Nickel(II)-Methyl Complexes Adopting Idealized Seesaw Geometries
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We report four-coordinate nickel(II)-methyl complexes of tris-carbene borate ligands which adopt rare seesaw geometries. Experimental and computational results suggest the structural distortion from threefold symmetry results from a combination of electronic stabilization of the singlet state, strong field donors, and constrained angles from the chelating ligand.
1974 ◽
Vol 32
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pp. 174-175
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1993 ◽
Vol 51
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pp. 154-155
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2006 ◽
Vol 11
(1)
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pp. 13-32
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2002 ◽
Vol 76
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pp. 47
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