ChemInform Abstract: The First Aldehyde-Derived Crystalline Geminal Diol (III) Lacking Internal Electronic Stabilization

ChemInform ◽  
2010 ◽  
Vol 22 (26) ◽  
pp. no-no
Author(s):  
D. A. SMITH ◽  
D. BAKER ◽  
A. F. M. M. RAHMAN
Keyword(s):  
Electronic Stabilization ◽  
Geminal Diol

The first aldehyde-derived crystalline geminal diol lacking internal electronic stabilization

1991 ◽  
Vol 2 (1) ◽  
pp. 65-70 ◽  
Author(s):  
Douglas A. Smith ◽  
David Baker ◽  
A. F. M. Maqsudur Rahman
Keyword(s):  
Electronic Stabilization ◽  
Geminal Diol

Nickel(II)-Methyl Complexes Adopting Idealized Seesaw Geometries

2019 ◽  
Author(s):  
Ethan A. Hill ◽  
Norman Zhao ◽  
Alexander S. Filatov ◽  
John Anderson
Keyword(s):  
Singlet State ◽  
Strong Field ◽  
Structural Distortion ◽  
Computational Results ◽  
Threefold Symmetry ◽  
Chelating Ligand ◽  
Electronic Stabilization

We report four-coordinate nickel(II)-methyl complexes of tris-carbene borate ligands which adopt rare seesaw geometries. Experimental and computational results suggest the structural distortion from threefold symmetry results from a combination of electronic stabilization of the singlet state, strong field donors, and constrained angles from the chelating ligand.

Photoemission evidence of electronic stabilization of polar surfaces inK3C60

2000 ◽  
Vol 62 (23) ◽  
pp. 16046-16055 ◽  
Author(s):  
R. Hesper ◽  
L. H. Tjeng ◽  
A. Heeres ◽  
G. A. Sawatzky
Keyword(s):  
Polar Surfaces ◽  
Electronic Stabilization

Gaseous infrared spectra of the simplest geminal diol CH2(OH)2 and the isotopic analogues in the hydration of formaldehyde

2021 ◽  
Author(s):  
Hung-Yang Jain ◽  
Chih-Tsun Yang ◽  
Li-Kang Chu
Keyword(s):  
Infrared Spectrum ◽  
Infrared Spectra ◽  
Absorption Bands ◽  
Geminal Diol

The infrared spectrum of the simplest geminal diol, methanediol or methylene glycol (CH2(OH)2), was successfully probed in the gaseous hydration of formaldehyde. The observed absorption bands coincided with the anharmonic...

Electronic stabilization of the Si(111)5 × 2–Au surface: Pb and Si adatoms

2012 ◽  
Vol 24 (9) ◽  
pp. 095002 ◽  
Author(s):  
A Stȩpniak ◽  
M Krawiec ◽  
G Zawadzki ◽  
M Jałochowski
Keyword(s):  
Electronic Stabilization
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