ChemInform Abstract: Formation and Reaction of Trichloro Complexes of Bivalent Transition Metals in 1,2-Dichloroethane.

ChemInform ◽  
1988 ◽  
Vol 19 (24) ◽  
Author(s):  
K. SATOH ◽  
T. SUZUKI ◽  
K. SAWADA
Keyword(s):  
Transition Metals ◽  
Bivalent Transition Metals

Metallkomplexe des Dihydrazido-thiophosphorsäure-phenylesters und des Dihydrazido-thiophosphats / Metal Complexes of Dihydrazido-thiophosphoric Acid Phenylester and Dihydrazido-thiophosphate

1976 ◽  
Vol 31 (12) ◽  
pp. 1553-1561 ◽  
Author(s):  
Udo Engelhardt ◽  
Guido Scherer
Keyword(s):  
Transition Metals ◽  
Metal Complexes ◽  
Elemental Analysis ◽  
Complex Salt ◽  
Chelate Ligand ◽  
Thiophosphoric Acid ◽  
X Ray ◽  
Distorted Octahedral Coordination ◽  
Bivalent Transition Metals ◽  
Distorted Octahedral

Dihydrazido-thiophosphoric acid phenylester as a tridentate chelate ligand forms complexes with bivalent transition metals. The compounds [Ni(II)(L)2]Cl2, [Zn(L)2]Cl2 and [Cd(L)Cl2] are prepared and characterized by elemental analysis, IR, Raman, UV/VIS spectra and X-ray powder diagrams. The nickel possesses a slightly distorted octahedral coordination. The nickel(II) complex can be transformed to a carbon free inner complex salt of the formula [Ni(II){(NH2-NH)2Ρ(S)O-}2] by hydrolysis.

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