ChemInform Abstract: Triphenylpyrylium Salt Sensitized Electron Transfer Oxygenation of Adamantylideneadamantane. Product, Fluorescence Quenching, and Laser Flash Photolysis Studies.

ChemInform ◽  
2010 ◽  
Vol 22 (24) ◽  
pp. no-no
Author(s):  
R. AKABA ◽  
H. SAKURAGI ◽  
K. TOKUMARU
Keyword(s):  
Electron Transfer ◽  
Fluorescence Quenching ◽  
Flash Photolysis ◽  
Laser Flash Photolysis ◽  
Laser Flash

Electron transfer sensitized photolysis of 'onium salts

1988 ◽  
Vol 66 (2) ◽  
pp. 319-324 ◽  
Author(s):  
R. J. DeVoe ◽  
M. R. V. Sahyun ◽  
Einhard Schmidt ◽  
N. Serpone ◽  
D. K. Sharma
Keyword(s):  
Electron Transfer ◽  
Flash Photolysis ◽  
Laser Flash Photolysis ◽  
Laser Flash ◽  
Quantitative Model ◽  
Intersystem Crossing ◽  
Single Electron Transfer ◽  
Onium Salts ◽  
Encounter Complex ◽  
Back Electron Transfer

We have studied the anthracene-sensitized photolyses of both diphenyliodonium and triphenylsulphonium salts in solution using both steady-state and laser flash photolysis techniques. Photoproducts, namely, phenylated anthracenes along with iodobenzene or diphenylsulphide, respectively, are obtained from both salts with quantum efficiencies of ca. 0.1 at 375 nm. We infer the intermediacy of diphenyliodo and triphenylsulphur radicals formed by single electron transfer from the singlet-excited anthracene. We have developed a quantitative model of this chemistry, and identify the principal sources of inefficiency as back electron transfer, which occurs at nearly the theoretically limiting rate, intersystem crossing from the initially formed sensitizer–'onium salt encounter complex, and in-cage radical recombination.

Laser flash photolysis studies of intramolecular electron transfer in milk xanthine oxidase

Biochemistry ◽  
1983 ◽  
Vol 22 (23) ◽  
pp. 5270-5279 ◽  
Author(s):  
Anjan Bhattacharyya ◽  
Gordon Tollin ◽  
Michael Davis ◽  
Dale E. Edmondson
Keyword(s):  
Electron Transfer ◽  
Xanthine Oxidase ◽  
Flash Photolysis ◽  
Laser Flash Photolysis ◽  
Laser Flash ◽  
Intramolecular Electron Transfer

Direct Measurement by Laser Flash Photolysis of Intraprotein Electron Transfer in a Rat Neuronal Nitric Oxide Synthase

2007 ◽  
Vol 129 (17) ◽  
pp. 5621-5629 ◽  
Author(s):  
Changjian Feng ◽  
Gordon Tollin ◽  
James T. Hazzard ◽  
Nickolas J. Nahm ◽  
J. Guy Guillemette ◽  
...  
Keyword(s):  
Nitric Oxide ◽  
Electron Transfer ◽  
Nitric Oxide Synthase ◽  
Direct Measurement ◽  
Flash Photolysis ◽  
Laser Flash Photolysis ◽  
Neuronal Nitric Oxide Synthase ◽  
Laser Flash ◽  
Oxide Synthase
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