ChemInform Abstract: Crystal Plane-Dependent Surface Reactivity and Catalytic Property of Oxide Catalysts Studied with Oxide Nanocrystal Model Catalysts

ChemInform ◽  
2013 ◽  
Vol 44 (49) ◽  
pp. no-no
Author(s):  
Weixin Huang
2012 ◽  
Vol 463-464 ◽  
pp. 189-193
Author(s):  
Kong Zhai Li ◽  
Masaaki Haneda ◽  
Masakuni Ozawa

Maghemite (γ-FeSubscript text2OSubscript text3) and hematite (α-Fe2O3) nanoparticles with various dominant exposure crystal planes were prepared by several different methods. The structure and the reducibility of these materials were investigated by XRD, Raman and H2-TPR technologies, and their catalytic performance for propene oxidation was also discussed. The maghemite (γ-FeSubscript text2OSubscript text3) showed a better reducibility than hematite (α-FeSubscript text2OSubscript text3), but its activity for propene oxidation is relatively lower. The exposure crystal plane of hematite has a significant influence on its catalytic activity for propene oxidation. Among the prepared four samples, the hematite-1 sample showed the best activity. The selective growth of any planes with a relative low density of Fe atoms for the α-FeSubscript text2OSubscript text3 catalyst would lead to an obvious decrease in the catalytic activity.


Author(s):  
Zhenhua Zhang ◽  
Rui You ◽  
Weixin Huang

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Author(s):  
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