ChemInform Abstract: The Catalytic Activity of Titania Nanostructures in the Synthesis of Amides under Solvent-Free Conditions.

ChemInform ◽  
2012 ◽  
Vol 43 (44) ◽  
pp. no-no
Author(s):  
Sangaraiah Nagarajan ◽  
Park Ran ◽  
Poovan Shanmugavelan ◽  
Murugan Sathishkumar ◽  
Alagusundaram Ponnuswamy ◽  
...  
2012 ◽  
Vol 36 (6) ◽  
pp. 1312 ◽  
Author(s):  
Sangaraiah Nagarajan ◽  
Park Ran ◽  
Poovan Shanmugavelan ◽  
Murugan Sathishkumar ◽  
Alagusundaram Ponnuswamy ◽  
...  

2019 ◽  
Vol 48 (10) ◽  
pp. 3447-3452 ◽  
Author(s):  
Alexandra A. Ageshina ◽  
Grigorii K. Sterligov ◽  
Sergey A. Rzhevskiy ◽  
Maxim A. Topchiy ◽  
Gleb A. Chesnokov ◽  
...  

A single catalyst for solvent-free Buchwald–Hartwig amination with both primary and secondary amines.


Catalysts ◽  
2020 ◽  
Vol 10 (2) ◽  
pp. 252 ◽  
Author(s):  
Gabriela Dobras ◽  
Kornela Kasperczyk ◽  
Sebastian Jurczyk ◽  
Beata Orlińska

N-Hydroxyphthalimide was immobilized via ester bond on commercially available silica gel (SiOCONHPI) and then coated with various ionic liquids containing dissolved CoCl2 (SiOCONHPI@CoCl2@IL). New catalysts were characterized by means of FT IR spectroscopy, elemental analysis, SEM and TGA analysis and used in ethylbenzene oxidation with oxygen under mild solvent-free conditions (80 °C, 0.1 MPa). High catalytic activity of SiOCONHPI was proved. In comparison to a non-catalytic reaction, a two-fold increase in conversion of ethylbenzene was observed (from 4.7% to 8.6%). Coating of SiOCONHPI with [bmim][OcOSO3], [bmim][Cl] and [bmim][CF3SO3] containing CoCl2 enabled to increase the catalytic activity in relation to systems in which IL and CoCl2 were added directly to reaction mixture. The highest conversion of ethylbenzene was obtained while SiOCONHPI@CoCl2@[bmim][OcOSO3] were used (12.1%). Catalysts recovery and reuse was also studied.


RSC Advances ◽  
2015 ◽  
Vol 5 (26) ◽  
pp. 19790-19798 ◽  
Author(s):  
Farhad Shirini ◽  
Omid Goli Jolodar ◽  
Mohadeseh Seddighi ◽  
Hojatollah Takbiri Borujeni

Succinimidinium hydrogensulfate ([H-Suc]HSO4), which is prepared from the reaction of succinimide and sulfuric acid, showed excellent catalytic activity for the N-Boc protection of various amines under solvent free conditions.


2009 ◽  
Vol 6 (s1) ◽  
pp. S390-S396 ◽  
Author(s):  
Abdolkarim Zare ◽  
Alireza Hasaninejad ◽  
Esmael Rostami ◽  
Ahmad Reza Moosavi-Zare ◽  
Maria Merajoddin ◽  
...  

A highly efficient, green and expeditious solvent-free method is described for the chemoselective conversion of aldehydes to the corresponding acylals in excellent yields, using acetic anhydride in the presence of catalytic amount (20 mol%) of silica-supported LiHSO4. Ketones does not react under these reaction conditions. LiHSO4/SiO2can be recovered and reused without any significant loss of its catalytic activity.


2019 ◽  
Vol 6 (1) ◽  
pp. 317-325 ◽  
Author(s):  
Yixing Li ◽  
Xiao Zhang ◽  
Ping Xu ◽  
Zimin Jiang ◽  
Jianmin Sun

Novel Zn(PZDC)(ATZ) with Lewis acid–base sites exhibited strong resistance to acids/alkalis and moisture and possessed high catalytic activity for CO2 transformation.


2020 ◽  
Vol 9 (1) ◽  
pp. 72-79
Author(s):  
Jhansi R. Sunkara ◽  
Sathish M. Botsa

Background: Metal oxide or metal oxide composite nanoparticles are attaining tremendous importance due to their catalytic activities for various organic transformations. Objective: To report the one-pot synthesis of xanthene derivatives prepared by ZnS-Fe2O3-Ag composite under solvent-free conditions. Method: To prepare nanocomposite by a facile and simple hydrothermal approach. Results: The prepared composite is smaller (17.56 nm) in size and can be easily separable, recycled and reused six times without any significant loss of catalytic activity with excellent yields. In short reaction time, great catalytic activity was perceived with no co-catalyst and any other activator. Conclusion: In conclusion, ZnS-Fe2O3-Ag composite provides a simple, economical, efficient and greener method for the synthesis of one-pot multicomponent reaction of aldehyde with 1,3-diketones under solvent free conditions for the synthesis of 1,8-dioxooctahydro xanthenes. In short reaction time, great catalytic activity was perceived with no co-catalyst and any other activator.


2019 ◽  
Vol 21 (11) ◽  
pp. 3029-3049 ◽  
Author(s):  
Sara S. E. Ghodsinia ◽  
Batool Akhlaghinia

The catalytic activity of SBA-16/GPTMS-TSC-CuI as a novel and efficient heterogeneous catalyst was investigated for S-arylation reaction under solvent-free conditions.


Sign in / Sign up

Export Citation Format

Share Document