keyword(s):

Raman Spectra ◽

Infrared Spectra ◽

Methyl Ethyl ◽

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Rates of solvolysis of 2-methyl-, 2-tert-butyl-, 2-phenyl-, and 2-cyclopropyl-2-propyl p-nitrobenzoates. Evidence that carbon-13 chemical shifts of carbonium ions do not correlate with the stabilities of solvolytic transition states and the corresponding cationic intermediates

Journal of the American Chemical Society ◽

10.1021/ja00788a070 ◽

1973 ◽

Vol 95 (7) ◽

pp. 2400-2401 ◽

Author(s):

Herbert C. Brown ◽

Edward N. Peters

Keyword(s):

Chemical Shifts ◽

Transition States ◽

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New Synthesis of Alkyl 1-tert-Butyl-4,4-dimethyl-2,5-dioxo-pyrrolidine-3-carboxylate and Dialkyl 2-(1-tert-Butylcarbamoyl-1-methyl-ethyl)-malonates.

10.1002/chin.200346068 ◽

2003 ◽

Vol 34 (46) ◽

Author(s):

Issa Yavari ◽

Mohammad R. Hosseini-Tabatabaei ◽

Azizollah Habibi

Keyword(s):

Methyl Ethyl ◽

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Kinetic study of the cyclohexadienyl radical. Part 2.—Patterns of combination and disproportionation with the methyl, ethyl, sec-propyl and tert-butyl radicals

Transactions of the Faraday Society ◽

10.1039/tf9686402735 ◽

1968 ◽

Vol 64 (0) ◽

pp. 2735-2751 ◽

Author(s):

D. G. L. James ◽

R. D. Suart

Keyword(s):

Kinetic Study ◽

Methyl Ethyl ◽

Cyclohexadienyl Radical

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Application of photoelectron spectroscopy to substituent effects. Conformational analysis of some flexible allylic ethers and alcohols

Canadian Journal of Chemistry ◽

10.1139/v79-300 ◽

1979 ◽

Vol 57 (14) ◽

pp. 1890-1896 ◽

Author(s):

R. S. Brown ◽

R. W. Marcinko ◽

A. Tse

Keyword(s):

Conformational Analysis ◽

Gas Phase ◽

Photoelectron Spectroscopy ◽

Ionization Energy ◽

Substituent Effects ◽

Allylic Alcohol ◽

Cis And Trans ◽

He(I) photoelectron (pe) spectroscopy is applied to determine the preferred gas phase conformations of a limited number of flexible allylic ethers and alcohols. Based on earlier observations that the π-ionization energy is increased more when the allylic C—O bond is coplanar (with the π-system) than when it is perpendicular, the pe spectrum of cis and trans-4-tert-butyl-2-cyclohexanol and their corresponding ethers, and 5α-hydroxy(and methoxy)-10α-Δ3-octalin have been determined. The results indicate that when a coplanar arrangement of the allylic C—O bond can be attained, it is preferred, leading to a favored conformation of the allylic alcohol or ether.

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